ACS Applied Materials & Interfaces,
Journal Year:
2025,
Volume and Issue:
17(9), P. 14488 - 14498
Published: Feb. 25, 2025
Liquid
crystal
elastomers
(LCEs)
are
among
the
key
smart
materials
driving
soft
robotics
and
LCE
fibers
have
garnered
significant
attention
for
their
rapid
response
characteristics.
A
convenient
fast
method
programming
orientations
of
liquid
molecules
is
a
focal
issue
in
applications.
Inspired
by
Kirigami
technique,
here,
we
propose
novel
fabricating
based
on
customizable
cutting
paths
secondary
photo-cross-linking.
While
most
existing
actuators
exhibit
contraction
ratios
around
30
to
40%,
our
conical
spiral
actuator,
fabricated
from
LCE-carbon
nanotube
(CNT)
fiber
using
proposed
method,
demonstrates
significantly
higher
ratio,
reaching
up
80%.
The
ratio
can
be
controlled
adjusting
path
parameters
elucidate
mechanism
linking
orientation
distribution
ratio.
Additionally,
deformation
actuator
manipulated
with
light
radiation,
enabling
versatile
functionalities
such
as
catching,
twisting,
gripping.
We
hope
that
fabrication
presented
provides
new
insights
preparing
fibers,
offering
valuable
reference
application
materials.
Communications Chemistry,
Journal Year:
2024,
Volume and Issue:
7(1)
Published: March 19, 2024
Abstract
Self-sustainable
autonomous
locomotion
is
a
non-equilibrium
phenomenon
and
an
advanced
intelligence
of
soft-bodied
organisms
that
exhibit
the
abilities
perception,
feedback,
decision-making,
self-sustainment.
However,
artificial
self-sustaining
architectures
are
often
derived
from
algorithms
onboard
modules
soft
robots,
resulting
in
complex
fabrication,
limited
mobility,
low
sensitivity.
actuators
have
emerged
as
naturally
evolving
systems
do
not
require
human
intervention.
With
shape-morphing
materials
integrating
their
structural
design,
can
direct
responses
to
environmental
changes
achieve
robust
motions
under
sustained
stimulation.
This
perspective
article
discusses
recent
advances
self-sustainable
actuators.
Specifically,
materials,
motion
characteristics,
built-in
negative
feedback
loops,
constant
stimulus
response
patterns
used
summarized.
Artificial
concepts,
modes,
deformation-induced
functional
applications
described.
The
current
challenges
future
opportunities
for
actuation
also
discussed.
Journal of Applied Mechanics,
Journal Year:
2024,
Volume and Issue:
91(10)
Published: June 14, 2024
Abstract
Recent
experiments
have
found
that
a
fiber-mass
system
can
self-oscillate
along
the
vertical
direction
under
non-uniform
temperature
field,
which
necessitates
significant
space.
To
address
challenge
in
adapting
to
situations
with
limited
space,
current
work
introduces
self-oscillating
string-mass
system,
comprising
of
mass
ball
and
thermally
responsive
liquid
crystal
elastomer
string
exposed
constant
gradient
temperature.
By
employing
theoretical
modeling
numerical
simulation,
we
identified
two
motion
regimes
namely,
static
regime
self-oscillation
regime,
elucidated
mechanism
self-oscillation.
Utilizing
analytical
method,
derived
expressions
for
bifurcation
point,
amplitude,
frequency
self-oscillation,
investigated
impact
parameters
on
these
aspects,
were
verified
by
solutions.
Compared
has
superior
stability
deal
small
horizontal
disturbances,
amplify
its
amplitude
thermal
deformation
material,
saves
amount
Given
attributes,
such
presents
novel
possibilities
designing
energy
harvesters,
active
machinery,
soft
robots.
Advanced Science,
Journal Year:
2024,
Volume and Issue:
11(14)
Published: Jan. 29, 2024
Abstract
Helical
structures
of
liquid
crystal
elastomers
(LCEs)
hold
promise
in
soft
robotics
for
self‐regulated
rolling
motions.
The
understanding
their
motion
paths
and
potentials
terrain
exploration
remains
limited.
This
study
introduces
a
self‐adjusting,
lateral‐rolling
robot
inspired
by
sidewinder
snakes.
spring‐like
LCE
helical
filaments
(HFs)
autonomously
respond
to
thermal
cues,
demonstrating
dynamic
sustainable
locomotion
with
adaptive
along
non‐linear
paths.
By
fine‐tuning
the
diameter,
pitch,
modulus
HFs,
environmental
temperature,
movements
allowing
diverse
terrains
over
600
cm
2
area
within
few
minutes,
can
be
programmed.
HFs
are
showcased
navigate
through
nine
obstacles,
including
maze
escaping,
exploration,
target
hunting,
successfully
surmounting
staircases
adaptable
rolling.
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: June 20, 2024
Abstract
The
design
and
engineering
of
liquid
crystal
elastomers
(LCE)
composites
for
enhanced
multifunctionality
responsiveness
is
highly
desired.
Here,
a
hollow
LCE
(h‐LCE)
fiber
fabricated
via
coaxial
spinning,
enabling
the
straightforward
yet
effective
creation
functional
composites,
reported.
Inspired
by
fiber‐tubule
architecture
in
skeletal
muscles,
features
an
outer
shell
programmable
actuation
inner
channel
allowing
integration
variety
media.
Thus,
h‐LCE
can
serve
as
versatile
platform
multifunctionalities
composites.
With
this
unique
strategy,
fibers
are
with
lengths
exceeding
3
meters
lab
diameters
small
250
mm
120
µm,
respectively.
versatility
these
across
various
applications
further
demonstrated,
from
fast‐response
stiffness‐tunable
actuators
integrating
water
flow
triggering
media
shape
memory
polymer
(SMP)
mechanical
properties,
to
electrically
driven
actuating
systems
through
incorporation
metal,
light‐guides
combining
SMP
PDMS
optical
fiber.
conception
not
only
advances
multifunctional
but
also
paves
way
their
application
soft
robotics,
artificial
beyond.
Advanced Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 26, 2025
Cholesteric
liquid
crystal
elastomers
(CLCEs)
hold
great
promise
for
mechanochromic
applications
in
anti-counterfeiting,
smart
textiles,
and
soft
robotics,
thanks
to
the
structural
color
elasticity.
While
CLCEs
are
printed
via
direct
ink
writing
(DIW)
fabricate
free-standing
films,
complex
3D
structures
not
fabricated
due
opposing
rheological
properties
necessary
cholesteric
alignment
multilayer
stacking.
Here,
CLCE
realized
by
utilizing
coaxial
DIW
print
a
CLC
within
silicone
ink.
By
tailoring
compositions,
thus,
properties,
phase
rapidly
forms
without
an
annealing
step,
while
shell
provides
encapsulation
support
core,
allowing
layer-by-layer
printing
of
self-supported
structures.
As
demonstration,
bistable
thin-shell
domes
printed.
Color
changes
compressive
tensile
stresses
can
be
witnessed
from
top
bottom
inverted
domes,
respectively.
When
arranged
array
inverted,
they
snap
back
their
base
state
uniaxial
stretching,
thereby
functioning
as
mechanical
sensors
with
memory.
The
additive
manufacturing
platform
enables
rapid
fabrication
expanding
realm
potential
CLCEs.
Advanced Materials,
Journal Year:
2023,
Volume and Issue:
36(7)
Published: Oct. 9, 2023
Abstract
The
sophisticated
and
complex
haptonastic
movements
in
response
to
environmental‐stimuli
of
living
organisms
have
always
fascinated
scientists.
However,
how
fundamentally
mimic
the
hierarchical
architectures
provide
artificial
counterparts
with
similar
or
even
beyond‐natural
functions
based
on
underlying
mechanism
remains
a
major
scientific
challenge.
Here,
liquid
crystal
elastomer
(LCE)
tendrils
showing
evolutionary
biomimetic
locomotion
are
developed
following
structure–function
principle
that
is
used
nature
grow
climbing
plants.
These
elaborately
designed
tendril‐like
LCE
actuators
possess
an
asymmetric
core–sheath
architecture
which
shows
higher‐to‐lower
transition
degree
LC
orientation
from
sheath‐to‐core
layer
across
semi‐ellipse
cross‐section.
Upon
heating
cooling,
tendril
can
undergo
reversible
shape‐morphing
behaviors,
such
as
helical
coiling/winding,
perversion.
fundamental
revealed
by
using
theoretical
models
finite
element
simulations.
Besides,
incorporation
metal‐ligand
coordination
into
network
provides
reconfigurable
performances
transitions
rotational
deformations.
Finally,
abilities
deformations
integrated
new
reprogrammed
flagellum‐like
perform
mimicking
natural
flagellum.
Deleted Journal,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 15, 2024
Abstract
Responsive
polymers
can
react
to
surrounding
environments
by
changing
their
physical
and/or
chemical
properties.
Among
them,
liquid
crystal
elastomers
(LCEs)
have
emerged
as
one
of
the
important
branches
in
field
applied
polymer
science
due
significant
advantages
flexible
mechanics
and
shape
memory.
Manufacturing
LCE
fibers
with
a
large
specific
surface
area
functional
fillers
has
become
research
hotspot
recent
years.
This
type
LCE‐contained
fibrous
composite
(LCEF)
exhibits
not
only
extremely
high
response
sensitivity
but
also
excellent
axial
mechanical
strength
degree
deformation
freedom.
In
this
paper,
we
provide
bird's
eye
view
developments
LCEF,
including
structural
designs,
synthesis
forming
methods,
principles
modes.
Furthermore,
discuss
advances
LCEF
artificial
muscles,
smart
textiles,
biomimetic
systems,
intelligent
soft
machines,
followed
challenges
possible
routes
fabrications
applications
LCEF.
At
end,
aim
perspective
for
an
emerging
stimulus‐responsive
polymeric
fiber
composites.