Mechano-driven chemical reactions

Green Energy & Environment, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 1, 2024

Traditional chemical processes often generate substantial waste, leading to significant pollution of water, air, and soil. Developing eco-friendly methods is crucial for economic environmental sustainability. Mechano-driven chemistry, with its potential material recyclability minimal byproducts, well-aligned green chemistry principles. Despite origins over 2000 years ago nearly 200 scientific investigation, mechano-driven has not been widely implemented in practice. This likely due a lack comprehensive understanding the complex physical effects mechanical forces, which challenge reaction efficiency scalability. review summarizes historical development discusses progress across various mechanisms, including mechanochemistry, tribochemistry, piezochemistry, contact electrification (CE) chemistry. CE-induced reactions, involving ion transfer, electron radical generation, are detailed, emphasizing dominant role radicals initiated by transfer influence through electrical double layer (EDL) formation. Advancing efficient, eco-friendly, controllable technologies can reduce reliance on traditional energy sources (such as electricity heat) toxic reagents, fostering innovation synthesis, catalytic technologies, establishing new paradigm broader applications.

Language: Английский

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Mechanochemical synthesis and catalysis of dinuclear Cu (II) complexes in C–S coupling

Applied Organometallic Chemistry, Journal Year: 2024, Volume and Issue: 38(11)

Published: July 25, 2024

This study introduces a mechanochemical approach for synthesizing dinuclear Cu (II) complexes and applying them directly in C – S coupling reactions, offering sustainable alternative to traditional solvent‐based syntheses. The method, recognized its environmental advantages efficiency, was employed synthesize the complex [CuL(μ‐Cl)Cl 2 ] ( I ) metal–organic salt 2L . 2[CuCl 4 2− II ), thereby minimizing solvent use waste production. synthesized exhibited superior catalytic activity coupling, achieving 96% yield within 20 min with methanol serving as grinding medium. process further refined confirmed sustainability, an E‐factor of 0.460 EcoScale score 78. synthetic method not only shortens reaction times reduces but also streamlines operational procedure, providing more environmentally benign economically viable route coupling. research highlights potential mechanochemistry simplifying processes enhancing their paving way future advancements green strategies.

Language: Английский

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Mechanochemical Cascade Synthesis of Zinc Complexes for Catalytic C–S Coupling in One-Pot

Organometallics, Journal Year: 2024, Volume and Issue: 43(15), P. 1640 - 1646

Published: July 13, 2024

Language: Английский

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Recent Advances in Visible Light Photocatalytic and Transition Metal-Catalyzed Synthesis of Disulfide Compounds

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Reviewing photocatalytic and metal-catalyzed disulfide synthesis, 2021–2024, emphasizes efficiency, selectivity, sustainability for drug material science.

Language: Английский

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Mechanochemistry Enabled Friedel-Crafts Alkylation Reactions of Donor-Acceptor Cyclopropanes with 2-Indolymethanols

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(11), P. 3437 - 3437

Published: Jan. 1, 2024

Language: Английский

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