Synthesis of Amine‐Functionalized Fly Ash‐Infused Polymeric Hydrogel for H2S Removal and Validation Using Molecular Dynamic Simulation DOI

Syed Farman Ali Shah,

Nurul Ekmi Rabat, Khairiraihanna Johari

et al.

Journal of Applied Polymer Science, Journal Year: 2025, Volume and Issue: unknown

Published: May 20, 2025

ABSTRACT Hydrogen sulfide (H 2 S) removal from natural gas is critical due to its toxicity and corrosive nature. Adsorption one of the most effective methods, but polymeric hydrogels often exhibit limited H S adsorption capacity. To overcome this, an amine‐functionalized fly ash (FA)‐grafted polyacrylic acid (PAA) hydrogel (FA‐ g ‐PAA) was synthesized using 5 wt.% FA via solution polymerization functionalized with 30 monoethanolamine (MEA) enhance removal. Physiochemical properties performance were evaluated Fourier‐transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) analysis, thermogravimetric analysis (TGA), X‐ray diffraction (XRD). The results confirmed successful grafting MEA into PAA matrix. Due FA, morphology surface area FA‐ ‐PAA enhanced 0.04 m /g (pure hydrogel) 0.8m /g. breakthrough showed MEA‐functionalized demonstrated a superior capacity (2.0 mmol/g), significantly outperforming nonfunctionalized (1.6 mmol/g) pure (0.08 at room temperature. Molecular dynamics (MD) simulations model revealed synergistic role in enhancing adsorption. Overall, shows efficient adsorbent for industrial purification applications.

Language: Английский

Review on Synthesis and Characterization of Advanced Nanomaterials-based Mixed Matrix Membranes (MMMs) for CO2 Capture: Progress, Challenges, and Prospects DOI

Syed Awais Ali,

Waqad Ul Mulk, Asmat Ullah Khan

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 21, 2024

Language: Английский

Citations

4
Experimental and modeling study of 6FDA-Durene polyimide/ionic liquid-modified ZIF-8 mixed matrix membranes for CO2 separation DOI
Mohammad Mehdi Moftakhari Sharifzadeh,

Farshid Pajoum Shariati,

Abtin Ebadi Amooghin

et al.

Results in Engineering, Journal Year: 2025, Volume and Issue: 26, P. 104686 - 104686

Published: March 26, 2025

Language: Английский

Citations

0
A Critical Review on Advancements and Challenges in CO2 Gas Separation via 6FDA-based Membranes DOI Creative Commons

Mehtab Ali Darban,

Serene Sow Mun Lock, Suhaib Umer Ilyas

et al.

Carbon Capture Science & Technology, Journal Year: 2025, Volume and Issue: unknown, P. 100423 - 100423

Published: April 1, 2025

Language: Английский

Citations

0
State-of-the-Art Membrane Solutions for Direct Air Carbon Capture (DACC): An Overview on the Current Status and Future Directions DOI

Syed Awais Ali,

Syed Nasir Shah, Malik Abdul Karim

et al.

Energy & Fuels, Journal Year: 2025, Volume and Issue: unknown

Published: May 10, 2025

Language: Английский

Citations

0
Synthesis of Amine‐Functionalized Fly Ash‐Infused Polymeric Hydrogel for H2S Removal and Validation Using Molecular Dynamic Simulation DOI

Syed Farman Ali Shah,

Nurul Ekmi Rabat, Khairiraihanna Johari

et al.

Journal of Applied Polymer Science, Journal Year: 2025, Volume and Issue: unknown

Published: May 20, 2025

ABSTRACT Hydrogen sulfide (H 2 S) removal from natural gas is critical due to its toxicity and corrosive nature. Adsorption one of the most effective methods, but polymeric hydrogels often exhibit limited H S adsorption capacity. To overcome this, an amine‐functionalized fly ash (FA)‐grafted polyacrylic acid (PAA) hydrogel (FA‐ g ‐PAA) was synthesized using 5 wt.% FA via solution polymerization functionalized with 30 monoethanolamine (MEA) enhance removal. Physiochemical properties performance were evaluated Fourier‐transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) analysis, thermogravimetric analysis (TGA), X‐ray diffraction (XRD). The results confirmed successful grafting MEA into PAA matrix. Due FA, morphology surface area FA‐ ‐PAA enhanced 0.04 m /g (pure hydrogel) 0.8m /g. breakthrough showed MEA‐functionalized demonstrated a superior capacity (2.0 mmol/g), significantly outperforming nonfunctionalized (1.6 mmol/g) pure (0.08 at room temperature. Molecular dynamics (MD) simulations model revealed synergistic role in enhancing adsorption. Overall, shows efficient adsorbent for industrial purification applications.

Language: Английский

Citations

0