Dynamic Reconstruction of Crystal/Amorphous Hetero‐Phosphate Janus Interfaces for Highly Stable Seawater Splitting DOI
Pengfei Tian, Wei Zong, Jin Xiong

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 5, 2025

Abstract The abundant seawater resources provide favorable advantages for the large‐scale application of electrolysis to produce hydrogen. However, catalysts are prone triggering chlorine evolution reaction (CER) and easily corroded by Cl − , which key challenges that need urgent resolution in technology. Here, a crystal/amorphous heterostructure bifunctional composite catalyst (caMo‐NiFePO/NMF) splitting is synthesized through situ etching phosphorylation. incorporation Mo facilitates formation crystalline‐amorphous interfaces adjusts Fe electronic states d‐band centers, thereby boosting adsorption capacity * OOH intermediates repulsion forming dynamic OOH‐rich, ‐poor Janus interface. This enhances catalytic activity prevents deep reconstruction toward hydroxyl metal oxide, leading highly stable effective splitting. Noteworthy, caMo‐NiFePO/NMF requires low overpotential 328 mV reach 500 mA cm −2 alkaline oxygen (OER), avoiding CER. It also shows excellent with 327 hydrogen (HER). As catalyst, demonstrates performance cell potential 1.7 V achieve 100 seawater, maintaining remarkable stability over 1000 h.

Language: Английский

A designed hierarchical porous Cu–Ni/Ni–Cu alloy converted from commercial nickel foam as versatile electrocatalysts for efficient and extremely stable water splitting DOI

Dongmei Shao,

Shuo Wang, Chaoyue Liu

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137565 - 137565

Published: April 1, 2025

Language: Английский

Citations

0
Chlorine repulsion layer via splicing of S, N co-doped carbon dots for photoelectrochemical seawater splitting DOI
Ziming Zhao, Wenhao Li, Yong Wang

et al.

Materials Today Energy, Journal Year: 2025, Volume and Issue: unknown, P. 101883 - 101883

Published: April 1, 2025

Language: Английский

Citations

0
Visualization of the Key Proton Activities in Hydrogen Evolution Reaction by Electrochromic Catalyst DOI
Yaping Jiang, Jun Hu,

Hang Cai

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: April 21, 2025

Abstract The electrocatalytic hydrogen evolution reaction (HER) is a promising route to produce sustainable energy carrier for global carbon neutrality. HER performance largely determined by the overall proton activities, but identification of such key activities in microscopic process rather difficult. Herein, study demonstrates visualized concept integrating fundamental with electrochromic technology on well‐designed Pt@WO 3 platform acidic electrolyte, where can be rapidly discriminated color changes electrode. In contrast bare WO counterpart, electrode displays more positive potential initial‐coloration state and faster decoloration rate associated significantly improved kinetics intercalation deintercalation within component. Correspondingly, as‐prepared catalyst exhibits remarkable activity lower onset‐potential (45 mV, adsorption accumulation) smaller Tafel slope (50 mV dec −1 , desorption), nearly 11.1‐ 3.5‐fold enhancement than those counterpart. It believed that work interesting visualization functionality into may improve readability advance exploration intelligent electrocatalysts.

Language: Английский

Citations

0
Nitrogen-doped carbon nanotube encapsulated CoCu bimetallic alloy particles to promote efficient oxygen evolution reaction via electronic structure regulation DOI
Xianyu Chu,

Yanan Wang,

Jiayi Sun

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137775 - 137775

Published: May 1, 2025

Language: Английский

Citations

0
Dynamic Reconstruction of Crystal/Amorphous Hetero‐Phosphate Janus Interfaces for Highly Stable Seawater Splitting DOI
Pengfei Tian, Wei Zong, Jin Xiong

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 5, 2025

Abstract The abundant seawater resources provide favorable advantages for the large‐scale application of electrolysis to produce hydrogen. However, catalysts are prone triggering chlorine evolution reaction (CER) and easily corroded by Cl − , which key challenges that need urgent resolution in technology. Here, a crystal/amorphous heterostructure bifunctional composite catalyst (caMo‐NiFePO/NMF) splitting is synthesized through situ etching phosphorylation. incorporation Mo facilitates formation crystalline‐amorphous interfaces adjusts Fe electronic states d‐band centers, thereby boosting adsorption capacity * OOH intermediates repulsion forming dynamic OOH‐rich, ‐poor Janus interface. This enhances catalytic activity prevents deep reconstruction toward hydroxyl metal oxide, leading highly stable effective splitting. Noteworthy, caMo‐NiFePO/NMF requires low overpotential 328 mV reach 500 mA cm −2 alkaline oxygen (OER), avoiding CER. It also shows excellent with 327 hydrogen (HER). As catalyst, demonstrates performance cell potential 1.7 V achieve 100 seawater, maintaining remarkable stability over 1000 h.

Language: Английский

Citations

0