Ubiquitous Liquid Metal 3D Printing: From Gas, Liquid to Rigid Media DOI

Xiaohui Shan,

Weichen Feng,

Ziliang Cui

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 28, 2024

Abstract Liquid metals (LMs) are opening large spaces for achieving functional 3D printing. However, previous fabrication strategies ever developed so far can only address a specific printing task that has yet to fulfill various needs. Conceiving all fabrications and their output quality dominated by the interactions between inks ambient environment, this review is dedicated presenting generalized framework toward ubiquitous LM summarizing its category thus integrated. A panoramic view provided intentionally administrating interfacial among different media guide ink modification optimization. Further, interpreted, ranging from gases, liquids soft matters, biological tissues, even rigid materials, exploring key mechanisms such as oxidation facilitation, heat dissipation, structural support, modulus matching, strong wettability, high reactivity. Following that, inks, typical technologies, diverse working media, enabled applications reviewed. The elucidation of these interactions, particularly physical chemical effects, lead incubation future centers. It expected interactional mold additive manufacturing into ever‐powerful tools in coming time.

Language: Английский

Efficient removal of ciprofloxacin from water by BiOX/GaMOF S-scheme heterojunction: A synergistic effect of adsorption and photocatalysis DOI Creative Commons

Pengyuan Chen,

Zhiqi Zhu,

Zhao-Hui LIU

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159689 - 159689

Published: Jan. 1, 2025

Language: Английский

Citations

5

The Liquid Metal Age: A Transition From Hg to Ga DOI
Stephan Handschuh‐Wang, Tao Wang, Tomasz Gancarz

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 19, 2024

Abstract This review offers an illuminating journey through the historical evolution and modern‐day applications of liquid metals, presenting a comprehensive view their significance in diverse fields. Tracing trajectory from mercury to contemporary innovations, paper explores pivotal role industry research. The analysis spans electrical switches, mechanical applications, electrodes, chemical synthesis, energy storage, thermal transport, electronics, biomedicine. Each section examines intricacies metal integration, elucidating contributions technological advancements societal progress. Moreover, critically appraises challenges prospects inherent addressing issues recycling, corrosion management, device stability, economic feasibility, translational hurdles, market dynamics. By delving into these complexities, advances scholarly understanding actionable insights for researchers, engineers, policymakers. It aims catalyze innovation, foster interdisciplinary collaboration, promote metal‐enabled solutions needs. Through its forward‐looking perspective, this serves as guide navigating landscape bridging legacies with challenges, highlighting transformative potential metals shaping future technologies.

Language: Английский

Citations

13

Mechanism behind the Controlled Generation of Liquid Metal Nanoparticles by Mechanical Agitation DOI

Nur‐Adania Nor‐Azman,

Mohammad B. Ghasemian, Richard Fuchs

et al.

ACS Nano, Journal Year: 2024, Volume and Issue: 18(17), P. 11139 - 11152

Published: April 15, 2024

The size-controlled synthesis of liquid metal nanoparticles is necessary in a variety applications. Sonication common method for breaking down bulk metals into small particles, yet the influence critical factors such as composition has remained elusive. Our study employs high-speed imaging to unravel mechanism particle formation during mechanical agitation. Gallium-based metals, with and without secondary bismuth, indium, tin, are analyzed observe effect cavitation surface eruption sonication release. impact inclusion investigated on metals' tension, solution turbidity, size distribution generated particles. work evidences that there an inverse relationship between tension ability be broken by sonication. We show even 0.22 at. % bismuth gallium, significantly decreased from 558 417 mN/m (measured Milli-Q water), resulting enhanced generation rate: 3.6 times increase turbidity ∼43% reduction particles gallium alloy compared same duration. particles' photocatalysis annealed also presented applicability process proof-of-concept demonstration. This contributes broader understanding nanoparticles, controlled characteristics, via agitation diverse

Language: Английский

Citations

9

Liquid Metal‐Based Conductive Nerve Guidance Conduit Combined With Electrical Stimulation Boosts Peripheral Nerve Repair DOI Open Access
Yujie Zhu, Chenchen Song, Dongdong Yao

et al.

Journal of Biomedical Materials Research Part A, Journal Year: 2025, Volume and Issue: 113(2)

Published: Feb. 1, 2025

The combination of nerve guide conduits (NGCs) and electrical stimulation (ES) is an effective treatment for peripheral injury (PNI). Flexible conductive materials with mechanical properties similar to those biological tissues have been shown better long-term biointegration functionality than rigid materials. In this study, liquid metal (LM)-based polycaprolactone/gelatin/polypyrrole/LM (PCL/Gel/PPy/LM, PGPL) NGC was combined exogenous ES repair PNI. PGPL membranes had good hydrophilicity, degradability, properties, its conductivity reached 0.66 ± 0.02 S/m. vitro studies showed that the (2 Hz, 100 mV/cm, 30 min/d) could significantly increase expression neuromarkers a pro-neural differentiation effect. vivo demonstrated NGCs in 200 mV/mm, effectively promote morphological reconstruction functional recovery sciatic rats. At 3 months post-surgery, restored conduction velocity 73.85% 5.45% normal value. LM-based prepared study long defects, which may further expand application LM field tissue engineering.

Language: Английский

Citations

2

Tumor-Specific Liquid Metal Nitric Oxide Nanogenerator for Enhanced Breast Cancer Therapy DOI Creative Commons
Su Chen, Jianhan Lin, Cong Li

et al.

Asian Journal of Pharmaceutical Sciences, Journal Year: 2025, Volume and Issue: 20(2), P. 101018 - 101018

Published: Jan. 10, 2025

Nitric oxide (NO) modulates several cancer-related physiological processes and has advanced the development of green methods for cancer treatment integrated platforms combination or synergistic therapies. Although a nanoengineering strategy been proposed to overcome deficiencies NO gas small donor molecules, such as short half-life, lipophilicity, non-selectivity, poor stability, it remains challenging prepare nanomedicines with simple composition, multiple functions enhanced therapeutic efficacy. Herein, we build liquid metal nanodroplet (LMND)-based nanogenerator (LMND@HSG) that is stabilized by bioreducible guanylated hyperbranched poly(amido amine) (HSG) ligand. Mechanically, tumor microenvironment specifically triggers cascade process glutathione elimination, reactive oxygen species (ROS) generation, release. According actual demand, ROS concentrations could be readily controlled tuning LMND HSG feed amounts. Along intrinsic anticancer property (ROS-mediated apoptosis anti-angiogenesis), LMND@HSG administration further enhance growth suppression compared alone. From this study, leveraging therapy provides more possibilities prospect LMND-based nanomedicines.

Language: Английский

Citations

1

Ni-based electrocatalysts for urea oxidation reaction: mechanism, catalyst design strategies and future perspectives DOI
Qing Li, Yingying Wang,

Tao Pan

et al.

Science China Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 18, 2024

Language: Английский

Citations

4

Production and recycling of the cutting edge material of gallium: A review DOI
Tangzhen Guan,

Minghui Guo,

Lei Wang

et al.

The Science of The Total Environment, Journal Year: 2025, Volume and Issue: 971, P. 179046 - 179046

Published: March 1, 2025

Language: Английский

Citations

0

Liquid Metal Enabled Thermoelectric Effects: Fundamental and Application DOI Open Access
Tangzhen Guan, Jianye Gao, Weiqiu Chen

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 20, 2025

Abstract The thermoelectric (TE) effect, capable of directly converting heat into electrical energy, has catalyzed the development numerous next‐generation functional devices. However, traditional TE generators (TEGs), predominantly composed rigid materials, are unable to maintain synchronous deformation under bending, twisting, or stretching, thereby limiting their application potential. Liquid metal (LM), with its exceptional conductivity, flexibility, thermal self‐healing properties, and unique effects, presents a compelling alternative as conductive heat‐transfer material. By integrating LM TEGs can achieve stretchability, capabilities, enhance conductivity encapsulating materials (ECMs), reduce interfacial contact resistance, improve overall performance. This article provides comprehensive review cutting‐edge intersection between encompassing applications in interconnects (INCs), heat‐conductive fabrication legs. Subsequently, effects at liquid–liquid interfaces gallium commonly used LMs reviewed. Additionally, emerging process fabricating (TEMs) using LM‐printed semiconductors is explored. Finally, based on an evaluation latest advancements this field, challenges promising directions for future research discussed.

Language: Английский

Citations

0

Injectable Bismuth‐Based Composite Enable Bone Defect Repair for Osteosarcoma Treatment and Mild Magnetothermal Bone Regeneration DOI Open Access
Xuelin Wang, Ziliang Cui, Qianchi Jia

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 27, 2025

Abstract Bone implant materials are essential for treating bone defects in clinical, however, current options face challenges minimally invasive implantation, precise situ molding, and long surgical times with large incisions. To address these drawbacks, the newly‐emerging low‐melting‐point bismuth‐based alloys as injectable implants, combined clinically applied polymethyl methacrylate (PMMA) cement proposed here to innovatively design multifunctional bismuth‐PMMA composites (BPCs) effective repair. The as‐prepared BPCs offer excellent injectability, enhanced mechanical properties (≈252% increase compressive strength), favorable magnetothermal effects, enabling invasive, molding via easygoing injection orthopedic surgeries. introduction of PMMA significantly improves strength while maintaining injectability bismuth alloys, reduces exothermic heat during curing prevent thermal damage tissue. In vivo experiments demonstrate that under an alternating magnetic field, exhibit outstanding tumor cell killing capability inhibit osteosarcoma growth through efficient hyperthermia. Further, long‐term implantation results coupled histological analysis display stable filling evident regeneration, attributed collaborative efficacy BPC mild therapy. This study promises revolutionize repair provide a versatile strategy 3D‐printed orthopedics future.

Language: Английский

Citations

0

Mechanical size effects of novel core-shell structured liquid gallium nanoparticles DOI

Wuxu Zhang,

Jinyun Liu,

Zidong He

et al.

Journal of Vacuum Science & Technology A Vacuum Surfaces and Films, Journal Year: 2025, Volume and Issue: 43(4)

Published: May 12, 2025

Liquid metal nanoparticles (LM NPs) find extensive applications in flexible electronics, nanomedicine, and various other fields owing to their deformability distinctive solid-liquid core-shell configuration. Nevertheless, the dynamic structural transformations size-dependent mechanical characteristics of gallium-based are not well comprehended due constraints high-precision nanoparticle characterization techniques. This limitation significantly hampers utilization advancement. study systematically investigates synthesis approaches thiolated nonthiolated gallium NPs comprehensively examines evolution structures properties relation time particle dimensions, leading several significant findings. Initially, scanning electron microscopy revealed formation a 3 nm thick oxide (Ga2O3) shell layer on both during synthesis. The shells these two types did form simultaneously; instead, they underwent further oxidation thickening over time, with thickness stabilizing at day 10 for 15 NPs. Subsequently, impact NPs’ size properties, such as elastic modulus critical fracture force, was investigated using atomic force finite element simulation. It observed that increased exponentially decreased. change only solely influenced by Young’s predicted classical Reissner’s theory but also increase bulk core its effects. A discovery made regarding internal pressure from liquid preventing inward buckling compression. notably nanoparticles, allowing them withstand strains 10% 18% without fracturing. unique behavior has been documented prior studies indicating promising opportunities utilizing designing structured LM

Language: Английский

Citations

0