ChemPlusChem, Journal Year: 2025, Volume and Issue: unknown

Published: May 12, 2025

The growing reliance on nuclear energy necessitates efficient strategies for managing spent fuel, particularly the capture of volatile radioactive iodine, which poses significant environmental and health risks. Crystalline porous materials have emerged as promising candidates iodine adsorption due to their high surface areas, tunable porosity, abundant active sites. This review comprehensively summarizes recent advancements in design application four classes crystalline capture: metal‐organic frameworks, covalent organic hydrogen‐bonded cages. discussion focuses key mechanisms, structural modifications, functionalization that enhance capacity, retention, recyclability. While progress has been made, challenges remain scaling up synthesis, improving stability under industrial conditions, achieving cost‐effective large‐scale applications. Future research should emphasize scalable validation, development multifunctional adsorbents with enhanced selectivity reusability. provides insights into rational next‐generation capture, contributing waste management sustainability.

Language: Английский