Strategic facet engineering of bismuth‐based photocatalysts for the applications in solar‐to‐chemical conversion DOI Creative Commons

Joel Jie Foo,

Zi‐Jing Chiah,

Sue‐Faye Ng

et al.

InfoScience., Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 5, 2024

Abstract Semiconductor photocatalysis is a promising tactic to simultaneously overcome global warming and the energy crisis as it can directly convert inexhaustible solar into clean fuels valuable chemicals, hence being employed in various applications. However, current performance of largely impeded by fast recombination photogenerated charge carriers insufficient light absorption. Among materials, bismuth‐based photocatalysts have stood out excellent candidates for efficient due their unique controllable crystal structures relatively narrow band gap. These features endow selective exposure active facets (facet engineering) wide absorption range, resulting tunable photocatalytic activity, selectivity, stability. Therefore, great potential use facet‐engineered applications (e.g., water splitting, CO 2 reduction, N fixation, H O production) achieve sustainable development. Herein, introduction provides overview this research, while synthesis, modification strategy, latest progress application were summarized highlighted review paper. Lastly, conclusion outlooks topic concluded give some insights direction focus future research.

Language: Английский

In Situ Construction of Fuzzy Sea‐Urchin ZnIn2S4/W18O49: Leveraging Interfacial Z‐Scheme Redox Sites toward Cooperative Electron–Hole Utilization in Photocatalysis DOI
Grayson Zhi Sheng Ling, Steven Hao Wan Kok,

Peipei Zhang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 9, 2024

Abstract Despite the significant milestones in half‐reduction process of photocatalysis, challenges remain fully utilizing electron–hole pairs simultaneous redox reactions. Herein, a Z‐scheme ZnIn 2 S 4 /W 18 O 49 (ZW) hybrid with complementary band edge potential is situ constructed. The resultant fuzzy 1D‐assembled sea‐urchin photocatalyst demonstrates an optimal H and benzaldehyde yield 122 106 µmol h −1 under λ > 420 nm light irradiation. This sacrificial‐agent‐free system entails solar‐to‐hydrogen (STH) apparent quantum efficiency (AQE) values 0.466% 2.48% (420 nm), respectively, surpassing most recently reported photocatalytic systems without aid noble metal cocatalysts. outstanding performance mainly attributed to synergistic formation intimate heterojunction induction localized surface plasmon resonances. Comprehensive characterization studies prove direct injection energetic hot electrons promote number long‐lived active electrons. Besides, electron paramagnetic resonance scavenger tests clarify complicated mechanistic puzzle dual‐redox reaction, where formed dominantly via O─H activation followed by C─H cleavage benzyl alcohol over ZW hybrid. Lastly, universal use composites testified various systems. study offers novel outlook for designing dual‐functioning heterojunctions toward feasible photoredox application.

Language: Английский

Citations

4
Recent advancements in metal-free nitrides based single-atom catalysts: Nanoarchitectonics and applications DOI Creative Commons

P.A. Aleena,

Gurwinder Singh, Devthade Vidyasagar

et al.

Progress in Materials Science, Journal Year: 2025, Volume and Issue: unknown, P. 101490 - 101490

Published: April 1, 2025

Language: Английский

Citations

0
Synergistic potassium intercalation and cyano group modification on crystalline carbon nitride homojunction towards dual-functional photoredox coupling of H2O2 and benzaldehyde production DOI

Joel Jie Foo,

Sue‐Faye Ng, Steven Hao Wan Kok

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 158992 - 158992

Published: Dec. 1, 2024

Language: Английский

Citations

3
Strategic facet engineering of bismuth‐based photocatalysts for the applications in solar‐to‐chemical conversion DOI Creative Commons

Joel Jie Foo,

Zi‐Jing Chiah,

Sue‐Faye Ng

et al.

InfoScience., Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 5, 2024

Abstract Semiconductor photocatalysis is a promising tactic to simultaneously overcome global warming and the energy crisis as it can directly convert inexhaustible solar into clean fuels valuable chemicals, hence being employed in various applications. However, current performance of largely impeded by fast recombination photogenerated charge carriers insufficient light absorption. Among materials, bismuth‐based photocatalysts have stood out excellent candidates for efficient due their unique controllable crystal structures relatively narrow band gap. These features endow selective exposure active facets (facet engineering) wide absorption range, resulting tunable photocatalytic activity, selectivity, stability. Therefore, great potential use facet‐engineered applications (e.g., water splitting, CO 2 reduction, N fixation, H O production) achieve sustainable development. Herein, introduction provides overview this research, while synthesis, modification strategy, latest progress application were summarized highlighted review paper. Lastly, conclusion outlooks topic concluded give some insights direction focus future research.

Language: Английский

Citations

2