Chemoselective C(sp2)–C(sp2) doubly decarbonylative cross-electrophile coupling enabled by palladium catalysis: Reaction development and mechanism studies

Journal of Catalysis, Journal Year: 2024, Volume and Issue: 437, P. 115671 - 115671

Published: July 26, 2024

Language: Английский

Nickel-Catalyzed Cross-Coupling of Aziridines with Thioesters toward Atom-Economic Synthesis of β-Sulfanyl Amides

Organic Letters, Journal Year: 2024, Volume and Issue: 26(40), P. 8457 - 8462

Published: Sept. 27, 2024

Thioesters have been recognized as a class of powerful bifunctional reagents, namely, great donors acyl and sulfide moieties. However, such application in value-added synthesis is still very limited to date. Herein, nickel-catalyzed cross-coupling reaction system aziridines with thioesters was developed under redox-neutral mild conditions. This catalytic method provides an atom-economic route for the diverse β-sulfanyl amide derivatives wide substrate scope (43 examples), good functional group tolerance, regioselectivity.

Language: Английский

Synthesis of allenones via nickel-catalyzed reductive coupling of propargyl esters with acyl chlorides

Tetrahedron Chem, Journal Year: 2024, Volume and Issue: unknown, P. 100113 - 100113

Published: Nov. 1, 2024

Language: Английский