Electrochemical and optical protocols for the detection and removal of an antibiotic drug rifaximin from wastewater DOI Creative Commons

Ifra Riffat,

Afzal Shah

RSC Advances, Journal Year: 2024, Volume and Issue: 14(32), P. 22867 - 22876

Published: Jan. 1, 2024

Improper disposal of pharmaceutical drugs is increasing the pollution level water reservoirs which in turn adversely impacts ecosystem. The current study presents an electrochemical scaffold that comprises a glassy carbon electrode modified with amino-functionalized multiwalled nanotubes (NH2-fMWCNTs) for detection drug rifaximin wastewater. Electrochemical impedance spectroscopic characterization revealed efficient charge transport through surface. Square wave voltammetry was employed probing electro-oxidation antibiotic rifaximin. Under optimized experimental conditions, designed sensor demonstrated qualities sensitivity, repeatability, and reproducibility as required practical applicability sensing device. After contaminant, its removal from imperative. In this regard adsorption method using ZnO nanoparticles adsorbents developed led to At lower adsorbate concentration, found occur according Langmuir model while at higher concentration data followed Freundlich model. rate over pseudo-second-order kinetics.

Language: Английский

Insight into the efficient removal of Cu (II) from aqueous solutions on a biochar-alginate hybrid composite DOI
Amany R. Salem,

Walaa A. Kassab,

Abeer M. Adel

et al.

Process Safety and Environmental Protection, Journal Year: 2025, Volume and Issue: unknown, P. 106985 - 106985

Published: March 1, 2025

Language: Английский

Citations

0

A novel structured graphene oxide@microalgae nanohybrids as adsorbents for removal of Cr(VI) ions in aqueous solutions DOI Creative Commons

Rolivhuwa Mulovhedzi,

Kholiswa Yokwana,

Timothy O. Ajiboye

et al.

Adsorption, Journal Year: 2025, Volume and Issue: 31(4)

Published: March 17, 2025

Language: Английский

Citations

0

Textile dye removal using diatomite nanocomposites: a metagenomic study in photosynthetic microalgae-assisted microbial fuel cells DOI Creative Commons

Anshuman Rai,

Vandana Sirotiya,

Ankesh Ahirwar

et al.

RSC Advances, Journal Year: 2025, Volume and Issue: 15(11), P. 8300 - 8314

Published: Jan. 1, 2025

In this study, Coomassie brilliant blue (CBB), green (BG), and rhodamine (Rh) dyes were used to simulate dye-rich wastewater. Adsorption degradation of these (2 μM, 10 30 μM) on diatomite (DE) evaluated under light (L) dark (D) conditions. The adsorption dye-DE composites followed pseudo-second-order kinetics at all concentrations conditions had R 2 > 0.99, thus showing a good fit. calculated equilibrium amount q e,(cal) was coherent with the value experimental e,(exp). poorest photocatalysis occurred prompting functionalization TiO2 Fe3O4 nanoparticles (NP(s)). highest dye efficiencies (DGeff) for μM 86.79% (CBB-DE-Fe3O4, 72 h), 96.10% (BG-DE-TiO2, 52 81.74% (Rh-DE-TiO2, 48 Rh-DE-TiO2 fastest degradation. Functionalized DE-dye (30 nanocomposites further tested in photosynthetic microalgae-assisted microbial fuel cell dye-simulated wastewater anode (PMA-MFC-1 CBB-DE-Fe3O4, PMA-MFC-2 BG-DE-TiO2 PMA-MFC-3 Rh-DE-TiO2) Asterarcys sp. GA4 microalgae cathode. chambers, achieved DGeff Rh as 88.23% polarization density 30.06 mW m-2, outperforming BG PMA-MFC-1 CBB dye. molecular identifier analysis microbes showed dominance Sphingobacteria Proteobacteria (Rh-DE-TiO2) COD removal 61.36%, highlighting its potential efficient bioelectricity generation. Furthermore, simultaneously demonstrated superior microalgal lipid yield 3.42 μg g-1 an algal growth 8.19

Language: Английский

Citations

0

Clean Water Production from Urban Sewage by Algae-Based Treatment Techniques, a Reflection of Case Studies DOI Open Access
Abdol Aziz Shahraki

Sustainability, Journal Year: 2025, Volume and Issue: 17(7), P. 3107 - 3107

Published: April 1, 2025

The inadequate collection and treatment of urban wastewater continue to pollute built environments, threaten public health, contribute epidemic outbreaks in many densely populated, underdeveloped regions. This study investigates whether algae-based offers an optimal efficient solution for drought-prone cities. Given recent global challenges, such as the COVID-19 pandemic, nature-based methods—particularly systems—have regained attention due their feasibility, cost-effectiveness, sustainability. Algae-based presents innovative approach sustainable development, offering environmental, resource-efficient, energy-saving, biodiversity benefits while supporting circular economy principles. evaluates advancements technologies applies a case methodology Zahedan City, analyzing sewage canal networks, composition, feasibility. Three techniques were assessed, with waste stabilization ponds (WSPs) identified most suitable based on technical, economic, environmental indicators. Key factors climate conditions, land-use policies, cost-effectiveness incorporated into comparative analysis, enhancing scientific rigor this compared prior research. findings provide actionable insights planners, engineers, policymakers address simultaneous challenges management, water scarcity.

Language: Английский

Citations

0

Preparation and Characterization of Low-Cost Bio-Sorbent and a Novel Activated Carbon from Agro-Wastes for Efficient Cr(VI) Removal DOI Creative Commons
Mehmet Erdem,

Ayşegül Öner

Water Air & Soil Pollution, Journal Year: 2025, Volume and Issue: 236(5)

Published: April 4, 2025

Language: Английский

Citations

0

The Potential to Produce Bio-Based Ammonia Adsorbents from Lignin-Rich Residues DOI Creative Commons

Daniel Chernick,

Valerie Dupont,

Andrew B. Ross

et al.

Clean Technologies, Journal Year: 2025, Volume and Issue: 7(2), P. 30 - 30

Published: April 5, 2025

The ammonia adsorption capacity of lignin-rich biomass solids was tested for the first time at low partial pressures (<1.5 kPa) and 20 °C. samples included untreated tree barks, husks, peats, as well biochars produced by their slow pyrolysis. Proximate ultimate analyses, lignin content, metal content are also presented. biosolids had higher VM/FC ratios, molar H/C, O/C than treated (biochars biochars). A novel methodology is described safe generation gaseous predictable from tabletop-scale batch reaction experiments NaOH with (NH4)2SO4 in aqueous solution, leading to determination capacities low-cost experiments. Statistically significantly larger NH3 were obtained (p < 0.001). In contrast, found be poor adsorbers without further treatment. this study’s compared those common adsorbent types same conditions using existing literature through equilibrium model interpolation (Dubinin–Astakhov, Toth, Freundlich) or cubic spline fit graphical isotherms. Controls consisting commercially sourced activated carbons (AC) capacities, close derived similar materials, confirming methodology’s robustness. biosolids’ range reported silica, gamma-alumina, some doped ACs. They performed better undoped, work suggests such barks peats competent adsorbents.

Language: Английский

Citations

0

Adsorption and ecotoxicology studies with aqueous solution of Cr(VI) ions using adsorbent materials derived from Inga edulis DOI
L. Lima,

Erica Porto Fernandes,

Andréa Novelli

et al.

Chemosphere, Journal Year: 2025, Volume and Issue: 378, P. 144378 - 144378

Published: April 10, 2025

Language: Английский

Citations

0

Natural gums-derived hydrogels for adsorptive removal of heavy metals: A review DOI

Jinhu Zhi,

Xinlu Bai, Qunyan Wang

et al.

International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: unknown, P. 143350 - 143350

Published: April 1, 2025

Language: Английский

Citations

0

Next-generation biomass nanocomposites for heavy metal ion adsorption: innovations and environmental impact DOI
Ruey‐Jen Yang,

Haiyang Lu,

Jing Zhou

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 133157 - 133157

Published: April 1, 2025

Language: Английский

Citations

0

Electrochemical Sensor for Levosulpiride Detection and Its Adsorptive Removal from Wastewater DOI Creative Commons
Mohsin Javed, Afzal Shah, Iltaf Shah

et al.

ACS Omega, Journal Year: 2025, Volume and Issue: unknown

Published: April 23, 2025

There is increasing apprehension regarding the harmful impacts of synthetic drugs, particularly antipsychotic levosulpiride. Consequently, it both an environmental and a social responsibility to create effective sensors materials for early detection removal this drug before consumption contaminated water. The goal achieved by development highly sensitive selective sensing platform, while objective polyacrylamide hydrogel. present study introduces novel combination advanced green chemistry concepts electrode modifier (functionalized MWCNTs) adsorbent (polyacrylamide hydrogel). Unlike conventional methods, where molecules slowly diffuse surface, our technique sensor preparation directly immobilizes these on electrode, leading robust electrochemical signals establishing platform with significantly reduced limit (0.7 nM). Furthermore, traditional adsorption processes may take hours or even days, unique levosulpiride demonstrates in just 45 min, as confirmed experimental findings. Results revealed that occurred accordance Langmuir model, kinetics adhered pseudo-second order kinetics. Thermodynamic parameters such negative ΔG positive ΔS spontaneous nature entropy-driven process adsorption.

Language: Английский

Citations

0