Oxygen Vacancies and Lattice Distortion Synergistically Enhanced Piezocatalysis of CaZn2(BO3)2 for Nonantibiotic Pharmaceutical Degradation DOI
Xinyi Lu,

Runzhe Zhang,

Yi Liu

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(46), P. 63692 - 63702

Published: Nov. 7, 2024

Piezocatalysis, an emerging green and advanced oxidation technology, has recently been widely researched in environmental treatment. However, the limited polarization efficiency of piezocatalyst is a serious bottleneck for its practical application. The search excellent with high piezoelectric coefficient abundant reactive sites remains urgent task that needs to be developed. Herein, piezocatalyst, CaZn2(BO3)2 (CZBO), obtained by quenching piezocatalysis, which exhibited superior activity ibuprofen (IBP) carbamazepine (CBZ) removal 100% 83.8% under ultrasonic cavitation (120 W, 40 kHz) within 36 min, respectively. outstanding piezocatalytic degradation was attributed strong material synergistic effect oxygen vacancies (OVs) lattice distortion, effectively facilitated generation concentration species (ROS). distortion induced O-deficient [BO3] plane units can promote e– h+ pair separation transportation, OVs electron-rich regions significantly decrease O–O bond activation energy, thus collaboratively contributing production ROS IBP CBZ degradation. This work provides simple avenue enhancing based on proposes insights into reaction mechanisms degrading nonantibiotic pharmaceuticals wastewater.

Language: Английский

Distribution status and influencing factors of antibiotic resistance genes in the Chaohu Lake, China DOI Creative Commons
Yan Zhang,

Guoao Ding,

Yue Gao

et al.

PeerJ, Journal Year: 2025, Volume and Issue: 13, P. e19384 - e19384

Published: April 25, 2025

Background Chaohu Lake (CL) is one of the most polluted areas in China due to its high content antibiotics. However, distribution and influencing factors antibiotic resistance genes (ARGs) this lake are still controversial. Methods To solve problem, we used metagenomic sequencing investigate in-fluencing ARGs CL. Results Our findings revealed existence nine kinds ARGs, including 45 specific genes. The abundant types were multidrug, bacitracin, polymyxin, macrolide lincosamide streptogramin, aminoglycoside. Multiple microorganisms undeniable ARG reservoirs, although they not dominant species microbiota. results also showed that both microbiota physiochemical played important roles shaping distributions Specifically, levels PO4-P (0.5927) total phosphorus (0.4971) had a greater impact than nitrogen (0.0515), NO 3- N (0.0352), NO2-N (−0.1975), NH3-N (−0.0952). Conclusions These provide valuable insights into lakes.

Language: Английский

Citations

0
Geographical and Environmental Factors Differentially Shape Planktonic Microbial Community Assembly and Resistomes Composition in Urban Rivers DOI
Xin Liao, Hongjie Wang,

Dong Wu

et al.

Global Change Biology, Journal Year: 2025, Volume and Issue: 31(4)

Published: April 1, 2025

ABSTRACT Global urbanization accelerates pollution challenges in urban rivers, including increased transmission of bacterial antibiotic resistance genes (ARGs), severely threatening the health aquatic ecosystems and human health. Yet, systematic knowledge differences distribution community assembly patterns across rivers at a continental scale is still insufficient. In this study, we conducted extensive sampling nine representative China. We used amplicon shotgun metagenomic sequencing, state‐of‐the‐art bioinformatics, multivariate statistics to investigate mechanisms planktonic microbiomes (i.e., bacterioplankton microeukaryotes), their resistomes, i.e., ARGs metal (MRGs). Geographical environmental factors played pivotal role shaping vs. resistomes studied rivers. Phylogenetic‐bin‐based null model analysis (iCAMP) indicated that microbiomes, dominated by dispersal limitation drift, tend toward spatial heterogeneity. contrast, driven deterministic processes, display more similar patterns. Cross‐validated Mantel tests revealed geographical geographic distance) were primary regulators microbial assembly, while temperature) control processes resistomes. Our findings provide crucial insights into driving biogeographical entities scale, offering valuable implications for mitigating managing spread from environment humans.

Language: Английский

Citations

0
A “Turn-on” Fluorescence Sensing Strategy Based on DNA-templated Silver Nanoclusters for the Detection of Antibiotic Resistance Genes DOI
Jiaqian Li, Benzhi Wang, Jing Peng

et al.

Analytica Chimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 344170 - 344170

Published: May 1, 2025

Language: Английский

Citations

0
Oxygen Vacancies and Lattice Distortion Synergistically Enhanced Piezocatalysis of CaZn2(BO3)2 for Nonantibiotic Pharmaceutical Degradation DOI
Xinyi Lu,

Runzhe Zhang,

Yi Liu

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(46), P. 63692 - 63702

Published: Nov. 7, 2024

Piezocatalysis, an emerging green and advanced oxidation technology, has recently been widely researched in environmental treatment. However, the limited polarization efficiency of piezocatalyst is a serious bottleneck for its practical application. The search excellent with high piezoelectric coefficient abundant reactive sites remains urgent task that needs to be developed. Herein, piezocatalyst, CaZn2(BO3)2 (CZBO), obtained by quenching piezocatalysis, which exhibited superior activity ibuprofen (IBP) carbamazepine (CBZ) removal 100% 83.8% under ultrasonic cavitation (120 W, 40 kHz) within 36 min, respectively. outstanding piezocatalytic degradation was attributed strong material synergistic effect oxygen vacancies (OVs) lattice distortion, effectively facilitated generation concentration species (ROS). distortion induced O-deficient [BO3] plane units can promote e– h+ pair separation transportation, OVs electron-rich regions significantly decrease O–O bond activation energy, thus collaboratively contributing production ROS IBP CBZ degradation. This work provides simple avenue enhancing based on proposes insights into reaction mechanisms degrading nonantibiotic pharmaceuticals wastewater.

Language: Английский

Citations

1