Tailoring the Porous Structure of Carbon for Enhanced Oxidative Cleavage and Esterification of C(CO)‐C Bonds DOI
Chao Xie,

Qidong Hou,

Hengli Qian

et al.

ChemSusChem, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 30, 2024

Abstract The cleavage and functionalization of carbon‐carbon bonds are crucial for the reconstruction upgrading organic matrices, particularly in valorization biomass, plastics, fossil resources. However, inherent kinetic inertness thermodynamic stability C‐C σ make this process challenging. Herein, we fabricated a glucose‐derived defect‐rich hierarchical porous carbon as heterogeneous catalyst oxidative esterification C(CO)‐C bonds. Systematic investigations revealed that structure enhances adsorption O 2 ketones, thereby boosting catalytic efficiency defects. This exhibits performance comparable to reported nitrogen‐doped or metal nanoparticle‐supported materials, well transition metal‐based homogeneous systems. work deepens our understanding reaction underlying transformation provides insights designing efficient carbon‐based materials transformations.

Language: Английский

Mechanically strong, reprocessable and chemically recyclable furan-based poly(acylhydrazone)s materials with hydrogen-bonding networks DOI
Xiaowei Li,

Chilong Liu,

Xiangchun Quan

et al.

European Polymer Journal, Journal Year: 2024, Volume and Issue: 221, P. 113584 - 113584

Published: Nov. 15, 2024

Language: Английский

Citations

1
Tailoring the Porous Structure of Carbon for Enhanced Oxidative Cleavage and Esterification of C(CO)‐C Bonds DOI
Chao Xie,

Qidong Hou,

Hengli Qian

et al.

ChemSusChem, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 30, 2024

Abstract The cleavage and functionalization of carbon‐carbon bonds are crucial for the reconstruction upgrading organic matrices, particularly in valorization biomass, plastics, fossil resources. However, inherent kinetic inertness thermodynamic stability C‐C σ make this process challenging. Herein, we fabricated a glucose‐derived defect‐rich hierarchical porous carbon as heterogeneous catalyst oxidative esterification C(CO)‐C bonds. Systematic investigations revealed that structure enhances adsorption O 2 ketones, thereby boosting catalytic efficiency defects. This exhibits performance comparable to reported nitrogen‐doped or metal nanoparticle‐supported materials, well transition metal‐based homogeneous systems. work deepens our understanding reaction underlying transformation provides insights designing efficient carbon‐based materials transformations.

Language: Английский

Citations

0