ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 3, 2024
Language: Английский
ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 3, 2024
Language: Английский
Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 129692 - 129692
Published: Sept. 1, 2024
Language: Английский
Citations
4ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 28, 2025
The upsurging of cost-effective de novo electrocatalysts through the operando electro-oxidation approaches holds great promise for scalable production green energy in pursuit sustainability. This work introduces an reconstitution strategy producing a smart electrocatalyst, cobalt "oxyhydroxide" derived from newly designed 2D cobalt(II) metal–organic framework (NBU-4) directly grown on nickel foam (NF), NBU-4/NF@CoOOH. NBU-4/NF@CoOOH, exhibits outstanding overpotential 76 mV hydrogen evolution reaction and 336 oxygen to achieve current density 10 mA/cm2 with remarkable Faradaic efficiencies 97.1 93.4%, respectively, 1 M aqueous KOH. Unveiling bifunctionality NBU-4/NF@CoOOH as cathode anode overall water splitting KOH, low voltage 1.65 V was needed obtain density. Nonetheless, displayed excellent stability 12 h evidenced chronopotentiometry recorded at mA/cm2. bifunctional electrocatalytic performance electrocatalyst 50 is attributed unique hexagonal nanosheet morphology microporous structure zigzag flow channels NF, facilitating faster kinetics Co3+ Ni2+ dual sites synergism.
Language: Английский
Citations
0Crystals, Journal Year: 2025, Volume and Issue: 15(4), P. 345 - 345
Published: April 6, 2025
This study aims to determine the electrochemical performance of FeWO4 (Fe), NiFeOOH (Ni), and FeWO4/NiFeOOH (FeNi) electrodes in 0.1 M Na2SO4 NaOH electrolytes, highlighting impact SO42− OH− ions. Nyquist analysis demonstrated that electrode had lowest charge transfer resistance, indicating superior transport capacitive over individual electrodes. In Na2SO4, ions stabilized double-layer capacitance enhance ionic mobility. Conversely, NaOH, highly conductive mobile significantly improved diffusion, making more effective for applications. Tafel revealed better kinetics greater energy efficiency with composite excelling both electrolytes. Linear voltammetry showed a synergistic interaction between NiFeOOH, achieving photocurrent density 6.70 mA·cm−2 under illumination, an 830.56% increase Na2SO4. Additionally, exhibited longer electron lifetimes than attributed smaller radius higher diffusion coefficient Pulsed notable improvements generation stability NaOH. These findings indicate is efficient stable material advanced technologies, providing optimal conditions.
Language: Английский
Citations
0ACS Applied Nano Materials, Journal Year: 2025, Volume and Issue: unknown
Published: April 18, 2025
Language: Английский
Citations
0The Chemical Record, Journal Year: 2025, Volume and Issue: unknown
Published: April 24, 2025
Abstract Metal‐organic frameworks (MOFs) and their derivatives have shown broad application prospects in fields such as water electrolysis, electrochemical energy storage, sensing due to high specific surface area, tunable structures, abundant active sites. This article provides a comprehensive overview of our research group′s recent advancements developing MOF‐based electrocatalysts for Oxygen Evolution Reaction (OER) Urea Oxidation (UOR) at anodes, well Hydrogen (HER) cathodes during electrolysis. Furthermore, we integrated these catalysts into practical applications, including metal‐air batteries, lithium‐sulfur non‐enzymatic glucose sensors. To further demonstrate the innovative contributions work, systematically compare it with advanced work by other groups. Based on findings performance benchmarking analyses, identify critical challenges that must be addressed advance MOFs‐based toward next‐generation conversion sensing.
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 180729 - 180729
Published: May 1, 2025
Language: Английский
Citations
0ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 3, 2024
Language: Английский
Citations
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