Iron-Photocatalyzed Decarboxylative Alkylation of Carboxylic Acids with Morita–Baylis–Hillman Acetates DOI
Yanli Yin, Fang Chen, Dong Chen

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 27, 2024

We present an iron-photocatalyzed decarboxylative alkylation strategy involving carboxylic acids and Morita–Baylis–Hillman (MBH) acetates to synthesize E-type tri- tetrasubstituted alkenes with moderate excellent stereoselectivity (E/Z ratio up >19:1). This method is applicable a broad range of structurally diverse primary, secondary, tertiary alkyl acids, as well complex pharmaceutical natural achieving efficient various MBH under mild conditions (>60 examples, yields 96%). approach offers powerful for streamlined alkylation.

Language: Английский

Value-Added Conversion of Lignin Based on Inorganic−Organic Dual-Ligand-Regulated CdSe@CdS Nanorods DOI
Qingqing Gan,

Huakang Yang,

Zining Zhang

et al.

Surfaces and Interfaces, Journal Year: 2025, Volume and Issue: 61, P. 106123 - 106123

Published: March 1, 2025

Language: Английский

Citations

0
Iron-Photocatalyzed Decarboxylative Alkylation of Carboxylic Acids with Morita–Baylis–Hillman Acetates DOI
Yanli Yin, Fang Chen, Dong Chen

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 27, 2024

We present an iron-photocatalyzed decarboxylative alkylation strategy involving carboxylic acids and Morita–Baylis–Hillman (MBH) acetates to synthesize E-type tri- tetrasubstituted alkenes with moderate excellent stereoselectivity (E/Z ratio up >19:1). This method is applicable a broad range of structurally diverse primary, secondary, tertiary alkyl acids, as well complex pharmaceutical natural achieving efficient various MBH under mild conditions (>60 examples, yields 96%). approach offers powerful for streamlined alkylation.

Language: Английский

Citations

1