Green synthesis of ZnO nanoparticles using Justicia adhatoda for photocatalytic degradation of malachite green and reduction of 4-nitrophenol
M. B. Mahajan,
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Sanjeev Kumar,
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Jyoti Gaur
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et al.
RSC Advances,
Journal Year:
2025,
Volume and Issue:
15(4), P. 2958 - 2980
Published: Jan. 1, 2025
Achieving
the
smallest
crystallite/particle
size
of
zinc
oxide
nanoparticles
(ZnO
NPs)
reported
to
date,
measuring
5.2/12.41
nm
with
Justicia
adhatoda
(J.
adhatoda)
leaf
extract,
this
study
introduces
a
facile
green
synthesis.
Utilizing
aqueous
J.
extract
as
both
reducing
and
stabilizing
agent,
method
leverages
plant's
rich
phytochemical
composition
produce
highly
crystalline
morphologically
controlled
ZnO
NPs.
This
precise
particle
control
highlights
effectiveness
synthesis
process
in
morphological
tuning.
The
synthesized
NPs
were
thoroughly
characterized
using
XRD,
UV-vis
spectroscopy,
FTIR,
FESEM,
HRTEM,
which
collectively
revealed
superior
crystallinity,
morphology,
unique
surface
properties
conferred
by
bio-capping.
photocatalytic
performance
these
biogenic
was
evaluated
for
degradation
two
model
pollutants:
malachite
(MG),
synthetic
dye,
4-nitrophenol
(4-NP),
toxic
organic
compound.
exhibited
exceptional
efficiency,
achieving
99.8%
MG
within
180
minutes
demonstrating
rapid
reduction
4-NP
4-aminophenol
reaction
rate
constant
0.245
min-1
under
UV
sunlight
irradiation.
Mechanistic
studies
attributed
high
reactive
oxygen
species
(ROS)
generation
electron-hole
pair
interactions,
supported
improved
charge
separation
area.
work
not
only
establishes
potential
adhatoda-mediated
addressing
persistent
pollutants
but
also
sets
benchmark
size-controlled
By
delivering
scalable
eco-friendly
water
remediation
technologies,
advances
nanotechnology.
Language: Английский
Unlock Laboratory Waste Potential to Turn into Sustainable Bi-metallic Nanoparticles with Dyes Degradation and Therapeutic Activities
Selma Hamimed,
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Mohammed Zakaria Khelifati,
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Rayene Hamimed
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et al.
Journal of Inorganic and Organometallic Polymers and Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 21, 2025
Language: Английский
MXene decorated ZnO-tetrapod for efficient degradation of Methyl Orange, Methylene Blue, and Rhodamine B dyes
Sahil Jangra,
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Azam Raza,
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Bhushan Kumar
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et al.
Materials Science and Engineering B,
Journal Year:
2024,
Volume and Issue:
311, P. 117832 - 117832
Published: Nov. 16, 2024
Language: Английский
Synthesis, characterization and determination of antifungal and antioxidant activities of plant-derived zinc oxide nanoparticles
Mohee Shukla,
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Satya Narain,
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Saket Jha
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et al.
Biomass Conversion and Biorefinery,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 11, 2025
Language: Английский
A porous sponge-like TiO2/ZnO composite catalyst for photocatalytic degradation of methyl orange
Mingliang Zhang,
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Yonghong Wu,
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Yanhu Yao
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et al.
Journal of Physics and Chemistry of Solids,
Journal Year:
2025,
Volume and Issue:
204, P. 112785 - 112785
Published: April 15, 2025
Language: Английский
Green-mediated sol-gel fabrication of CuO/ZnO nanoparticles from orange peel extract for environmental remediation: Insights from X-ray diffraction analysis using various models
Dilawar Ali,
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Iqra Muneer,
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M. D. S. Pirzada
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et al.
Physica Scripta,
Journal Year:
2024,
Volume and Issue:
100(1), P. 015980 - 015980
Published: Dec. 11, 2024
Abstract
This
study
introduces
an
eco-friendly
and
simple
approach
for
synthesizing
zinc
oxide
(ZnO),
copper
(CuO),
ZnO-CuO
composite
nanoparticles
using
orange
peel
extract,
minimizing
the
use
of
harmful
chemicals
while
enhancing
their
antibacterial
photocatalytic
properties.
The
were
annealed
at
400
°C
2
h
in
air.
Characterization
was
conducted
x-ray
Diffraction
(XRD),
Dynamic
Light
Scattering,
Fourier
Transform
Infrared
Spectroscopy
(FTIR),
UV-visible
Spectroscopy.
XRD
revealed
that
ZnO
CuO
crystallized
hexagonal
wurtzite
monoclinic
structures,
respectively,
with
crystallite
size
lattice
strain
analyzed
through
Williamson–Hall,
Size-Strain
Plot,
Halder-Wagner,
Wagner-Aqua
methods.
FTIR
spectra
confirmed
presence
Zn-O
bonds,
verifying
successful
synthesis.
optical
bandgaps
measured
3.07
eV
ZnO,
2.702
CuO,
1.842
nanocomposite.
Antimicrobial
efficacy,
assessed
via
disc
diffusion
method,
showed
exhibited
enhanced
activity
against
both
gram-positive
gram-negative
strains
compared
to
individual
CuO.
Photocatalytic
experiments
demonstrated
under
sunlight,
nanocomposite
achieved
78%
degradation
10
ppm
methylene
blue
within
90
min,
outperforming
(55%)
(38%).
These
results
highlight
composite’s
potential
effective
dye
environmental
remediation
applications.
Language: Английский
Exploring the physicochemical properties and antifungal activity of zinc oxide nanoparticles
Materials Technology,
Journal Year:
2024,
Volume and Issue:
40(1)
Published: Dec. 16, 2024
In
this
study,
zinc
oxide
nanoparticles
were
synthesized
using
the
chemical
precipitation
method
with
acetate
dihydrate
and
sodium
hydroxide
as
precursors.
UV-Vis
spectroscopy
confirmed
formation
of
ZnONPs,
showing
a
characteristic
absorption
peak
at
around
360–370
nm,
corresponding
to
band
gap
energy
approximately
3.2
eV.
XRD
analysis
indicated
crystalline
nature
ZnONPs
hexagonal
wurtzite
structure.
FTIR
EDS
analyses
presence
in
component.
TEM
revealed
nearly
spherical
average
particle
sizes
26.1
nm
for
bare
24.6
PVP-capped
ZnONPs.
BET
measurements
showed
higher
specific
surface
area
The
antifungal
efficacy
was
tested
against
Phytophthora
capsici
concentrations
ranging
from
20
100
ppm.
Results
demonstrated
significant
inhibition
fungal
growth,
especially
complete
≥60
ppm
after
12
48
hours
incubation.
Language: Английский
Biocompatibility of Kaffir lime fruit juice powered ZnO nanoparticles in earthworm, Eudrilus eugeniae: A green biomimetic approach
Sampath Paventhan,
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P. Kavitha,
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T. Balasubramanian
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et al.
BioResources,
Journal Year:
2024,
Volume and Issue:
20(1), P. 1345 - 1364
Published: Dec. 11, 2024
ZnO
nanoparticles
were
synthesized
using
the
raw
juice
of
Kaffir
lime
(Citrus
hystrix)
fruit
bya
simple
and
cost-effective
green
route
its
effects
on
earthworms,
Eudrilus
eugeniae,
studied.
The
kaffir-lime
powered
(ZnO:KL)
characterized
by
X-ray
diffraction
(XRD),
UV-Vis-NIR
spectroscopy,
Fourier-transform
infrared
spectroscopy
(FT-IR),
scanning
electron
microscopy
(SEM),
transmission
(TEM).
filter
paper
method
was
adopted
to
test
toxicity
ZnO:KL.
Earthworms
(species
eugeniae)
exposed
100
1000
mg/L
ZnO:KL
in
one-step
order.
During
study
period
(up
48
h),
no
mortality
found
any
treatment
group.
In
histological
observation,
damage
epidermal
layer
earthworm’s
skin
treated
up
800
mg/L,
whereas
slight
observed
only
900
earthworms.
GC-MS
spectrum
kaffir
revealed
22
bioactive
compounds.
predominantly
identified
compounds
vitamin
C
citric
acid
subjected
molecular
docking
reveal
their
binding
affinity
with
collagen
–
a
structural
protein
providing
strength
flexibility
body.
Vitamin
bind
favorable
orientation
-4.44
kcal/mol
-4.97
kcal/mol,
respectively.
Since
are
capable
influencing
biosynthesis
collagen,
they
could
prevent
damage.
sum,
lime-powered
nanomaterial
is
less
toxic
earthworm
when
compared
bare
ZnO.
Language: Английский