Synthesis of sulfonated naphthols via metal-free oxidative coupling of beta-tetralone and sodium sulfinates DOI

Saiwen Liu,

H. Xiao, Jin Zhang

et al.

Tetrahedron Letters, Journal Year: 2024, Volume and Issue: 148, P. 155209 - 155209

Published: Aug. 3, 2024

Language: Английский

Electrochemical Sulfonylation/Cyclization of N-Alkenylacrylamides with Sodium Sulfinates or Sulfonyl Hydrazides DOI
Zhixian Yang,

Lu-Cai Ding,

Gui-Hong Yang

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(15), P. 10660 - 10677

Published: July 18, 2024

Two general protocols for the regioselective electrochemically enabled sulfonylation cyclization of

Language: Английский

Citations

8
Controlled and Site-Selective C–H/N–H Alkenylation, Dialkenylation, and Dehydrogenative β-Alkenylation of Various N-Heterocycles DOI
Yan Jin,

Suijie Zhong,

Chen Xu

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(7), P. 4840 - 4850

Published: March 19, 2024

Here, we report controlled and site-selective C–H alkenylation dialkenylation of indolizines pyrrolo[1,2-a]quinolines with β-alkoxyvinyl trifluoromethylketones under simple practical conditions. Moreover, this direct strategy can also be extended to imidazo[1,2-a]pyridines. Notably, without a transition metal external oxidant, efficient dehydrogenative β-alkenylation tertiary amines is presented.

Language: Английский

Citations

5
Recent Advances on Direct Phosphorothiolation Reactions DOI

Haifa Zheng,

Ju Peng,

Xiang Liu

et al.

Advanced Synthesis & Catalysis, Journal Year: 2024, Volume and Issue: unknown

Published: July 23, 2024

Abstract Organophosphorothioates are organic molecules containing sulfur and phosphorus, with significant biological activity physicochemical properties, widely used in synthesis, medicinal chemistry, the agrochemical industry. In particular, many phosphorothioates display a variety of activities, such as antifungal, antibacterial, anti‐parasite, anticancer, so on. Traditionally, synthesis has mainly relied on indirect methods involving construction S−P bond. recent years, direct phosphorothiolation gained attention reliable rapid method for introducing −S−P(O)(OR) 2 group into parent molecules. This article reviews latest advances reactions, categorized based different sources group.

Language: Английский

Citations

2
Electrochemical Synthesis of Vinyl, Alkyl, and Allyl Sulfones from Sodium Sulfinates and Olefins DOI

Pengkai Fang,

Qingxu Wang,

Xiaoqian Shen

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(17), P. 12619 - 12627

Published: Aug. 16, 2024

An electrochemical synthesis of vinyl, alkyl, and allyl sulfones using sodium sulfinates olefins was reported. This method uses direct current to pass through an undivided cell equipped with graphite carbon electrodes, a series diverse sulfone compounds can be synthesized at room temperature in high yields.

Language: Английский

Citations

2
Recent Advances on the Construction of Functionalized Indolizine and Imidazo[1,2‐a]pyridine Derivatives DOI
Xiang Liu,

Haifeng Fu,

Qi Hu

et al.

The Chemical Record, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 22, 2024

Abstract Indolizines and imidazo[1,2‐ a ]pyridines are commonly found in natural products, synthetic drugs, bioactive molecules. These two types of derivatives possess good antibacterial, antiparasitic, anticancer activities, so on. The functionalization indolizines has always been hot topic organic chemistry research made significant progress. In recent years, our group dedicated to developing diverse methods for the preparation such important compounds. 1) We have developed C−H reactions efficient modification parent ]pyridines. 2) A variety cycloaddition were established construction indolizine ]pyridine from simple raw materials. 3) intriguing deconstruction‐functionalization indolizines, enabling reorganization heterocyclic frameworks. This paper outlines group's latest advancements constructing structurally derivatives. hope that this work will offer valuable insights inspiration ongoing field N‐heterocyclic

Language: Английский

Citations

1
Synthesis of N-Benzylidene Benzylamine from Dibenzylamine and Derivatization under Electrochemical Conditions DOI

Yunusi Reziguli,

Abuduwaili Kadierya,

Shi‐Wei Luo

et al.

Acta Chimica Sinica, Journal Year: 2024, Volume and Issue: 82(8), P. 843 - 843

Published: Jan. 1, 2024

Language: Английский

Citations

0
Synthesis of sulfonated naphthols via metal-free oxidative coupling of beta-tetralone and sodium sulfinates DOI

Saiwen Liu,

H. Xiao, Jin Zhang

et al.

Tetrahedron Letters, Journal Year: 2024, Volume and Issue: 148, P. 155209 - 155209

Published: Aug. 3, 2024

Language: Английский

Citations

0