EtIDip (EtIPr)—Synthesis, Characterisation and Reactivity of a Robust, Backbone-Modified N-Heterocyclic Carbene and Group 13 Element Complexes DOI Creative Commons
Huanhuan Dong, Albert Martinez‐Segura,

Riley W. Kelehan

et al.

Inorganics, Journal Year: 2025, Volume and Issue: 13(1), P. 27 - 27

Published: Jan. 17, 2025

We report the synthesis, characterisation and reactivity of stable imidazol-2-ylidene EtIDip (EtIPr), {EtCN(Dip)}2C:, Dip = 2,6-iPr2C6H3, as a chemically robust alternative to IDip (IPr), {HCN(Dip)}2C:. The N-heterocyclic carbene could be further converted oxidised species [EtIDipCl]Cl, EtIDipF2, EtIDipO, EtIDipSe, group 13 element complexes EtIDipEX3, with E B, X Br; Al, I; Ga, H. properties ligands are compared molecular structures (DipNCEt)2, [EtIDipH]Cl, [EtIDipH]I, EtIDip, EtIDipBBr3, EtIDipAlI3, EtIDipGaI3, EtIDipAlH3 have been determined.

Language: Английский

EtIDip (EtIPr)—Synthesis, Characterisation and Reactivity of a Robust, Backbone-Modified N-Heterocyclic Carbene and Group 13 Element Complexes DOI Creative Commons
Huanhuan Dong, Albert Martinez‐Segura,

Riley W. Kelehan

et al.

Inorganics, Journal Year: 2025, Volume and Issue: 13(1), P. 27 - 27

Published: Jan. 17, 2025

We report the synthesis, characterisation and reactivity of stable imidazol-2-ylidene EtIDip (EtIPr), {EtCN(Dip)}2C:, Dip = 2,6-iPr2C6H3, as a chemically robust alternative to IDip (IPr), {HCN(Dip)}2C:. The N-heterocyclic carbene could be further converted oxidised species [EtIDipCl]Cl, EtIDipF2, EtIDipO, EtIDipSe, group 13 element complexes EtIDipEX3, with E B, X Br; Al, I; Ga, H. properties ligands are compared molecular structures (DipNCEt)2, [EtIDipH]Cl, [EtIDipH]I, EtIDip, EtIDipBBr3, EtIDipAlI3, EtIDipGaI3, EtIDipAlH3 have been determined.

Language: Английский

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