Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 21, 2025
Abstract
The
demand
for
medical
imaging
with
reduced
patient
dosage
and
higher
resolution
is
growing,
driving
the
need
advanced
X‐ray
detection
technologies.
This
paper
proposes
a
design
paradigm
semiconductors
by
coupling
constituent
motifs
through
crystal
structure
engineering.
study
introduces
strongly
anisotropic
Aurivillius‐type
quasi‐2D
perovskite
structure,
combining
[Bi
2
O
]
2+
groups
stereochemically
active
lone
pair
electrons
(SCALPEs)
[W/Mo
7
2−
anionic
groups,
enabling
enhanced
Compton
scattering
self‐powered
capabilities
local
electric
field
ordering.
results
in
first
Bi‐based
tungstate
Bi
Mo
0.36
W
1.64
9
(BMWO)
detector,
achieving
record
sensitivity
of
381
µC
Gy
−1
cm
−2
.
Additionally,
demonstrates
capability
detector
operating
self‐driven
mode.
work
highlights
BMWO
as
promising
candidate
stable
direct
validates
material
strategy
that
leverages
large
anisotropy
structures
sensitive
detection.
Journal of Materials Chemistry C,
Journal Year:
2024,
Volume and Issue:
12(26), P. 9595 - 9605
Published: Jan. 1, 2024
Lanthanide-doped
fluoride
nanoscintillators
have
received
tremendous
attention
due
to
their
high
photochemical
stability
and
tunable
X-ray
excited
optical
luminescence
compared
traditional
inorganic
scintillators.
Advanced Optical Materials,
Journal Year:
2024,
Volume and Issue:
12(10)
Published: Feb. 12, 2024
Abstract
Effective
online
monitoring
of
the
spatial
distribution
high‐energy
radiation
is
significant
importance
in
various
fields
such
as
medical
imaging,
physics,
and
homeland
security.
However,
achieving
detectors
with
both
high
sensitivity
minimal
disturbance
an
enormous
challenge.
The
present
study
introduces
a
solution
to
this
bottleneck
issue
through
development
full‐inorganic
scintillating
fiber,
successfully
demonstrating
its
application
constructing
device.
activated
Ce
3+
fabricated
using
melt‐in‐tube
approach,
lightweight
density
2.5
g
cm
−3
exhibits
efficient
emission
light
yield
4000
photons
MeV
−1
.
These
characteristics
enable
achievement
detection
while
keeping
incident
beam
at
minimum.
Furthermore,
2D
3D
monitors
are
constructed
based
on
these
fibers,
facilitating
monitoring.
findings
demonstrate
that
fibers
devices
offer
synergistic
combination
negligible
disturbances.
This
progress
not
only
novel
fiber
for
but
also
suggests
promising
applications
nuclear
where
tracking
essential.
Abstract
0D
organic‐inorganic
Cu(I)‐based
halides
have
gained
significant
attention
due
to
their
low
toxicity,
structural
adjustability,
and
moderate
fabrication
conditions.
However,
it
is
still
challenging
explore
stable
efficient
hybrid
that
phase
transition
tunable
spectra
for
multifunctional
photoelectric
applications.
Herein,
two
copper
halides,
green‐emissive
(MTPP)
2
CuI
3
yellow‐emissive
Cu
4
I
6
(MTPP
=
Methyltriphenylphosphonium),
are
successfully
synthesized
using
a
slow
cooling
method.
Both
compounds
exhibit
high
photoluminescence
quantum
yield
(PLQY)
of
81.95
99.7%,
remarkable
steady‐state
light
38
750
63
700
photons
per
MeV,
respectively.
The
scintillation
screen
the
based
on
vacuum‐filtration
enables
X‐ray
imaging
resolution
17.83
18.49
lp
mm
−1
,
showing
great
potential
in
practical
Moreover,
reversible
fast
transformation
between
them
occurs
when
stimulated
by
ethanol
or
MTPP
solutions,
without
requiring
additional
thermal
treatment,
which
endows
with
level
anti‐counterfeiting
under
room
temperature
(RT).
It
worth
noting
they
display
resistance
water,
maintaining
its
purity
even
after
being
immersed
water
30
days.
This
study
introduces
new
approach
investigate
Cu‐based
excellent
performance,
stability,
tunability
multiple
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 21, 2025
Abstract
The
demand
for
medical
imaging
with
reduced
patient
dosage
and
higher
resolution
is
growing,
driving
the
need
advanced
X‐ray
detection
technologies.
This
paper
proposes
a
design
paradigm
semiconductors
by
coupling
constituent
motifs
through
crystal
structure
engineering.
study
introduces
strongly
anisotropic
Aurivillius‐type
quasi‐2D
perovskite
structure,
combining
[Bi
2
O
]
2+
groups
stereochemically
active
lone
pair
electrons
(SCALPEs)
[W/Mo
7
2−
anionic
groups,
enabling
enhanced
Compton
scattering
self‐powered
capabilities
local
electric
field
ordering.
results
in
first
Bi‐based
tungstate
Bi
Mo
0.36
W
1.64
9
(BMWO)
detector,
achieving
record
sensitivity
of
381
µC
Gy
−1
cm
−2
.
Additionally,
demonstrates
capability
detector
operating
self‐driven
mode.
work
highlights
BMWO
as
promising
candidate
stable
direct
validates
material
strategy
that
leverages
large
anisotropy
structures
sensitive
detection.