A Universal Strategy for Bridging Prussian Blue Analogues and Sodium Layered Oxide Cathodes: Direct Fast Conversion, Dynamic Structural Evolution, and Sodium Storage Mechanisms
Chemical Science,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
A
universal
strategy
is
proposed
to
convert
unqualified
Prussian
blue
analogues
(PBAs)
into
sodium
layered
oxide
cathodes
via
a
fast
sintering
process,
achieving
both
economic
and
environmental
benefits.
Language: Английский
Dual-enhancements of Stability and Wettability in O3-Na0.95Ni1/3Fe1/3Mn1/3O2 Cathodes by Converting Surface Residual Alkali into Ultalthin Na2Ti3O7 Coatings
Hao Gong,
No information about this author
B.K. Gan,
No information about this author
Xinkang Li
No information about this author
et al.
Nanoscale,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Residual-alkali-derived
Na
2
Ti
3
O
7
coatings
boost
electrolyte
wettability
and
electrochemical
performance
of
a
layered
oxide
cathode
for
sodium-ion
batteries.
Language: Английский
Jahn‐Teller Effect in Sodium Layered Oxide Cathodes: Inducement Mechanisms, Mitigation Strategies, and Rational Utilizations
Yanjiang Li,
No information about this author
Yan‐Fang Zhu,
No information about this author
Bing‐Bing Chen
No information about this author
et al.
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 2, 2025
Abstract
The
sodium‐layered
transition
metal
oxides
(Na
x
TMO
2
)
are
regarded
as
the
promising
cathode
for
sodium‐ion
batteries
(SIBs)
relying
on
their
high
theory
capacity
and
cost‐effectiveness.
Nevertheless,
intrinsic
lattice
distortions
caused
by
Jahn‐Teller
active
ions
significantly
degrade
structural
stability
of
Na
,
generally
resulting
in
unsatisfactory
electrochemical
properties.
In
this
review,
begins
introducing
inducement
mechanisms
effect
(TM)
ions.
Subsequently,
restraining
strategies
well
corresponding
using
element
doping/substitutions,
surface
reconstructions,
polyphase
symbiosis,
TM/oxygen/Na
+
vacancy
manipulations
summarized
detail.
Specifically,
influences
such
mitigation
deformation
properties,
phase
evolution
behaviors,
TM
dissolution
characteristics,
crystal
comprehensively
discussed.
Furthermore,
sensible
utilization
distortion
is
to
build
cathodes
with
and/or
repaid
ion
transport
kinetics
well.
end,
challenges
faced
amelioration
methods
overviewed
put
forward
research
directions
future
trenchantly
constrain
6
octahedron
deformation.
This
work
will
provide
more
perceptions
further
studies
SIBs.
Language: Английский
Cu-mediated bipolar-type extended π-conjugated microporous polymers for lithium-ion battery cathode with high energy density and fast-charging capability
Yitao Li,
No information about this author
Ju Duan,
No information about this author
Yuzhu Wang
No information about this author
et al.
Chemical Science,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
A
Cu
2+
-mediated
bipolar-type
CMP
is
developed
to
maximize
abundant
active
site
utilization
and
enhance
ion
diffusion
kinetics
for
durable,
high
energy-density,
fast-charging
LIB
cathodes.
Language: Английский