Flexible Linker Spacer Length Modulation in Cd‐Based Metal–Organic Frameworks: Impact on Polarity and Sequestration Abilities DOI
Himanshi Bhambri, Alisha Gogia, Sanjay K. Mandal

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 29, 2024

Abstract The heightening concerns over an outbreak of hazardous radioiodine from nuclear waste and carbon dioxide emissions fossil fuels have restricted access to clean water air. In this work, three Cd‐MOFs ( 1 ‐ 3 ) are self‐assembled under environment‐friendly conditions using i) a polypyridyl linker spanned by flexible poly(methylene) spacer, ii) bent dicarboxylate linker. With change in the length methylene dimensionality MOFs is tuned between 3D 2D 2 ). microscopic images reveal that displays larger particle sizes more pronounced morphology compared . These show high thermal stability (up 300 °C) wettability. A controlled polar feature utilized achieve uptake capacity iodine (I or I − bodies (2.46–2.37 g −1 vapor (3.31–2.65 remarkable CO , sorbate further fixated into market‐value products quantitative conversions atom economy room temperature solvent‐free conditions. comprehensive theoretical support provided configurational biased Monte Carlo (CBMC) simulations exact locale binding energies sorbates epoxide) toward these MOFs.

Language: Английский

The syntheses of the flexible TAPDA-based covalent organic frameworks utilized for capturing iodine and fluorescence sensing 2,4-dinitrophenol DOI
Feng Zhu,

Ya-Chen Wang,

Tong‐Mou Geng

et al.

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, Journal Year: 2025, Volume and Issue: unknown, P. 126100 - 126100

Published: March 1, 2025

Language: Английский

Citations

0
Donor-Acceptor Covalent Organic Frameworks Propel Oxygen Reduction Reaction with Push-Pull Dynamics DOI
Greesh Kumar, Sabuj Kanti Das,

Thakur Rochak Kumar Rana

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(41), P. 28085 - 28094

Published: Jan. 1, 2024

Extended π-conjugated COFs containing imine linked active sites have been synthesised and found to accelerate the ORR. The mechanism of ORR reaction has explored via in situ FTIR push–pull interaction alkaline media.

Language: Английский

Citations

0
Porous solids for energy applications DOI
Saman Alavi, L. E. Bove, Niall J. English

et al.

The Journal of Chemical Physics, Journal Year: 2024, Volume and Issue: 161(20)

Published: Nov. 26, 2024

Language: Английский

Citations

0
Flexible Linker Spacer Length Modulation in Cd‐Based Metal–Organic Frameworks: Impact on Polarity and Sequestration Abilities DOI
Himanshi Bhambri, Alisha Gogia, Sanjay K. Mandal

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 29, 2024

Abstract The heightening concerns over an outbreak of hazardous radioiodine from nuclear waste and carbon dioxide emissions fossil fuels have restricted access to clean water air. In this work, three Cd‐MOFs ( 1 ‐ 3 ) are self‐assembled under environment‐friendly conditions using i) a polypyridyl linker spanned by flexible poly(methylene) spacer, ii) bent dicarboxylate linker. With change in the length methylene dimensionality MOFs is tuned between 3D 2D 2 ). microscopic images reveal that displays larger particle sizes more pronounced morphology compared . These show high thermal stability (up 300 °C) wettability. A controlled polar feature utilized achieve uptake capacity iodine (I or I − bodies (2.46–2.37 g −1 vapor (3.31–2.65 remarkable CO , sorbate further fixated into market‐value products quantitative conversions atom economy room temperature solvent‐free conditions. comprehensive theoretical support provided configurational biased Monte Carlo (CBMC) simulations exact locale binding energies sorbates epoxide) toward these MOFs.

Language: Английский

Citations

0