Halogenated Anils of Sulfanilamide: Structural, Hirshfeld, and Optical Studies DOI

Aadil A. Ahangar,

Asif A. Malik,

Shamim Ahmad

et al.

ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(46)

Published: Dec. 1, 2024

Abstract Chemistry of functional organic materials is interesting in terms design and applications. Halogen functionalization molecules intriguing as besides affecting the intramolecular electronic properties, their presence triggers intermolecular halogen bonds, both packing bulk properties. We report rationally substituted halogenated anils sulfanilamide 1–3 to understand influence halogens on molecular The products 1 2 exhibit thermal stability beyond 300 ⁰C, whereas 3 undergoes early weight loss, indicating lattice solvent. phase purity has been confirmed with powder X‐ray analyses. Products have further characterized through single‐crystal diffraction studies crystal support from Hirshfeld studies. X⋯O interactions are predominant significant interhalogen X⋯X observed only . feebly emissive solid‐state. Interestingly, thin film forms undergo emission quenching, exhibits augmented emission. AIE active anil used for sensing explosive aromatic compound like picric acid.

Language: Английский

N,N-Dimethylbenzylamine as a Coformer for 3 Crystalline Organic Salts: Preparation, Spectral, Structural Investigation, Synthons Diversity and Hirshfeld Surface Analysis DOI
Rui Gao, Shouwen Jin, Zhaozhi Li

et al.

Journal of Chemical Crystallography, Journal Year: 2025, Volume and Issue: unknown

Published: April 23, 2025

Language: Английский

Citations

0
Halogenated Anils of Sulfanilamide: Structural, Hirshfeld, and Optical Studies DOI

Aadil A. Ahangar,

Asif A. Malik,

Shamim Ahmad

et al.

ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(46)

Published: Dec. 1, 2024

Abstract Chemistry of functional organic materials is interesting in terms design and applications. Halogen functionalization molecules intriguing as besides affecting the intramolecular electronic properties, their presence triggers intermolecular halogen bonds, both packing bulk properties. We report rationally substituted halogenated anils sulfanilamide 1–3 to understand influence halogens on molecular The products 1 2 exhibit thermal stability beyond 300 ⁰C, whereas 3 undergoes early weight loss, indicating lattice solvent. phase purity has been confirmed with powder X‐ray analyses. Products have further characterized through single‐crystal diffraction studies crystal support from Hirshfeld studies. X⋯O interactions are predominant significant interhalogen X⋯X observed only . feebly emissive solid‐state. Interestingly, thin film forms undergo emission quenching, exhibits augmented emission. AIE active anil used for sensing explosive aromatic compound like picric acid.

Language: Английский

Citations

0