Tailoring the Energetic Properties of Pyrazole Hybrids through Functionalization with Dinitromethyl and N-Hydroxytetrazole DOI
Vikranth Thaltiri, Richard J. Staples, Jean’ne M. Shreeve

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 5, 2024

The functionalization of pyrazole-based compounds with dinitromethyl and

Language: Английский

Advancing thermal stability through positional pyrazole isomerization: synthesis and characterization of 2’-(1H-pyrazol-4-yl)-1H,2’H-5,5’-bistetrazole and its energetic derivatives DOI Creative Commons
Jing Liu,

Yaqun Dong,

Miao Li

et al.

Energetic Materials Frontiers, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Language: Английский

Citations

0

New Zwitterionic Compounds Based on 1-(tetrazol-5-yl)-1,2,4-triazole: High-Energy, Low-Sensitivity Energetic Materials DOI

Fubing Yang,

Chengming Bian,

Ximei Yang

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 141579 - 141579

Published: Jan. 1, 2025

Language: Английский

Citations

0

A high-density energetic ammonium salt via a polynitropyrazolate counteranion DOI
Miao Li, Yubei Zhang,

Yaqun Dong

et al.

Dalton Transactions, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The energetic ammonium salt of dinitroamino-4,4′,5,5′-tetranitro-2 H ,2′ -[3,3′-bipyrazole] exhibits exceptionally high density, excellent detonation properties, and non-hygroscopic behavior.

Language: Английский

Citations

0

Combination of Nitropyrazole and Nitroaminotriazole: A Novel High-Energy Insensitive Energetic Material DOI
Luyao Chen, Jie Tang,

Teng Zhu

et al.

Crystal Growth & Design, Journal Year: 2025, Volume and Issue: unknown

Published: April 28, 2025

Language: Английский

Citations

0

Exploring Nonmetallic Pentazolate Salts with High Density over 1.7 g·cm-3 DOI
Pengfei Wang, B. X. Liu,

Haohao Ren

et al.

Materials Today Communications, Journal Year: 2025, Volume and Issue: unknown, P. 112725 - 112725

Published: May 1, 2025

Language: Английский

Citations

0

Energetic Nitrated Azole Assemblies: Linear Alliance of Isomeric Furazan-1,2,4-triazole-pyrazole Combinations DOI
Igor L. Dalinger,

T. E. Khoranyan,

Kyrill Yu. Suponitsky

et al.

Crystal Growth & Design, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 19, 2024

While the effect of isomerism on properties energetic molecules has long been recognized, use this phenomenon to deliberately improve performance materials now approached. Here, we report development effective protocols for preparation isomeric compounds with a furazan-triazole-pyrazole framework, which differ in binding points these subunits and position nitro group. The two synthesized isomers readily form X-ray quality crystals solvates DMSO water, but only one isomer was able give unsolvated crystals. Significant differences molecular geometry noncovalent interactions due solvent incorporated into crystal lattice are highlighted. ambiguity evaluating structure–property relationships single compound from data its solvate is demonstrated. first time, 3-(5-(5-(3,4-dinitro-1H-pyrazol-5-yl)-1H-1,2,4-triazol-3-yl)-4-nitrofurazan (6), greater interest because, unlike other isomer, it not hygroscopic higher density. Isomer 6 shock sensitivity detonation velocity similar those RDX, more thermally stable insensitive friction.

Language: Английский

Citations

2

Construction of heterocycle-triazolotriazine framework energetic compounds:Towards novel high-performance explosives DOI
Pengju Yang,

Xiaoxiao Zheng,

Guojie Zhang

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(76), P. 10588 - 10591

Published: Jan. 1, 2024

In this paper, three neutral heterocycle-triazolotriazine compounds featuring multiple amino groups and nitro were designed synthesized. Among them, 2 6 exhibit high detonation performance (

Language: Английский

Citations

1

Tailoring the Energetic Properties of Pyrazole Hybrids through Functionalization with Dinitromethyl and N-Hydroxytetrazole DOI
Vikranth Thaltiri, Richard J. Staples, Jean’ne M. Shreeve

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 5, 2024

The functionalization of pyrazole-based compounds with dinitromethyl and

Language: Английский

Citations

1