Investigating New Reactivities Enabled by Polariton Photochemistry DOI
Arkajit Mandal, Pengfei Huo

The Journal of Physical Chemistry Letters, Journal Year: 2019, Volume and Issue: 10(18), P. 5519 - 5529

Published: Sept. 1, 2019

We perform quantum dynamics simulations to investigate new chemical reactivities enabled by cavity electrodynamics. The light-matter interactions between the molecule and quantized radiation mode inside an optical create a set of hybridized electronic-photonic states, so-called polaritons. polaritonic states adapt curvatures from both ground excited electronic opening up possibilities control photochemical reactions exploiting intrinsic behaviors interactions. With simulations, we demonstrate that selectivity model photoisomerization reaction can be controlled tuning photon frequency or coupling strength, providing ways manipulate via interaction. further collective effects multiple molecules. Our results suggest in resonance case, is recycled among molecules enable state reactions, thus effectively functioning as catalyst. In nonresonance emit absorb virtual photons initiate through fundamental electrodynamics processes. These reveal basic principles polariton photochemistry well promising take advantage photons.

Language: Английский

Towards properties on demand in quantum materials DOI
D. N. Basov, Richard D. Averitt, David Hsieh

et al.

Nature Materials, Journal Year: 2017, Volume and Issue: 16(11), P. 1077 - 1088

Published: Oct. 25, 2017

Language: Английский

Citations

781
Polariton chemistry: controlling molecular dynamics with optical cavities DOI Creative Commons
Raphael F. Ribeiro, Luis Á. Martínez-Martínez, Matthew Du

et al.

Chemical Science, Journal Year: 2018, Volume and Issue: 9(30), P. 6325 - 6339

Published: Jan. 1, 2018

Strong coupling of molecules with confined electromagnetic fields provides novel strategies to control chemical reactivity and spectroscopy.

Language: Английский

Citations

563
Manipulating matter by strong coupling to vacuum fields DOI
F. J. García‐Vidal, Cristiano Ciuti,

Thomas W. Ebbesen

et al.

Science, Journal Year: 2021, Volume and Issue: 373(6551)

Published: July 9, 2021

Captivating cavities Laser technology is a familiar example of how confining light between two mirrors can tune its properties. Quantum mechanics also dictates that even without extraneous light, matter confined in cavity resonant with electronic or vibrational transitions couple vacuum electromagnetic field fluctuations. Garcia-Vidal et al. review the remarkable and still somewhat mysterious implications this “strong-coupling” regime, manifestations ranging from enhanced charge transport to site-selective chemical reactivity across range molecular solid-state materials. Science , abd0336, issue p. eabd0336

Language: Английский

Citations

503
Polaritonic Chemistry with Organic Molecules DOI
Johannes Feist, Javier Galego, F. J. García‐Vidal

et al.

ACS Photonics, Journal Year: 2017, Volume and Issue: 5(1), P. 205 - 216

Published: Sept. 26, 2017

We present an overview of the general concepts polaritonic chemistry with organic molecules, i.e., manipulation chemical structure that can be achieved through strong coupling between confined light modes and molecules. Strong associated formation polaritons, hybrid light–matter excitations, lead to energy shifts in such systems amount a large fraction uncoupled transition energy. This has recently been shown significantly alter coupled which opens possibility manipulate control reactions. discuss current state theory for describing these changes several applications, particular focus on collective effects observed when many molecules are involved coupling.

Language: Английский

Citations

416
Strong light–matter interactions: a new direction within chemistry DOI Creative Commons
Manuel Hertzog, Mao Wang, Jürgen Mony

et al.

Chemical Society Reviews, Journal Year: 2019, Volume and Issue: 48(3), P. 937 - 961

Published: Jan. 1, 2019

It is possible to modify the chemical and physical properties of molecules, not only through modifications but also by coupling molecules strongly light. More intriguingly, strong between light even without presence a photon. The phenomenon that makes this called vacuum fluctuations, which finite zero point energy quantized electromagnetic field inside an optical cavity. light-matter coupling, can be as large 1 eV (100 kJ mol-1), leads formation new hybrid states, polaritons. formed states viewed linear combination (vacuum field) matter (molecules), thus completely changing landscape system. Using interactions have for instance been used change reactivity, charge conductivity, excited state relaxation pathways rates reactions organic molecules. In review brief history given, followed theoretical framework, methods analysis, accomplishments. Finally, personal reflection on future perspectives applications within given.

Language: Английский

Citations

360
Challenges in Plasmonic Catalysis DOI
Emiliano Cortés, Lucas V. Besteiro, Alessandro Alabastri

et al.

ACS Nano, Journal Year: 2020, Volume and Issue: 14(12), P. 16202 - 16219

Published: Dec. 14, 2020

The use of nanoplasmonics to control light and heat close the thermodynamic limit enables exciting opportunities in field plasmonic catalysis. decay excitations creates highly nonequilibrium distributions hot carriers that can initiate or catalyze reactions through both thermal nonthermal pathways. In this Perspective, we present current understanding catalysis, capturing vibrant debates literature, discuss future avenues exploration overcome critical bottlenecks. Our Perspective spans first-principles theory computation correlated far-from-equilibrium light-matter interactions, synthesis new nanoplasmonic hybrids, steady-state ultrafast spectroscopic probes interactions recognizing key contributions each discipline realizing promise We conclude with our vision for fundamental technological advances plasmon-driven chemical coming years.

Language: Английский

Citations

292
From a quantum-electrodynamical light–matter description to novel spectroscopies DOI
Michael Ruggenthaler, Nicolas Tancogne-Dejean, Johannes Flick

et al.

Nature Reviews Chemistry, Journal Year: 2018, Volume and Issue: 2(3)

Published: March 7, 2018

Language: Английский

Citations

281
Cavity Catalysis by Cooperative Vibrational Strong Coupling of Reactant and Solvent Molecules DOI Creative Commons

Jyoti Lather,

Pooja Bhatt,

Anoop Thomas

et al.

Angewandte Chemie International Edition, Journal Year: 2019, Volume and Issue: 58(31), P. 10635 - 10638

Published: June 12, 2019

Here, we report the catalytic effect of vibrational strong coupling (VSC) on solvolysis para-nitrophenyl acetate (PNPA), which increases reaction rate by an order magnitude. This is observed when microfluidic Fabry-Perot cavity in VSC generated tuned to C=O stretching mode both reactant and solvent molecules. Thermodynamic experiments confirm nature system. The change follows exponential relation with respect strength solvent, indicating a cooperative between molecules reactant. Furthermore, study kinetic isotope clearly shows that overlap bands strongly coupled critical for catalysis this reaction. combination effects confirms potential as new frontier chemistry.

Language: Английский

Citations

263
Strong light-matter coupling in quantum chemistry and quantum photonics DOI Creative Commons
Johannes Flick, Nicholas Rivera, Prineha Narang

et al.

Nanophotonics, Journal Year: 2018, Volume and Issue: 7(9), P. 1479 - 1501

Published: Sept. 1, 2018

Abstract In this article, we review strong light-matter coupling at the interface of materials science, quantum chemistry, and photonics. The control light heat thermodynamic limits enables exciting new opportunities for rapidly converging fields polaritonic chemistry optics atomic scale from a theoretical computational perspective. Our follows remarkable experimental demonstrations that now routinely achieve limit matter. many molecules couple collectively to single-photon mode, whereas, in field nanoplasmonics, can be achieved single-molecule limit. Theoretical approaches address these experiments, however, are more recent come spectrum merging developments electrodynamics alike. We latest highlight common features between two different limits, maintaining focus on tools used analyze classes systems. Finally, present perspective need steps toward merging, formally computationally, most prominent Nobel Prize-winning theories physics chemistry: electronic structure (density functional) theory. case how fully description matter treats electrons, photons, phonons same quantized footing will unravel effects cavity-controlled chemical dynamics, optomechanics, nanophotonics, other use phonons.

Language: Английский

Citations

239
Polariton panorama DOI Creative Commons
D. N. Basov, Ana Asenjo-Garcı́a, P. James Schuck

et al.

Nanophotonics, Journal Year: 2020, Volume and Issue: 10(1), P. 549 - 577

Published: Nov. 11, 2020

Abstract In this brief review, we summarize and elaborate on some of the nomenclature polaritonic phenomena systems as they appear in literature quantum materials optics. Our summary includes at least 70 different types light–matter dressing effects. This also unravels a broad panorama physics applications polaritons. A constantly updated version review is available https://infrared.cni.columbia.edu .

Language: Английский

Citations

229