Applied Organometallic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 18, 2024

ABSTRACT A salamo‐type biscompartmental ligand was successfully prepared. On this basis, two novel pentanuclear zinc (II) complexes possessing solvent effect were self‐assembled with different salts: [Zn 5 (L) 2 ( μ ‐OAc) (CH 3 COCH )] 1 ) and CN)] ). Complex contains fully deprotonated 4− units, five Zn(II) atoms, coordinating acetate anions, one acetone molecule. The atoms are all in a slightly distorted triangular bipyramidal geometrical configurations. consists of anions acetonitrile structures the self‐assembling may be attributed to various effects applied self‐assembly. As result, involved bridging coordination, thereby expanding distance between secondary building units (SBUs). In addition, polar nonprotonic solvents, especially molecules, coordination process. Finally, reaction sites intermolecular interactions further discussed by MEP, IRI, Hirshfeld surfaces, their fluorescence properties explored.

Language: Английский