Science China Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 10, 2024
Language: Английский
Nature, Journal Year: 2024, Volume and Issue: 633(8029), P. 359 - 364
Published: July 8, 2024
Language: Английский
Citations
67
Materials Futures, Journal Year: 2024, Volume and Issue: 3(2), P. 022102 - 022102
Published: April 24, 2024
Abstract Perovskite (PVK) solar cells (PSCs) have garnered considerable research interest owing to their cost-effectiveness and high efficiency. A systematic annual review of the on PSCs is essential for gaining a comprehensive understanding current trends. Herein, analysis papers reporting key findings in 2023 was conducted. Based results, were categorized into six classifications, including regular n–i–p PSCs, inverted p–i–n PVK-based tandem cells, PVK modules, device stability, lead toxicity green solvents. Subsequently, detailed overview summary advancements within each classification presented. Overall, this serves as valuable resource guiding future endeavors field PSCs.
Language: Английский
Citations
23
Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(10)
Published: Jan. 17, 2024
The thermally stable inorganic cesium-based perovskites promise efficient and photovoltaics. Unfortunately, the strong ionic bonds lead to uncontrollable rapid crystallization, making it difficult in fabricating large-area black-phase film for Herein, we developed a facile hydrogen-bonding assisted strategy modulating crystallization of CsPbI
Language: Английский
Citations
19
Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 5, 2025
Abstract The complete phase transition from DMAPbI 3 and Cs 4 PbI 6 intermediates to the final CsPbI perovskite is pivotal for fabricating high‐quality inorganic films. In this study, reaction energy barrier between sought be reduced by increasing their surface energy, where a perfluorinated compound designed using DFT modeling saturate of effectively prevent crystalline growth. Consequently, smaller with ultrahigh react more energetically facilitate rapid conversion desired phase. It found that resultant shows improved crystallinity morphology, as demonstrated suppressed non‐radiative recombination prolonged carrier lifetimes. As result, optimized solar cells (PSCs) achieve power efficiency (PCE) over 20%, along significantly light thermal stability. This work provides way regulate crystallization dynamics advanced quality perovskites.
Language: Английский
Citations
2
Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 34(6)
Published: Oct. 27, 2023
Abstract All‐inorganic perovskite cesium lead triiodide (CsPbI 3 ) with inorganic nature, low‐temperature synthesis, and a suitable bandgap is desirable for high‐performance photovoltaics. However, the scalable production of CsPbI photovoltaics still challenging due to large nucleation energy barrier slow phase transition during unassisted natural crystallization. Here, crystallization dynamics thin films tailored via acetate (PbAc 2 substitution in precursor ink, allowing fabrication efficient all‐inorganic solar cells minimodules. Introducing PbAc enlarges colloid size reduces barrier. Additionally, reactions between dimethylammonium wet film accelerate removal additives generate solvent vapors self‐regulate internal annealing, resulting densely packed, uniform, pinhole‐free over areas. This strategy demonstrates inverted 20.17% efficiency good operational stability (retaining 95.5% initial after continuous operation 1800 h) 15.1%‐efficient minimodules an active area 26.8 cm .
Language: Английский
Citations
27
Joule, Journal Year: 2024, Volume and Issue: 8(10), P. 2851 - 2862
Published: July 24, 2024
Language: Английский
Citations
9
Materials Today Electronics, Journal Year: 2025, Volume and Issue: unknown, P. 100138 - 100138
Published: Jan. 1, 2025
Language: Английский
Citations
1
SusMat, Journal Year: 2023, Volume and Issue: 3(6), P. 894 - 908
Published: Dec. 1, 2023
Abstract Cesium lead triiodide (CsPbI 3 ) perovskite receives tremendous attention for photovoltaic applications, owing to its remarkable thermal stability and optoelectronic properties. However, realizing the CsPbI with high black‐phase properties remains a significant challenge, which largely affects performance of solar cells (PSCs). Herein, aromatic ammonium agents are used modulate crystallization improve efficient PSCs. Systemically experimental studies comprehensively theoretical calculations performed, reveal that histammonium dihydrochloride (HACl 2 could strongly couple during crystallization, leading faster nucleation slower growth, thus modulating dynamics perovskites. Moreover, residual diammonium cations (HA 2+ distributed at grain boundaries on surface perovskites can effectively passivate defects through electrostatic interactions, substantially suppressing trap‐assisted nonradiative recombination, prompting more matched energetics. Consequently, PSCs is improved because combination enhanced crystallinity This work offers new avenue prepare inorganic photovoltaics.
Language: Английский
Citations
17
Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(19), P. 7271 - 7280
Published: Jan. 1, 2024
p–i–n inorganic PSCs with ytterbium cation surface treatment achieve an efficiency of 21.4% enhanced stability, benefiting from improved interfacial band energy alignment, reduced defects and iodide migration.
Language: Английский
Citations
8
Matter, Journal Year: 2024, Volume and Issue: 7(9), P. 3205 - 3220
Published: July 30, 2024
Language: Английский
Citations
6