Enhancing Photostability of Prochloraz via Designing Natural Acid-Derived Prochloraz-Based Ionic Liquids DOI Creative Commons
Zhiqiang Gao, Fengmao Liu, Qingrong Peng

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(7), P. 1641 - 1641

Published: April 7, 2025

Converting pesticides into ionic liquids by designing counterions can modulate their physicochemical properties, thus improving efficacy and environmental safety. In this study, eight prochloraz-based (PILs) were synthesized using natural organic acids, toxicity, antifungal activity, in postharvest mango preservation evaluated. The results showed that the properties of propiconazole, including water solubility, logKow, surface light stability, could be adjusted selecting with varying structures. These correlated toxicity to zebrafish embryos activity against Colletotrichum gloeosporioides. Notably, except for benzoate PIL, photostability other seven PILs was enhanced under UV irradiation, cinnamate PIL exhibiting a half-life 2.28 times longer than prochloraz. Spectral analysis indicated anions influenced shielding or interacting cations. Furthermore, three selected improved pesticide deposition on during preservation, salicylate penetration fruit, potentially contributing its therapeutic activity. conclusion, liquid strategy offers an effective method modify improve photostability, reduce losses, optimize formulation.

Language: Английский

Enhancing Photostability of Prochloraz via Designing Natural Acid-Derived Prochloraz-Based Ionic Liquids DOI Creative Commons
Zhiqiang Gao, Fengmao Liu, Qingrong Peng

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(7), P. 1641 - 1641

Published: April 7, 2025

Converting pesticides into ionic liquids by designing counterions can modulate their physicochemical properties, thus improving efficacy and environmental safety. In this study, eight prochloraz-based (PILs) were synthesized using natural organic acids, toxicity, antifungal activity, in postharvest mango preservation evaluated. The results showed that the properties of propiconazole, including water solubility, logKow, surface light stability, could be adjusted selecting with varying structures. These correlated toxicity to zebrafish embryos activity against Colletotrichum gloeosporioides. Notably, except for benzoate PIL, photostability other seven PILs was enhanced under UV irradiation, cinnamate PIL exhibiting a half-life 2.28 times longer than prochloraz. Spectral analysis indicated anions influenced shielding or interacting cations. Furthermore, three selected improved pesticide deposition on during preservation, salicylate penetration fruit, potentially contributing its therapeutic activity. conclusion, liquid strategy offers an effective method modify improve photostability, reduce losses, optimize formulation.

Language: Английский

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