Small, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 10, 2024
Metalloporphyrins modified carbon-based materials, owing to the excellent acid-base resistance, optimal electron transfer rates, and superior catalytic performance, have shown great potential in energy electrocatalysis. Recently, numerous efforts concentrated on employing substrates as platforms anchor metalloporphyrins, thereby fabricating a diverse array of composite catalysts tailored for assorted electrocatalytic processes. However, interplay through bonding regulation metalloporphyrins with carbon materials resultant enhancement catalyst performance remains inadequately elucidated. Gaining an in-depth comprehension synergistic interactions between within realm electrocatalysis is imperative advancing development innovative catalysts. Herein, review systematically classifies binding modes (i.e., covalent grafting non-covalent interactions) followed by discussion structural characteristics applications supported various substrates, categorized according their modes. Additionally, this underscores principal challenges emerging opportunities carbon-supported metalloporphyrin catalysts, offering both inspiration methodological insights researchers involved design application these advanced systems.
Language: Английский