Host–Guest Complexation of α‐Cyclodextrin and Triiodide Ions for Enhanced Performance of Ionic Thermoelectric Capacitors
Shin-Shin Kao,
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Ching‐Chieh Hsu,
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Shao‐Huan Hong
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et al.
Advanced Energy Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 22, 2025
Abstract
Ionic
thermoelectric
materials
have
emerged
as
a
promising
avenue
for
harvesting
low‐grade
waste
heat,
with
significant
potential
applications
in
wearable
electronics.
This
study
introduces
novel
design
ionic
capacitors
(ITECs)
by
incorporating
host–guest
complexation
between
α–cyclodextrin
(α‐CD)
and
triiodide
ions
(I
3
−
).
The
strong
α‐CD
I
confines
the
diffusion
of
within
cylindrical
cavities
α‐CD,
evidenced
UV–vis
spectroscopy
13
C‐NMR
analysis.
confinement
enhances
ion
mobility
difference
sodium
ions,
which
turn
significantly
boosts
thermopower
polyvinyl
alcohol/α‐CD/NaI
hydrogels.
Accordingly,
optimized
sample
achieves
an
impressive
positive
14.24
mV
K
−1
high
power
factor
477.2
µW
−2
m
.
Furthermore,
stretchable
ITEC
demonstrates
substantial
density
5.9
mW
When
integrated
into
3‐leg
device,
stable
thermovoltage
176
is
generated
under
temperature
gradient
4.4
K,
thus
highlighting
this
system
efficient
thermal
energy
harvesting.
Language: Английский
Recent Progress in Polymer Gel‐Based Ionic Thermoelectric Devices: Materials, Methods, and Perspectives
Chia‐Yu Lee,
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Shao‐Huan Hong,
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Cheng‐Liang Liu
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et al.
Macromolecular Rapid Communications,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 2, 2025
Polymer
gel-based
ionic
thermoelectric
(i-TE)
devices,
including
thermally
chargeable
capacitors
and
thermogalvanic
cells,
represent
an
innovative
approach
to
sustainable
energy
harvesting
by
converting
waste
heat
into
electricity.
This
review
provides
a
comprehensive
overview
of
recent
advancements
in
i-TE
materials,
focusing
on
their
Seebeck
coefficients,
the
mechanisms
underlying
thermodiffusion
effects,
various
strategies
employed
enhance
performance.
Gel-based
materials
show
great
promise
due
flexibility,
low
cost,
suitability
for
flexible
wearable
devices.
However,
challenges
such
as
improving
conductivity
stability
redox
couples
remain.
Future
directions
include
enhancing
efficiency
ionic-electronic
coupling
developing
more
robust
electrode
optimize
conversion
real-world
applications.
Language: Английский
Approaches and methods for improving the performance of ionic thermoelectric materials
Liuqi Cao,
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Tingting Sun,
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Huiru Zhao
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et al.
Chemical Engineering Journal,
Journal Year:
2025,
Volume and Issue:
unknown, P. 160206 - 160206
Published: Feb. 1, 2025
Language: Английский
Lignin for Thermoelectrics
Published: Jan. 1, 2025
Language: Английский
Conductive Polymer/Multidimensional Carbon Composite on Graphite Felt Electrodes for Liquid Thermo-Electrochemical Cells
Guanhua Ren,
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Wei Yang,
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Jingjing Bao
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et al.
ACS Sustainable Chemistry & Engineering,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 11, 2025
Language: Английский
Back Mirror‐Free Selective Light Absorbers for Thermoelectric Applications
Advanced Optical Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 16, 2024
Abstract
Improving
light
absorption
is
essential
for
the
development
of
solar
thermoelectric
generators.
Most
efficient
absorbers
require
a
back
mirror
(a
thick
metal
film)
to
reduce
reflectivity
by
promoting
interference
between
incident
and
reflected
light.
However,
presence
continuous
film
supposes
limitation
applications,
as
it
behaves
like
shortcut
Seebeck
voltage.
In
this
work,
mirror‐free
selective
absorber
presented,
designed
fabrication
devices.
The
combination
high
low
refractive
index
material
covered
semi‐transparent
electrode
optimized.
As
difference
mirror,
can
be
patterned
prevent
quenching
Thanks
this,
replaced
transparent
thermoelectric,
enabling
heat‐to‐energy
conversion
with
negligible
loss
performance.
Language: Английский