Conjugated
microporous
polymers
(CMPs),
as
an
emerging
class
of
organics,
have
generated
keen
interest
due
to
their
excellent
structural
stability
and
stronger
designability.
Herein,
redox
donor–acceptor
conjugated
(TAPB-AQ
PBAPD-AQ)
were
prepared
by
utilizing
anthraquinone
anilines
linkers
via
C–N
linkages
used
anodes
build
high-performance
LIBs.
Compared
with
TAPB-AQ,
PBAPD-AQ
has
more
electroactive
groups,
a
narrower
band
gap,
higher
thermal
decomposition
temperatures
(5%
mass
loss
was
up
384
°C).
Benefiting
from
the
insolubility
in
electrolyte
richer
pore
structure,
shows
high
capability
(219.8
mA
h
g–1
at
0.5
A
g–1)
ultrastable
cycling
performance
(96.1%
retention
after
1200
cycles
g–1).
Moreover,
lithium
storage
mechanism
anode
electrode
material
is
explored
through
ex
situ
XPS
DFT
computations.
RSC Advances,
Journal Year:
2025,
Volume and Issue:
15(10), P. 7750 - 7757
Published: Jan. 1, 2025
A
novel
poly(4-aminotriphenylamine-3,3′,4,4′-benzophenone
tetramide)
(PTNBI)
organic
cathode
for
lithium/sodium-ion
batteries
has
been
synthesized,
which
can
effectively
reduce
dissolution
in
electrolytes
and
improve
the
discharge
platform.
Chemical Science,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
A
tertiary-amine-decorated
CMP
photocatalyst
was
fabricated
for
high-performance
H
2
O
production,
enabled
by
the
synergistic
effects
of
a
proton
sponge
and
reservoir.
Macromolecular Rapid Communications,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 28, 2024
Abstract
The
pursuit
of
innovative
organic
materials
and
the
examination
“structure‐function”
correlation
in
lithium‐ion
batteries
(LIBs)
are
crucial
highly
desirable.
Current
research
focuses
on
creation
novel
conjugated
polymers
with
polycarbonyl
groups
examining
impact
electrode
structure
function
batteries.
In
this
paper,
two
cyanovinylene‐based
polymers,
NBA‐TFB
NBA‐TFPB,
synthesized
using
a
Knoevenagel
condensation
reaction
naphthalene
diimide
as
integral
unit.
performance
NBA‐TFPB
cathodes
is
investigated.
Improved
conductivity
increased
active
site
density
resulted
superior
electrochemistry
compared
to
NBA‐TFB.
Specifically,
exhibited
larger
reversible
capacity
(87.58
mAh
g
−1
at
0.2C
88.34%
retention
after
100
cycles),
exceptional
rate
capability
(66.13
5C),
robust
cycling
stability
(99.58%
coulombic
efficiency
1C
60.71%
2000
cycles).
This
study
expands
family
diimide‐based
provides
strategy
for
enhancing
containing
structure.