A Fluorinated Chiral Liquid with Thermal Robustness for Inducing Circularly Polarized Luminescence DOI
Z.Y. Xiao, Ran Wang, Li Zhang

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 9, 2024

A chiral liquid based on a fluorinated glutamate was designed and synthesized, exhibiting the capacity to transfer chirality achiral components along with thermal stability in induced chirality. Notably, chiroptical signal inverted upon phase transition of glutamate, which is attributed alteration arrangement.

Language: Английский

Synthesis and Properties of Mesogen-Jacketed Liquid Crystal Copolymers with Long-Lived Circularly Polarized Room-Temperature Phosphorescence DOI

Zui Liu,

Fengyu Deng,

Sha Huang

et al.

ACS Applied Polymer Materials, Journal Year: 2024, Volume and Issue: 6(16), P. 9582 - 9592

Published: Aug. 3, 2024

Circularly polarized phosphorescence (CPP) materials, integrating the advantages of with circularly luminescence, show wide applications in many fields. However, designing and preparing pure organic CPP materials remain challenging, as ensuring stability triplet excitons at room temperature while achieving chiral transfer from structures to achiral chromophores is difficult. Herein, we propose a strategy harness structural features mesogen-jacketed liquid crystal polymers (MJLCPs) for material construction. A monomer MJ0Chol phosphorescent MJ0DFM are polymerized prepare homopolymers PMJ0Chol PMJ0DFM copolymers DFM(x)-Chol(y). The lifetime effectively enhanced by "jacketing" effect MJLCPs, luminescence activated through construction helical columnar phase. With content component increasing, gradually improves. Meanwhile, |glum| values samples exhibit an initial increase followed decrease increasing cholesterol content. DFM(0.6)-Chol(0.4) shows highest glum both fluorescence phosphorescence, reaching −4.4 × 10–3 −7.1 10–3, respectively. can be achieved 252 ms.

Language: Английский

Citations

1
Tunable Helix Inversion and Circularly Polarized Luminescence in Cholesteric Liquid Crystal Copolymers with Room-Temperature Phosphorescence DOI
Sha Huang,

Qimei Wu,

Renhua Luo

et al.

Macromolecules, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 24, 2024

Language: Английский

Citations

1
A Fluorinated Chiral Liquid with Thermal Robustness for Inducing Circularly Polarized Luminescence DOI
Z.Y. Xiao, Ran Wang, Li Zhang

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 9, 2024

A chiral liquid based on a fluorinated glutamate was designed and synthesized, exhibiting the capacity to transfer chirality achiral components along with thermal stability in induced chirality. Notably, chiroptical signal inverted upon phase transition of glutamate, which is attributed alteration arrangement.

Language: Английский

Citations

0