Microchemical Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113964 - 113964
Published: May 1, 2025
Language: Английский
Microchemical Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113964 - 113964
Published: May 1, 2025
Language: Английский
Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 131429 - 131429
Published: Jan. 1, 2025
Language: Английский
Citations
5International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 101, P. 636 - 649
Published: Jan. 5, 2025
Language: Английский
Citations
2Optical Materials, Journal Year: 2025, Volume and Issue: unknown, P. 116749 - 116749
Published: Jan. 1, 2025
Language: Английский
Citations
1ACS Nano, Journal Year: 2025, Volume and Issue: unknown
Published: March 17, 2025
Heterophase homojunctions, which connect two compounds having different crystal structures but the same compositions, are important components of many nanoscale photocatalysts and electronic device systems because they integrate electronically distinct materials with minimal lattice mismatch. Making heterophase homojunctions in high yield is challenging has largely been limited to post-processing, aggregation, modulated growth techniques. As a result, within colloidal nanoparticles rare, despite their potentially beneficial characteristics. Here, we demonstrate retrosynthetic pathway for rationally incorporating into nanoparticles. Our approach leverages structure-shifting intermediate that applied during nanoparticle cation exchange. Specifically, partial exchange reactions roxbyite Cu1.8S nanorods, exhibit distorted hexagonal close-packed (hcp) structure, Ni2+ produce regions Ni9S8 have cubic (ccp) structure. The resulting hcp-Cu1.8S/ccp-Ni9S8 nanorods interface crystallographically aligned hcp ccp provide synthetic entryway, through additional series reactions, form derivative maintain hcp/ccp junction while further modifying composition. Using this approach, multistep pathways metal sulfide roxbyite-Cu1.8S (hcp)/digenite-Cu1.8S wurtzite-CdS (hcp)/zincblende-CdS (ccp). CdS incorporate homojunction single band gap energy between those individual phases. ability design achieving synergistic enhanced optical properties semiconductor systems.
Language: Английский
Citations
1Next research., Journal Year: 2025, Volume and Issue: unknown, P. 100135 - 100135
Published: Jan. 1, 2025
Language: Английский
Citations
0Chemistry of Materials, Journal Year: 2025, Volume and Issue: unknown
Published: April 4, 2025
Language: Английский
Citations
0Waste and Biomass Valorization, Journal Year: 2025, Volume and Issue: unknown
Published: April 10, 2025
Language: Английский
Citations
0Journal of Industrial and Engineering Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
Language: Английский
Citations
0ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: May 5, 2025
This study presents a series of 1-Tb/CdS binary heterojunctions, synthesized by combining 1-Tb (a Co3+-Tb3+-based supramolecular complex) and CdS in various weight ratios via solvothermal process. These heterojunctions have been thoroughly characterized to elucidate their chemical, structural, optoelectronic properties. The catalytic effectiveness these was evaluated with respect the hydrogen evolution reaction (HER), spanning photocatalytic, electrocatalytic, photoelectrocatalytic processes. Significantly outperforming individual photocatalysts (CdS 1-Tb) other heterostructures, 7.5-1-Tb/CdS heterojunction exhibited highest HER efficiency. exceptional performance is attributed synergistic integration CdS, enabling highly efficient Z-scheme heterojunction. unique architecture enhances charge separation transfer leveraging complementary electronic properties semiconductors while minimizing recombination losses. X-ray photoelectron spectroscopy, band structure analysis, photoluminescence, electrochemical impedance spectroscopy further validated mechanism, highlighting optimal alignment energy levels. Overall, this highlights potential as robust catalysts for HER. simplicity synthesis process, coupled activity, offers significant advancement clean technologies, paving way sustainable production.
Language: Английский
Citations
0Microchemical Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113964 - 113964
Published: May 1, 2025
Language: Английский
Citations
0