Electrophotographic Powder Application for Surface Functionalization of Polymer Parts with Thin Silver‐Nanoadditivated Bactericidal Layers DOI Creative Commons
Jan Lino Kricke,

Niklas Ebert,

Ane Sorarrain

et al.

Advanced Materials Technologies, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 29, 2025

Abstract The feedstock in laser beam powder bed fusion of plastics (PBF‐LB/P) is typically limited to a few materials with strict flowability requirements and low recycling rates, compromising its economic efficiency sustainability. Polymer nanoadditivation gains attraction tailor their physiochemical properties by incorporating nanoadditives. Herein, new approach introduced functionalize polymer part surfaces via electrophotographic application (EPA). Polyamide 12 (PA 12) microparticles decorated laser‐synthesized silver nanoparticles (Ag NPs) are printed as thin layers on bulk PA parts. coating provides bactericidal functionality the reduced nanoadditive employment. Indeed, only two Ag‐PA accounting for 140 µm thick inhibit S. aureus E. coli bacteria growth. As result thickness Ag NP loading 0.1 wt.%, mechanical calorimetric remain unaffected. Owing versatility, proposed envisioned facilitate selective surface functionalization toward graded printing at costs waste generation.

Language: Английский

Mechanistic insights into ZIF-67-derived Ir-doped Co3O4@N-doped carbon hybrids as efficient electrocatalysts for overall water splitting using in situ Raman spectroscopy DOI

Sieon Jung,

Raja Arumugam Senthil, Cheol Joo Moon

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 468, P. 143717 - 143717

Published: May 24, 2023

Language: Английский

Citations

97

Electrokinetic-mechanism of water and furfural oxidation on pulsed laser-interlaced Cu2O and CoO on nickel foam DOI

Yewon Oh,

Jayaraman Theerthagiri,

M.L. Aruna Kumari

et al.

Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 91, P. 145 - 154

Published: Jan. 4, 2024

Language: Английский

Citations

78

Recent progress on plant extract-mediated biosynthesis of ZnO-based nanocatalysts for environmental remediation: Challenges and future outlooks DOI
Osman Ahmed Zelekew, Haileyesus Hatano Haitosa, Xiao Yun Chen

et al.

Advances in Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 317, P. 102931 - 102931

Published: May 25, 2023

Language: Английский

Citations

56

Manifolding surface sites of compositional CoPd alloys via pulsed laser for hydrazine oxidation-assisted energy-saving electrolyzer: Activity origin and mechanism discovery DOI
Yujeong Jeong,

Shreyanka Shankar Naik,

Jayaraman Theerthagiri

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 470, P. 144034 - 144034

Published: June 12, 2023

Language: Английский

Citations

51

Green nanoparticle synthesis at scale: a perspective on overcoming the limits of pulsed laser ablation in liquids for high-throughput production DOI Creative Commons
Inna Yusnila Khairani, Gladys Mı́nguez-Vega, Carlos Doñate‐Buendía

et al.

Physical Chemistry Chemical Physics, Journal Year: 2023, Volume and Issue: 25(29), P. 19380 - 19408

Published: Jan. 1, 2023

This article explores upscaling productivity of laser-generated nanoparticles in liquid and its automatization for industrial applications, considering laser chamber design, scanner technology, target properties.

Language: Английский

Citations

51

Pulsed laser interference patterning of transition‐metal carbides for stable alkaline water electrolysis kinetics DOI Creative Commons

Yewon Oh,

Jayaraman Theerthagiri, Ahreum Min

et al.

Carbon Energy, Journal Year: 2024, Volume and Issue: 6(5)

Published: Jan. 5, 2024

Abstract We investigated the role of metal atomization and solvent decomposition into reductive species carbon clusters in phase formation transition‐metal carbides (TMCs; namely, Co 3 C, Fe TiC, MoC) by pulsed laser ablation Co, Fe, Ti, Mo metals acetone. The interaction between s – p ‐orbitals d‐orbitals causes a redistribution valence structure through charge transfer, leading to surface defects as observed X‐ray photoelectron spectroscopy. These influence evolved TMCs, making them effective for hydrogen oxygen evolution reactions (HER OER) an alkaline medium. C with more affinity promoted CoO(OH) intermediates, electrochemical oxidation O 4 was captured via situ/operando Raman probes, increasing number active sites OER activity. MoC d‐vacancies exhibits strong binding, promoting HER kinetics, whereas TiC defect states trap carriers may hinder both activities. results show that assembled membrane‐less electrolyzer C∥Co MoC∥MoC electrodes requires ~2.01 1.99 V, respectively, deliver 10 mA cm − 2 excellent structural stability. In addition, ascertained synthesis mechanism unit‐cell packing relations will open up sustainable pathways obtaining highly stable electrocatalysts electrolyzers.

Language: Английский

Citations

47

Modulating the Electronic Structure of Ni/NiO Nanocomposite with High‐Valence Mo Doping for Energy‐Saving Hydrogen Production via Boosting Urea Oxidation Kinetics DOI Creative Commons

V. Maheskumar,

Ahreum Min, Cheol Joo Moon

et al.

Small Structures, Journal Year: 2023, Volume and Issue: 4(12)

Published: Sept. 3, 2023

Electrocatalytic urea oxidation reaction (UOR) has emerged as a promising alternative to the anodic oxygen evolution (OER) in water electrolysis. However, UOR faces challenges like slow kinetics, high energy barriers, and complex mechanism, necessitating development of efficient electrocatalysts. Herein, rapid method is proposed for synthesizing Mo‐doped Ni/NiO (Ni/MNO) nanocomposite highly effective electrocatalyst. Mo doping oxidizes Ni 2+ 3+ , creating abundant active sites UOR. The Ni/MNO catalyst exhibits remarkable activity both OER due doping, structural modulation, increased sites, presence ions. Optimized Ni/MNO‐10 shows low overpotential 280 mV working potential 1.37 V versus reversible hydrogen electrode at 10 mA cm −2 with exceptional stability over 12 h continuous Notably, urea‐assisted splitting requires only 1.45 significantly less than overall voltage (1.65 V), indicating energy‐efficient production. Moreover, outstanding long‐term stability. This work presents approach cost‐effective electrocatalysts clean production wastewater treatment.

Language: Английский

Citations

45

Leveraging phosphate group in Pd/PdO decorated nickel phosphate microflowers via pulsed laser for robust hydrogen production in hydrazine-assisted electrolyzer DOI
Hyeyeon Lee, Jayaraman Theerthagiri,

M.L. Aruna Kumari

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 57, P. 176 - 186

Published: Jan. 8, 2024

Language: Английский

Citations

38

Pulsed Laser-patterned high-entropy single-atomic sites and alloy coordinated graphene oxide for pH-universal water electrolysis DOI

Yeryeong Lee,

Jayaraman Theerthagiri, Wanwisa Limphirat

et al.

Journal of Materials Chemistry A, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

We introduce high-entropy single-atom catalysts (HESACs) from FeRuPtNiCoPd HEA on GO via pulsed laser irradiation in liquids. Synergistic interactions and rapid Fe 2+ photoreduction enhance active sites, achieving superior overall water splitting.

Language: Английский

Citations

3

Constructing Mo-Co2P/Ni12P5 heterostructures as highly efficient electrocatalysts for overall water splitting DOI
Ning Ye, Yisong Wang, Lei Han

et al.

Journal of Power Sources, Journal Year: 2025, Volume and Issue: 637, P. 236597 - 236597

Published: Feb. 22, 2025

Language: Английский

Citations

2