Published: Jan. 1, 2025
Language: Английский
Published: Jan. 1, 2025
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 496, P. 154097 - 154097
Published: July 19, 2024
Language: Английский
Citations
50Chemical Science, Journal Year: 2024, Volume and Issue: 15(36), P. 14585 - 14607
Published: Jan. 1, 2024
The development of high-efficiency atomic-level catalysts for energy-conversion and -storage technologies is crucial to address energy shortages. spin states diatomic (DACs) are closely tied their catalytic activity. Adjusting the DACs' active centers can directly modify occupancy d-orbitals, thereby influencing bonding strength between metal sites intermediates as well transfer during electro reactions. Herein, we discuss various techniques characterizing atomic strategies modulating center states. Next, outline recent progress in study effects DACs oxygen reduction reaction (ORR), evolution (OER), hydrogen (HER), electrocatalytic nitrogen/nitrate (eNRR/NO
Language: Английский
Citations
28Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 529, P. 216462 - 216462
Published: Jan. 21, 2025
Language: Английский
Citations
6Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 532, P. 216545 - 216545
Published: Feb. 19, 2025
Language: Английский
Citations
5ACS Energy Letters, Journal Year: 2025, Volume and Issue: 10(1), P. 600 - 619
Published: Jan. 2, 2025
The electrochemical reduction reaction of CO2 (eCO2RR) to chemicals presents a viable solution for addressing climate change and sustainable manufacturing. In this Review, we describe the recent advancements in eCO2RR multicarbon (C2+) production from aspects catalyst structure, microenvironments, mechanistic understanding. We draw experimental theoretical comparisons between systems containing bulk highly dispersed metals, alloys, metal compounds recount new results microenvironmental impacts as well catalytic mechanism. From our own studies, offer some viewpoints on electrocatalytic mechanism during complex multistep proton-coupled electron transfers propose several research directions unlocking full potential scalable industrial CO2-to-C2+ conversion.
Language: Английский
Citations
2Materials Science and Engineering R Reports, Journal Year: 2024, Volume and Issue: 162, P. 100886 - 100886
Published: Nov. 23, 2024
Language: Английский
Citations
10Chemical Science, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Doping strategies have been recognized as effective approaches for developing cost-effective and durable catalysts with enhanced reactivity selectivity in the electrochemical synthesis of value-added compounds directly from CO 2 .
Language: Английский
Citations
1Microstructures, Journal Year: 2025, Volume and Issue: 5(1)
Published: Jan. 17, 2025
Carbon dioxide reduction reaction (CO2RR) is an efficacious method to mitigate carbon emissions and simultaneously convert CO2 into high-value products. The efficiency of CO2RR depends on the development highly active selective catalysts. Copper (Cu)-based catalysts can effectively reduce hydrocarbons oxygen-containing compounds because their unique geometric electronic structures. Most importantly, Cu multiple products (C2+). Therefore, this review aims outline recent research progress in Cu-based for CO2RR. After introducing mechanism electroreduction reaction, we summarize influence size, morphology, coordination environment single component performance, especially performance control that contain nano or single-atom sites. Then, synergistic regulation strategies doping other metals are summarized. Finally, supports used reviewed. prospects challenges discussed.
Language: Английский
Citations
1Journal of Rare Earths, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 1, 2025
Language: Английский
Citations
1Chemical Science, Journal Year: 2024, Volume and Issue: unknown
Published: Jan. 1, 2024
Utilizing double coordination shell modulation, we construct a novel nitrogen-free single-atom manganese configuration catalyst on graphene oxide (Mn–S 1 O 4 G), which exhibits excellent ORR and zinc–air battery performances.
Language: Английский
Citations
7