Oxygen Vacancy Engineering for High-Performance Li-Rich Manganese Cathodes: Advances and Prospects DOI Creative Commons

Pengzu Kou,

Lei Zhang,

Zhigui Zhang

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104321 - 104321

Published: May 1, 2025

Language: Английский

Homogenized Upcycling for Spent LiNi0.5Co0.2Mn0.3O2: Modulating O Vacancies toward Enhanced Structural Stability DOI Open Access
Peng Ge,

Bin Wang,

Zihao Zeng

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 19, 2025

Abstract Fascinated by the high value and low pollution, direct recycling of spent LiNi 0.5 Co 0.2 Mn 0.3 O 2 (S‐NCM) has triggered plenty exploring activities. Considering different industry sources, they always display various particle sizes surface traits. Therefore, simple recovery chemical defects hardly meets market demand. Herein, homogenized strategy, containing physical crushing recovering, is introduced to regenerate morphology components S‐NCM, where successfully regenerated samples displayed uniform size stable lattice. Assisted crushing, precursors show a large contacting area with oxygen during reconstruction, accompanied effective repairing internal More significantly, unique manner induces vacancies (OVs) lowering Li/Ni disorder, bringing about enhanced structural stability. Moreover, redox activity improvement binding energy are further revealed theoretical calculations. The as‐optimized considerable capacity 139.6 mAh g −1 remarkable retention 94% at 1.0 C. Even 5.0 C, its could be kept ≈80.8% after 150 loops. Given this, this work expected provide guidance for NCM regenerations, meanwhile offering an in‐depth understanding morphology/lattice reconstruction.

Language: Английский

Citations

0
Understanding the electrochemical decomposition of Li2CO3 artificial interface layer on Li-rich layered cathodes for cycle stability DOI
Zhou Zhou,

Yongchun Zhu,

Zhaoping Liu

et al.

Journal of Power Sources, Journal Year: 2025, Volume and Issue: 631, P. 236317 - 236317

Published: Jan. 25, 2025

Language: Английский

Citations

0
Low-Temperature Synthesis of Amorphous Lif/Li3bo3 Interfaces with F, B Co-Doped Subsurface for Long-Cycling and High-Rate Ni-Rich Cathodes DOI
Guangchang Yang, Bin Liu, Feiyan Lai

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0
Countering voltage fade and capacity decay of Li-rich layered oxides endowed by a hydridoaluminate additive DOI
Shujun Qiu,

Longde Duan,

Errui Wang

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 179885 - 179885

Published: March 1, 2025

Language: Английский

Citations

0
Universal Single Atom Engineering Enhances Coulombic Efficiency of Ion Storage in Carbon Materials DOI Open Access
Tiantian Wang, Xuliang Deng, Wei Shao

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: March 27, 2025

Metal single atoms are widely used to optimize the microstructure of carbon materials improve their ion storage capacity and rate performance, but impact on another key parameter, Coulombic efficiency (CE), is not sufficiently addressed confirmed. Herein, a universal phenomenon reported that carbon-loaded asymmetric sulfur-modified metal-N4 moiety (MN4-S, M = Zn, Fe, Cu, Ni) possesses higher CE than symmetric MN4 moiety, this applicable various matrices, ions (Li+, Na+, K+), charge discharge rates, electrolyte formulations. The MN4-S exhibits larger CEs (0.03-0.46% average CEs, 4.2-28.4% initial CEs) smaller variance compared implying better reversible stability. mechanism driving revealed by ZnN4-S sodium process. coordination promotes rapid diffusion kinetics changing density. Meanwhile, can reduce adsorption energy regulate surface chemical reactivity material increase reversibility storage, thereby achieving

Language: Английский

Citations

0
Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries DOI

L. W. Song,

Haoyan Liang,

Shunqing Li

et al.

Acta Physico-Chimica Sinica, Journal Year: 2025, Volume and Issue: unknown, P. 100085 - 100085

Published: April 1, 2025

Language: Английский

Citations

0
Low-Temperature Synthesis of Amorphous LiF/Li₃BO₃ Interfaces with F, B Co-Doped Subsurface for Long-Cycling and High-Rate Ni-Rich Cathodes DOI
Guangchang Yang, Bin Liu, Feiyan Lai

et al.

Nano Energy, Journal Year: 2025, Volume and Issue: unknown, P. 111009 - 111009

Published: April 1, 2025

Language: Английский

Citations

0
Oxygen Vacancy Engineering for High-Performance Li-Rich Manganese Cathodes: Advances and Prospects DOI Creative Commons

Pengzu Kou,

Lei Zhang,

Zhigui Zhang

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104321 - 104321

Published: May 1, 2025

Language: Английский

Citations

0