Metal-free Decarboxylative Oxygenation of α-Amino Acids to Amide Compounds via Photoredox Catalysis DOI
Rui Zhu,

Yaxin Wang,

Minshu Cui

et al.

Applied Catalysis A General, Journal Year: 2024, Volume and Issue: unknown, P. 120084 - 120084

Published: Dec. 1, 2024

Language: Английский

Engineering Defect-Mediated S-scheme heterojunctions in MOF-Derived N-doped NiO porous microrods and ZnIn2S4 nanosheets for superior photocatalytic hydrogen evolution DOI
Yang Li, Hongli Yang, Rui Wang

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 684, P. 805 - 818

Published: Jan. 10, 2025

Language: Английский

Citations

1

Organic-inorganic hybrid-based S-scheme heterostructure in solar-to-fuel conversion DOI
Yongkang Liu, Chunguang Chen, Graham Dawson

et al.

Journal of Material Science and Technology, Journal Year: 2025, Volume and Issue: unknown

Published: March 1, 2025

Language: Английский

Citations

1

Metal–organic framework derived micro-/nano-materials: precise synthesis and clean energy applications DOI

Guangxun Zhang,

Xinyi Li,

Yuxin Liu

et al.

Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(19), P. 6275 - 6306

Published: Jan. 1, 2024

We summarize the different synthetic strategies of MOF-derived micro-/nano-materials to date, including but not limited calcining, phosphating, sulfurization, selenylation method, ion exchange, and etching strategies.

Language: Английский

Citations

6

Noble‐Metal‐Free Cocatalysts Reinforcing Hole Consumption for Photocatalytic Hydrogen Evolution with Ultrahigh Apparent Quantum Efficiency DOI Open Access
Yajie Feng,

Shaokuan Gong,

Yang Wang

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 26, 2024

Achieving efficient and sustainable hydrogen production through photocatalysis is highly promising yet remains a significant challenge, especially when replacing costly noble metals with more abundant alternatives. Conversion efficiency noble-metal-free alternatives frequently limited by high charge recombination rates, mainly due to the sluggish transfer inefficient consumption of photo-generated holes. To address these challenges, rational design cocatalysts as oxidative sites reported facilitate hole consumption, leading markedly increased H

Language: Английский

Citations

6

Recent Advances in the Tunable Optoelectromagnetic Properties of PEDOTs DOI Creative Commons
Ling Zhu,

Qi Liu,

Y L Zhang

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(1), P. 179 - 179

Published: Jan. 4, 2025

Conducting polymers represent a crucial class of functional materials with widespread applications in diverse fields. Among these, poly(3,4-ethylenedioxythiophene) (PEDOT) and its derivatives have garnered significant attention due to their distinctive optical, electronic, magnetic properties, as well exceptional tunability. These properties often exhibit intricate interdependencies, manifesting synergistic, concomitant, or antagonistic relationships. In optics, PEDOTs are renowned for high transparency unique photoelectric responses. From an electrical perspective, they display conductivity, thermoelectric, piezoelectric performance, along notable electrochemical activity stability, enabling wide array electronic applications. terms demonstrate outstanding electromagnetic shielding efficiency microwave absorption capabilities. Moreover, these can be precisely tailored through molecular structure modifications, chemical doping, composite formation suit various application requirements. This review systematically examines the mechanisms underlying optoelectromagnetic PEDOTs, highlights tunability, outlines prospective research directions. By providing critical theoretical insights technical references, this aims advance landscape PEDOTs.

Language: Английский

Citations

0

Nitrogen Defects and Interfacial Chemical Bonds in Fe Single‐Site Mediated C3N4 With Rod‐Like Fe2O3 Enhanced the S‐Scheme Heterojunction for Efficient Energy Conversion DOI Open Access
Xinglin Wang, Huihui Zhang,

Yamei Huang

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 16, 2025

Abstract The rational design of S‐scheme heterojunctions holds significant potential for efficient photocatalytic energy conversion, attributed to their enhanced carrier separation efficiency and high redox capacity. Nevertheless, achieving precise control transfer dynamics in remains a substantial challenge. Herein, unique architecture is devised featuring porous rod‐shaped Fe 2 O 3 particles loaded onto single‐sites modified g‐C N 4 nanosheets via mediated heterocomponent anchorage, the directed growth using as anchoring points, thereby forming O─Fe─N interfacial chemical bonds (ICBs) generating abundant nitrogen defects (FeO/FeCN‐N v ). Photophysical processes are further investigated femtosecond transient absorption spectroscopy (fs‐TAS) situ irradiated X‐ray photoelectron (ISI‐XPS) with an adjustable wavelength irradiation light source. Encouragingly, results reveal internal electric field (IEF) constructed at these semicoherent phase boundaries, creating asymmetrical charge distribution. Simultaneously, introduce additional defect level that accelerates electron through IEF, enabling more rapid migration surface‐active sites both styrene epoxidation hydrogen evolution. synergistic effect ICBs coupling regulating offers new insights into photocatalysis, paving way advancements conversion.

Language: Английский

Citations

0

Enhanced carrier separation and decreased reaction barrier in cobalt-doped CdIn2S4 nanosheets for photocatalytic hydrogen evolution DOI
Liang Mao,

Qinran Li,

Qing Zhou

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Language: Английский

Citations

0

Graphene-Based Multi-Nanocomposites: Synthesis, Characterization and Photodegradation Analysis DOI

Adeeba Sadia,

Muhammad Sultan Irshad, Muhammad Faran Akhtar

et al.

Journal of Fluorescence, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 2, 2025

Language: Английский

Citations

0

Thiadiazole/Triazole-Based Covalent Organic Frameworks for Efficient Photocatalytic Reduction of U(Vi): Isomeric Effect and Delocalization Degree DOI
Xin Zhong, Ji Zhang, Jing Xu

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0

Reinforced Hole Trapping in S‐Scheme Photoharvesters for Markedly Enhanced Photocatalytic Hydrogen Evolution and Nitrogen Fixation DOI Open Access
Xiaoyan Lu, Jindou Hu, Xinhui Jiang

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 7, 2025

Abstract The S‐scheme heterojunction exerts a profoundly positive influence on enhancing carrier separation efficiency and redox capability. However, there are few reports accelerating the reaction rate of photogenerated charge carriers, particularly consumption holes in heterojunction. Herein, an situ construction strategy is employed to construct ultra‐small nonprecious metal NiO (≈2 nm) By incorporating into heterojunctions, photocatalytic hydrogen production performance significantly improved by 380 times, nitrogen fixation enhanced 20 times. Density function theoretical (DFT) calculations, X‐ray photoelectron spectroscopy (in XPS), Diffuse Reflectance Infrared Fourier Transform Spectroscopy DRIFTS) characterization results indicate that incorporation heterojunctions can not only enhance photo‐generated carriers ability but also further promote sacrificial agents, thereby achieving secondary enhancement efficiency. Therefore, (H 2 ) (N markedly improved. successful execution this work provides novel approach material structure design, offering valuable insights for development improvement high‐performance materials.

Language: Английский

Citations

0