The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 21, 2024

The first deoxygenative hydrosilylation of ketones promoted by samarium diiodide and has been reported. In this approach, secondary alkyl silanes are synthesized from unactivated chlorosilanes in one step. carbonyl group is activated SmI2-mediated single-electron transfer process, which follows a elimination O=Sm. Broad substrate scope excellent functional tolerance demonstrated.

Language: Английский