Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 178351 - 178351
Published: Dec. 1, 2024
Language: Английский
Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 178351 - 178351
Published: Dec. 1, 2024
Language: Английский
Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 689, P. 137204 - 137204
Published: March 1, 2025
Language: Английский
Citations
0ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: May 5, 2025
This study presents a series of 1-Tb/CdS binary heterojunctions, synthesized by combining 1-Tb (a Co3+-Tb3+-based supramolecular complex) and CdS in various weight ratios via solvothermal process. These heterojunctions have been thoroughly characterized to elucidate their chemical, structural, optoelectronic properties. The catalytic effectiveness these was evaluated with respect the hydrogen evolution reaction (HER), spanning photocatalytic, electrocatalytic, photoelectrocatalytic processes. Significantly outperforming individual photocatalysts (CdS 1-Tb) other heterostructures, 7.5-1-Tb/CdS heterojunction exhibited highest HER efficiency. exceptional performance is attributed synergistic integration CdS, enabling highly efficient Z-scheme heterojunction. unique architecture enhances charge separation transfer leveraging complementary electronic properties semiconductors while minimizing recombination losses. X-ray photoelectron spectroscopy, band structure analysis, photoluminescence, electrochemical impedance spectroscopy further validated mechanism, highlighting optimal alignment energy levels. Overall, this highlights potential as robust catalysts for HER. simplicity synthesis process, coupled activity, offers significant advancement clean technologies, paving way sustainable production.
Language: Английский
Citations
0Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 526, P. 216351 - 216351
Published: Nov. 27, 2024
Language: Английский
Citations
2ChemSusChem, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 13, 2024
Abstract Poly(heptazine imide) (PHI) has received widely interest in the photocatalytic CO 2 reduction due to its good crystallinity and complete in‐plane structure. However, poor photo‐induced carrier separation migration efficiency insufficient active sites results undesirable performance. Herein, we designed constructed a novel ohmic junction photocatalyst by integrating melamine edge‐modified PHI (mel‐PHI) with extended π‐conjugated system TiN (TiN/mel‐PHI) for enhancing activity. Strikingly, yield of optimal TiN/mel‐PHI is 62.64 μmol g −1 h , which 5.6 2.8 times higher than (11.26 ) mel‐PHI (22.32 ), respectively. The superior activity attributed not only formation D‐A structure introduction melamine, extends π‐conjugation system, alters electronic PHI, accelerates charge migration, but also induced internal electric field further enhances efficiency. Meanwhile, synergistic effect enriched electron number TiN, reducing potential. This work highlights enhancement transfer between motifs junctions, confirming their potential optimizing photocatalysts.
Language: Английский
Citations
1Fuel, Journal Year: 2024, Volume and Issue: 385, P. 134102 - 134102
Published: Dec. 14, 2024
Language: Английский
Citations
0Acta Physico-Chimica Sinica, Journal Year: 2024, Volume and Issue: unknown, P. 100039 - 100039
Published: Dec. 1, 2024
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 683, P. 546 - 554
Published: Dec. 26, 2024
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 178351 - 178351
Published: Dec. 1, 2024
Language: Английский
Citations
0