Hi-Catalyzed Intermolecular Hydroarylation of Alkenyl Alcohols with Indole Nucleophiles to Access C3-Benzylated Indole Derivatives
Published: Jan. 1, 2025
Language: Английский
I2-Induced Metal-Free C(sp2)–H Functionalization of Indoles via One-Pot and Two-Step Reaction with 1-(2-Hydroxyphenyl)-propargyl Alcohols: Access to 3-(Benzofuran-3-yl)-1H-indoles
Yang Zhu,
No information about this author
Guisheng Deng
No information about this author
The Journal of Organic Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 3, 2025
The
I2-catalyzed
reaction
of
1-(2-hydroxyphenyl)-propargyl
alcohols
with
indoles
and
subsequent
treatment
K2CO3
provided
(benzofuran-3-yl)-1H-indoles
in
good
to
excellent
yields
high
regioselectivity.
This
one-pot
two-step
strategy
proved
be
suitable
for
a
wide
range
substrates
except
aliphatic
alkynyl
as
well
the
bearing
N-protected
groups
such
Ts
group
possessing
strong
electron-withdrawing
feature.
procedure
involved
cross-coupling
construction
benzofuran
framework
via
5-exo-dig
cyclization.
Language: Английский
HI-Catalyzed Intermolecular Hydroarylation of Alkenyl Alcohols with Indole Nucleophiles to Access C3-Benzylated Indole Derivatives
Tetrahedron,
Journal Year:
2025,
Volume and Issue:
unknown, P. 134699 - 134699
Published: May 1, 2025
Language: Английский
Advances in Self-Organized Total Synthesis of Natural Products
Chemical Communications,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
In
this
review,
we
account
for
the
definition,
delimitation,
and
categorization
of
self-organized
total
synthesis
then
elucidate
a
comprehensive
understanding
synthetic
strategy
based
on
our
intensive
explorations.
Language: Английский
A new synthesis of indolo[2,3-b]quinolines from 3-acetyl-N-alkyl-2-chloroindoles with 2-aminobenzophenone
Hong Zhang,
No information about this author
Yunhe Jiang,
No information about this author
Xiao‐Xue Sun
No information about this author
et al.
RSC Advances,
Journal Year:
2024,
Volume and Issue:
14(42), P. 30707 - 30712
Published: Jan. 1, 2024
A
new
synthesis
of
N
-alkyl-
and
11-phenyl-modified
indolo[2,3-
b
]quinolines
was
achieved
via
PEG-400-promoted
visible
light-induced
one-step
reaction
3-acetyl-
-alkyl-2-chloroindoles
with
2-aminobenzophenone
in
40%
methanol
aqueous
solution.
Language: Английский