The role of reverse Boudouard reaction during integrated CO2 capture and utilisation via dry reforming of methane
Chemical Engineering Journal,
Journal Year:
2024,
Volume and Issue:
491, P. 151668 - 151668
Published: April 26, 2024
Integrated
carbon
capture
and
utilisation
(ICCU)
is
an
emerging
technology
for
simultaneous
CO2
adsorption
conversion
into
value-added
products.
This
provides
a
more
sustainable
approach
compared
to
storage.
Dual-functional
materials
(DFMs)
that
couple
sorbents
(e.g.
CaO)
catalysts
Ni)
enable
direct
of
sorbed
reactions
like
dry
reforming
methane
(DRM).
However,
the
potential
interactions
between
sorbent
catalyst
components
within
DFMs
may
induce
distinct
mechanisms
individual
materials.
Elucidating
these
synergies
interfacial
phenomena
vital
guiding
rational
design
DFMs.
article
investigates
respective
roles
Ni/SiO2
sol–gel
synthesised
CaO
in
integrated
via
(ICCU-DRM)
using
decoupling
approach.
Through
decoupled
reactor
experiments,
it
found
activates
react
with
deposits
from
CH4
decomposition,
achieving
maximal
CO
H2
yields
43.41
mmol
g−1
46.78
as
well
87.2
%
at
650
°C.
Characterisation
shows
coke
would
encapsulate
Ni
nanoparticles
be
active
Boudouard
reaction,
indicating
sufficient
catalyst-sorbent
contact
necessary
spillover.
In-situ
DRIFTS
reveals
no
obvious
CH4-CaCO3
reaction
occurs,
chemisorption
on
enables
reverse
which
further
verified
by
DFT
calculations.
The
findings
elucidate
dependent
synergistic
CaO/CaCO3
ICCU-DRM,
highlight
importance
catalyst-adsorbent
optimising
dual-functional
Language: Английский
Enhancing CO2 Capture and Conversion to Formic Acid via a Membrane-Photocatalytic Hybrid System with ZnO–ZnS Heterojunction Catalyst
ACS Omega,
Journal Year:
2025,
Volume and Issue:
10(6), P. 5563 - 5573
Published: Feb. 5, 2025
A
combined
approach
for
CO2
capture
and
photoreduction
provides
a
comprehensive
solution
to
address
exhaust
emissions.
This
study
aims
develop
hybrid
system
integrating
membrane
contactor
photocatalytic
technology
conversion
formic
acid
by
optimizing
the
synthesis
of
ZnO-ZnS
heterojunction
photocatalysts
through
controlled
variations
in
precursor
concentrations
calcination
temperatures.
The
catalysts
are
characterized
assess
their
structural
optical
properties,
activity,
stability
reaction
kinetics.
Additionally,
performance
is
also
tested
using
model
gas
composition
that
simulates
power
plant
emission
with
UV
or
visible
light
serving
as
energy
source.
synthesized
exhibit
diffraction
patterns
consistent
standard
references,
measured
band
gap
interval
3.06-3.13
eV.
Among
three
most
effective
catalysts,
labeled
Z1
(ZnO:ZnS
ratio
1:2
at
400
°C),
Z2
1:1
Z4
500
yields
were
0.643,
0.554,
0.626
mmol/(L
gcat
h),
respectively.
highest
yield,
0.936
gcat),
was
achieved
under
low
feed
concentration
(15
vol%).
Furthermore,
LED
irradiation,
catalyst
produced
yield
0.394
gcat)
after
4
h,
demonstrating
higher
selectivity
production.
Electrochemical
impedance
spectroscopy
(EIS)
analysis
shows
exhibits
lower
resistance,
enhancing
charge
transfer
efficiency.
Scanning
electron
microscopy
(SEM)
reveals
nanorod-like
ZnO
globular
ZnS
structures
ranging
from
50
100
nm,
while
high-resolution
transmission
(HRTEM)
confirms
presence
patterns.
After
h
test,
XRD
confirmed
peaks
remained
intact,
indicating
stability.
Ultimately,
optimized
demonstrate
promising
efficiency
selective
light,
offering
viable
reduction
advanced
membrane-photocatalytic
technology.
Language: Английский
Predictive neural network model and empirical equations for the physico-chemical properties and solvent characteristics of potassium carbonate solutions in carbon capture processes
Frontiers of Chemical Science and Engineering,
Journal Year:
2025,
Volume and Issue:
19(4)
Published: March 7, 2025
Language: Английский
Revealing the promotion mechanism of low concentration SO2 to Chlorella sorokiniana from macroscopic growth to microscopic metabolism
Hongyan Peng,
No information about this author
Yun Huang,
No information about this author
Ao Xia
No information about this author
et al.
Chemical Engineering Journal,
Journal Year:
2024,
Volume and Issue:
unknown, P. 158447 - 158447
Published: Dec. 1, 2024
Language: Английский
Dynamic Interactive Effects of Technological Innovation, Transportation Industry Development, and CO2 Emissions
Kaige An,
No information about this author
Xiaowei Wang,
No information about this author
Zhenning Wang
No information about this author
et al.
Sustainability,
Journal Year:
2024,
Volume and Issue:
16(19), P. 8672 - 8672
Published: Oct. 8, 2024
This
paper
aims
to
clarify
the
intricate
relationships
between
technological
innovation,
transportation
industry
development,
and
CO2
emissions
facilitate
a
positive
synergy
among
technology,
economy,
climate,
advancing
fulfillment
of
‘double
carbon’
goal.
Utilizing
panel
data
from
30
provinces
in
China
2005
2020,
we
employ
vector
autoregressive
model
using
generalized
method
moments
empirically
examine
dynamic
interactive
effects
these
participants.
The
findings
reveal
that
significantly
promoted
inhibitory
impact
innovation
on
emissions.
However,
such
reductions
cannot
counterbalance
rise
industry.
Moreover,
its
varied
across
regions.
Specifically,
development
within
eastern
contributed
shift
local
carbon
emission
negative
under
influence
innovation.
In
northeast,
enhanced
effect
contrast,
western
region,
industrial
intensified
role
promoting
Furthermore,
this
work
found
notably
diminished
reduction
performance
part
northeastern
region.
These
further
revealed
complex
interplay
industry,
They
offer
insights
for
policymakers
tailor
region-specific
technologies
bolster
‘dual
goal
sustainable
strategies,
thereby
achieving
reduction.
Language: Английский