One-step in-situ synthesis of nickel–cobalt sulfide catalysts for ultra-efficient electrooxidation of 5-hydroxymethylfurfural DOI

Lili Geng,

Sen Li,

Haifeng Shi

et al.

Chemical Engineering Science, Journal Year: 2024, Volume and Issue: 302, P. 120919 - 120919

Published: Nov. 8, 2024

Language: Английский

Interface engineering of Co9S8-Ni3S2/Cu heterogeneous electrocatalyst for enhanced HMF oxidation DOI
Na Wang,

Longyu Wang,

Suohe Yang

et al.

Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162401 - 162401

Published: Jan. 1, 2025

Language: Английский

Citations

4
Regulating Intermediate Adsorption and Promoting Charge Transfer of CoCr‐LDHs by Ce Doping for Enhancing Electrooxidation of 5‐Hydroxymethylfurfural DOI Open Access
Ling Ding,

Zewen Shen,

Hao Pan

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 14, 2025

Abstract Electrochemical oxidation of 5‐hydroxymethylfurfural (HMFOR) to generate high‐value chemicals under mild conditions acts as an energy‐saving and sustainable strategy. However, it is still challenging develop electrocatalysts with high efficiency good durability. Here, nickel foam (NF) supported CoCrCe(7.5%)‐LDH (layered double hydroxides) by doping Ce into CoCr‐LDH show (HMF) conversion (99%), 2,5‐furandicarboxylic acid (FDCA) yield Faraday (100%) at 1.4 V RHE . The also exhibits remarkable stability 97% HMF after 10 cycles. X‐ray absorption near‐edge spectroscopy (XANES) theoretical calculation that beneficial the formation high‐valance Co significantly facilitates electron transfer, regulates adsorption behavior intermediates, reduces Gibbs free energy barrier accelerates reaction rate. This work promotes use rare earth elements promote HMF.

Language: Английский

Citations

3
Advances in the Energy‐Saving Electro‐Oxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid DOI Open Access

Yujie Ren,

Shilin Fan,

Yu Xiao

et al.

Advanced Sustainable Systems, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 5, 2025

Abstract As a pivotal bio‐based building block, 2,5‐furandicarboxylic acid (FDCA) holds immense and broad application potential in the chemistry industry. Its polymeric derivative, polyethylene furandicarboxylate (PEF), emerges as an appealing alternative to conventional petroleum‐based terephthalate (PET). The electrochemical route for oxidizing 5‐hydroxymethylfurfural (HMF) into FDCA presents significant advantages over thermochemical processes, without requirements of high temperature, pressure, chemical oxidants, precious metal catalysts, featuring higher energy efficiency. Furthermore, electrosynthesis at anode can be synergistically integrated with selective reduction reactions cathode, enabling simultaneous production two desirable value‐added products further enhancing overall utilization This work reviews advancements electrocatalytic HMF (EHTF), encompassing catalyst design, reaction mechanisms, coupling strategies, reactor configurations. It also indicates challenges opportunities EHTF provides insights future development directions.

Language: Английский

Citations

3
Spin polarization tailoring by W doping for C-H/O-H activation and hydroxyl adsorption boosting 5-hydroxymethylfurfural oxidation DOI
Yanan Zhou, Ning Yu,

Ruo‐Yao Fan

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: unknown, P. 124692 - 124692

Published: Oct. 1, 2024

Language: Английский

Citations

5
Advances and Prospects of Selective Electrocatalytic Upgrading of 5‐Hydroxymethylfurfural to Furan‐2,5‐Dicarboxylic Acid DOI Open Access

Lianhua Chen,

Yang Liu

The Chemical Record, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

Abstract The electrocatalytic upgrading of 5‐hydroxymethylfurfural (HMF, 5‐(Hydroxymethyl) furan‐2‐carbaldehyde) has emerged as a renewable and environmentally friendly means for the production high‐value chemicals, with oxidation product furan‐2,5‐dicarboxylic acid (FDCA, 2,5‐furandicarboxylic acid) possessing economic viability in substituting terephthalic polymer synthesis. This article reviews recent advancements selective HMF to FDCA, including reaction pathways, mechanisms, well activity descriptors (HMFOR), alongside advanced operando characterization techniques. Subsequently, representative HMFOR catalysts, encompassing noble metal, non‐noble transition metal‐based catalysts metal free‐based are presented. Then strategies regulating longevity were introduced, followed by an exploration future prospects development catalysts.

Language: Английский

Citations

0
Ni3S2–Co9S8 Heterojunction Integrated within Cobalt Layered Double Hydroxide Nanosheets for 5-Hydroxymethylfurfural Oxidation and Oxygen Evolution Reaction DOI
Tianmin Zhang, Ming Xiang, Xianfeng Yang

et al.

ACS Applied Nano Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 31, 2025

Language: Английский

Citations

0
CeO2 enhancement on self-grown Ni(OH)2 on nickel foam for 5-hydroxymethylfurfural electrooxidation DOI

Z. C. Kang,

Yongming Zeng, Xiaofei Li

et al.

Electrochimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 146201 - 146201

Published: April 1, 2025

Language: Английский

Citations

0
Construction of CoO–Cu2O Composites with Enhanced HMF Adsorption and Passivated Water Oxidation for High-Efficiency Biomass Valorization DOI
Zhuolun Li, Junwei Sun, Yue Wang

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: April 9, 2025

Language: Английский

Citations

0
Quantitative kinetic and catalytic analysis of 5-hydroxymethylfurfural electrooxidation reaction through in-situ Raman spectroscopy DOI
Hui Dong, Hongbo Li, Fenghui Ye

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162518 - 162518

Published: May 1, 2025

Language: Английский

Citations

0
In Situ Construction of N-Doped Ni3S2@Ni(OH)2 Self-Supported Heterostructures for Highly Selective Electrooxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran DOI
Wenbiao Wang, Ao Wang, Gang Xu

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 15, 2025

The selective electrooxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) is promising for biomass valorization but remains challenging under alkaline conditions due inefficient nonprecious metal catalysts. Herein, we develop a scalable N-doped Ni3S2@Ni(OH)2 heterostructure via molten-salt-derived precursor and one-pot hydrothermal synthesis. This catalyst achieves low potential 1.395 V (10 mA cm-2) 96% DFF selectivity, with 47.6% yield in 1.0 M K2CO3 (pH = 12). Experimental DFT studies reveal that interfacial electron redistribution enhances HMF hydroxyl radical adsorption, lowers the HMF-to-DFF energy barrier, accelerates charge transfer. group more reactive than aldehyde, boosting selectivity. heterojunction's synergistic effect key achieving high-value aldehydes efficiently.

Language: Английский

Citations

0