Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 156769 - 156769
Published: Oct. 1, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 156769 - 156769
Published: Oct. 1, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159620 - 159620
Published: Jan. 1, 2025
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: 507, P. 160741 - 160741
Published: Feb. 17, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132504 - 132504
Published: March 1, 2025
Language: Английский
Citations
0Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 20, 2025
Abstract The electrochemical oxidation (EO) process has the unique advantage of in situ generation reactive oxygen species for organic synthesis and wastewater purification. However, strong binding H 2 O anode inhibits desorption species, exacerbating their peroxidation into thus weakening EO performance. In this work, an electron delocalization strategy is proposed by introducing Cu 2+ tetrahedral sites (A Td ) Co 3 4 (Cu x 3‐x to trigger super‐exchange effect ─O─Co Oh 3+ , constructing electron‐rich accelerating *OH promotion Experimental results confirm electron‐delocalized disrupts kinetic equilibrium evolution reaction balances energy barriers adsorption, dehydrogenation, over sites, realizing •OH‐mediated process. required free •OH decreases from 1.14 0.70 eV. extraordinary activity elimination multiple aromatic contaminants demonstrates feasibility practical landfill leachate treatment. This study offers in‐depth understanding active formation systems guides design superior stable electrodes efficient conversion matter.
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 156769 - 156769
Published: Oct. 1, 2024
Language: Английский
Citations
3