Practical Electrochemical Hydrogenation of Nitriles at Nickel Foam Cathode

Green Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

We report a scalable hydrogenation method for nitriles based on cost-effective materials in very simple two-electrode setup under galvanostatic conditions. All components are commercially and readily available. The is easy to conduct applicable variety of nitrile substrates, leading exclusively primary amine products yields up 89% using an work-up protocol. Importantly, this transferable from the milligram scale batch-type screening cells multi-gram flow-type electrolyser. transfer flow electrolysis enabled us achieve notable 20 g day

Language: Английский

A Stepwise Electrochemical Baeyer–Villiger Oxidation with Water as the Oxygen Source

The Journal of Physical Chemistry Letters, Journal Year: 2024, Volume and Issue: 15(42), P. 10435 - 10441

Published: Oct. 10, 2024

Baeyer-Villiger oxidation is a method with 125-year history that produces lactones through synergistic mechanism by reaction stoichiometric peracids. Therefore, substituted can be obtained from only cyclic ketones. In this context, an electrochemical was developed using CeO

Language: Английский