Chemical Communications,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
Smart
aqueous
two-phase
systems
(ATPSs)
were
fabricated
using
ferrocenyl
and
benzyl-modified
poly(ionic
liquid)s
for
the
first
time.
The
novel
ATPSs
found
to
be
pH-sensitive.
upper
phase
lower
could
inverted
reversibly
by
adjusting
pH
value
of
ATPSs.
Advances in Colloid and Interface Science,
Journal Year:
2024,
Volume and Issue:
331, P. 103242 - 103242
Published: June 24, 2024
Proteins
in
ionic
liquids
(ILs)
and
deep
eutectic
solvents
(DESs)
have
gained
significant
attention
due
to
their
potential
applications
various
fields,
including
biocatalysis,
bioseparation,
biomolecular
delivery,
structural
biology.
Scattering
approaches
dynamic
light
scattering
(DLS)
small-angle
X-ray
neutron
(SAXS
SANS)
been
used
understand
the
solution
behavior
of
proteins
at
nanoscale
microscale.
This
review
provides
a
thorough
exploration
application
these
techniques
elucidate
protein
properties
ILs
DESs.
Specifically,
begins
with
theoretical
foundations
relevant
describes
essential
solvent
DESs
linked
such
as
refractive
index,
length
density,
ion-pairs,
liquid
nanostructure,
aggregation,
specific
ion
effects.
Next,
detailed
introduction
is
provided
on
type,
concentration,
size,
flexibility
structure
observed
through
methodologies.
followed
by
literature
use
for
It
highlighted
that
enhanced
data
analysis
modeling
tools
are
necessary
assessing
structure,
understanding
hydration,
aggregation
also
noted
complementary
recommended
comprehensively
complex
interplay
factors,
ion-binding,
intermolecular
interactions,
Finally,
challenges
research
directions
this
field
proposed,
experimental
design,
approaches,
supporting
methods
obtain
fundamental
understandings
systems
solution.
We
envisage
will
support
further
studies
interface
science,
particular
effects
proteins.
Journal of Materials Chemistry B,
Journal Year:
2024,
Volume and Issue:
12(38), P. 9478 - 9507
Published: Jan. 1, 2024
Wound
infections,
marked
by
the
proliferation
of
microorganisms
at
surgical
sites,
necessitate
development
innovative
wound
dressings
with
potent
bactericidal
properties
to
curb
microbial
growth
and
prevent
bacterial
infiltration.
This
study
explores
recent
strides
in
utilizing
ionic
liquid-based
polymers
as
highly
promising
antimicrobial
agents
for
advanced
healing
applications.
Specifically,
cationic
containing
quaternary
ammonium,
imidazolium,
guanidinium,
pyridinium,
triazolium,
or
phosphonium
groups
have
emerged
exceptionally
effective
compounds.
Their
mechanism
action
involves
disrupting
membranes,
thereby
preventing
resistance
minimizing
toxicity
mammalian
cells.
comprehensive
review
not
only
elucidates
intricate
dynamics
skin's
immune
response
various
stages
but
also
delves
into
synthesis
methodologies
polymers.
By
spotlighting
practical
applications
dressings,
particularly
those
incorporating
materials,
this
aims
lay
groundwork
future
research
endeavors
burgeoning
field.
Through
a
nuanced
examination
these
advancements,
article
seeks
contribute
ongoing
progress
developing
cutting-edge
platforms
that
can
effectively
address
challenges
posed
infections
wounds.
Macromolecular Rapid Communications,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 2, 2025
Polymer
gel-based
ionic
thermoelectric
(i-TE)
devices,
including
thermally
chargeable
capacitors
and
thermogalvanic
cells,
represent
an
innovative
approach
to
sustainable
energy
harvesting
by
converting
waste
heat
into
electricity.
This
review
provides
a
comprehensive
overview
of
recent
advancements
in
i-TE
materials,
focusing
on
their
Seebeck
coefficients,
the
mechanisms
underlying
thermodiffusion
effects,
various
strategies
employed
enhance
performance.
Gel-based
materials
show
great
promise
due
flexibility,
low
cost,
suitability
for
flexible
wearable
devices.
However,
challenges
such
as
improving
conductivity
stability
redox
couples
remain.
Future
directions
include
enhancing
efficiency
ionic-electronic
coupling
developing
more
robust
electrode
optimize
conversion
real-world
applications.