Enhanced Circularly Polarized Luminescence of Urea-Bridged Dimers of Axially Chiral BODIPY–Carbohydrate Hybrids DOI
Ana M. Gómez, Arthur H. G. David, Araceli G. Campaña

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(24), P. 18522 - 18528

Published: Dec. 9, 2024

Herein, we report the synthesis of novel dimeric urea-bridged BODIPY-carbohydrate conjugates, which display circularly polarized luminescence (CPL). The dimers are composed diastereomerically pure, axially chiral (P or M) BODIPY monomers containing a pendant glucose (d- l-) unit. latter was intended to add chirality, biocompatibility, and enhanced water solubility facilitate chromatographic resolution intermediate atropisomers. dimerization process based on ureation reaction azidomethyl BODIPYs. rigorous structural assignment possible by X-ray diffraction analysis one

Language: Английский

Enhanced Circularly Polarized Luminescence of Urea-Bridged Dimers of Axially Chiral BODIPY–Carbohydrate Hybrids DOI
Ana M. Gómez, Arthur H. G. David, Araceli G. Campaña

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(24), P. 18522 - 18528

Published: Dec. 9, 2024

Herein, we report the synthesis of novel dimeric urea-bridged BODIPY-carbohydrate conjugates, which display circularly polarized luminescence (CPL). The dimers are composed diastereomerically pure, axially chiral (P or M) BODIPY monomers containing a pendant glucose (d- l-) unit. latter was intended to add chirality, biocompatibility, and enhanced water solubility facilitate chromatographic resolution intermediate atropisomers. dimerization process based on ureation reaction azidomethyl BODIPYs. rigorous structural assignment possible by X-ray diffraction analysis one

Language: Английский

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