Synthesis of Ngai Reagent and Longer Carbon Chain Variants for Perfluoroalkoxylations DOI

Koki Kawai,

Sota Ikawa,

Naoyuki Hoshiya

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 5, 2024

We present a straightforward method for the synthesis of Ngai trifluoromethoxy reagent and longer carbon chain variants, thereby expanding range options perfluoroalkoxylation reactions. Utilizing cost-effective sodium perfluoroalkane sulfinates (R

Language: Английский

Copper(I) Iodide-Catalyzed Perfluoroalkoxylation Reaction of Alkyl Halides DOI

Xiong Wu,

Bingjun Le,

Wangchuan Xiao

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(34), P. 7139 - 7143

Published: Aug. 15, 2024

We report an efficient perfluoroalkoxylation reaction of alkyl halides catalyzed by copper(I) iodide (CuI), which facilitates the simultaneous activation both perfluoroalkoxide and halides. This methodology is tolerant a wide range functional groups eliminates need for costly metal reagents. The conducted in single step under mildly practical conditions.

Language: Английский

Citations

1
A silylboronate-mediated strategy for cross-coupling of alkyl fluorides with aryl alkanes: mechanistic insights and scope expansion DOI Creative Commons
Jun Zhou,

Zhengyu Zhao,

Tatsuki Kiyono

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

The construction of C(sp

Language: Английский

Citations

1
Synthesis of Ngai Reagent and Longer Carbon Chain Variants for Perfluoroalkoxylations DOI

Koki Kawai,

Sota Ikawa,

Naoyuki Hoshiya

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 5, 2024

We present a straightforward method for the synthesis of Ngai trifluoromethoxy reagent and longer carbon chain variants, thereby expanding range options perfluoroalkoxylation reactions. Utilizing cost-effective sodium perfluoroalkane sulfinates (R

Language: Английский

Citations

1