Nature, Journal Year: 2020, Volume and Issue: 587(7834), P. 408 - 413
Published: Nov. 18, 2020
Language: Английский
Science, Journal Year: 2017, Volume and Issue: 355(6321)
Published: Jan. 12, 2017
Better living through water-splitting Chemists have known how to use electricity split water into hydrogen and oxygen for more than 200 years. Nonetheless, because the electrochemical route is inefficient, most of made nowadays comes from natural gas. Seh et al. review recent progress in electrocatalyst development accelerate water-splitting, reverse reactions that underlie fuel cells, related oxygen, nitrogen, carbon dioxide reductions. A unified theoretical framework highlights need catalyst design strategies selectively stabilize distinct reaction intermediates relative each other. Science , this issue p. 10.1126/science.aad4998
Language: Английский
Citations
9980
Chemical Society Reviews, Journal Year: 2017, Volume and Issue: 46(2), P. 337 - 365
Published: Jan. 1, 2017
We review the fundamental aspects of metal oxides, chalcogenides and pnictides as effective electrocatalysts for oxygen evolution reaction.
Language: Английский
Citations
5348
Chemical Society Reviews, Journal Year: 2020, Volume and Issue: 49(7), P. 2196 - 2214
Published: Jan. 1, 2020
The fundamentals related to the oxygen evolution reaction and catalyst design are summarized discussed.
Language: Английский
Citations
2088
Chemical Reviews, Journal Year: 2018, Volume and Issue: 118(13), P. 6337 - 6408
Published: March 19, 2018
Over the past few decades, design and development of advanced electrocatalysts for efficient energy conversion technologies have been subjects extensive study. With discovery graphene, two-dimensional (2D) nanomaterials emerged as some most promising candidates heterogeneous due to their unique physical, chemical, electronic properties. Here, we review 2D-nanomaterial-based selected electrocatalytic processes. We first discuss advances in 2D based on different compositions functions followed by specific principles. Following this overview, various processes involved water cycle, carbon nitrogen cycle from fundamental conception functional application. place a significant emphasis engineering strategies influence these intrinsic material performance, such properties adsorption energetics. Finally, feature opportunities challenges ahead electrocatalysts. By considering theoretical calculations, surface characterization, electrochemical tests, describe relationships between structure, energy, apparent activity wide variety with goal providing better understanding emerging at atomic level.
Language: Английский
Citations
1822
Nano Energy, Journal Year: 2017, Volume and Issue: 37, P. 136 - 157
Published: May 10, 2017
Language: Английский
Citations
1474
Chemical Reviews, Journal Year: 2017, Volume and Issue: 117(15), P. 10121 - 10211
Published: July 26, 2017
Spinels with the formula of AB2O4 (where A and B are metal ions) properties magnetism, optics, electricity, catalysis have taken significant roles in applications data storage, biotechnology, electronics, laser, sensor, conversion reaction, energy storage/conversion, which largely depend on their precise structures compositions. In this review, various spinels controlled preparations oxygen reduction/evolution reaction (ORR/OER) beyond summarized. First, composition structure introduced. Then, recent advances preparation solid-, solution-, vapor-phase methods summarized, new particularly highlighted. The physicochemical characteristics such as compositions, structures, morphologies, defects, substrates been rationally regulated through approaches. This regulation can yield improved ORR/OER catalytic activities, further accelerate speed, prolong life, narrow polarization fuel cells, metal-air batteries, water splitting devices. Finally, magnetic, optical, electrical, OER/ORR also discussed. future considered to be closely related environmental issues, will aided by development species advanced characterizations.
Language: Английский
Citations
1397
Energy & Environmental Science, Journal Year: 2019, Volume and Issue: 12(9), P. 2620 - 2645
Published: Jan. 1, 2019
Alkaline water splitting is an attractive method for sustainable hydrogen production.
Language: Английский
Citations
1380
Nature Energy, Journal Year: 2019, Volume and Issue: 4(4), P. 329 - 338
Published: March 25, 2019
Language: Английский
Citations
1369
Energy & Environmental Science, Journal Year: 2018, Volume and Issue: 12(1), P. 322 - 333
Published: Nov. 21, 2018
Defect-rich and ultrathin N doped carbon nanosheets exhibited low overpotentials robust stability for simultaneous ORR, OER HER.
Language: Английский
Citations
1271
Advanced Materials, Journal Year: 2019, Volume and Issue: 31(31)
Published: Jan. 18, 2019
Electrochemical energy storage by making H2 an carrier from water splitting relies on four elementary reactions, i.e., the hydrogen evolution reaction (HER), oxidation (HOR), oxygen (OER), and reduction (ORR). Herein, central objective is to recommend systematic protocols for activity measurements of these reactions benchmark activities comparison, which critical facilitate research development catalysts with high stability. Details electrochemical cell setup, measurements, data analysis used quantify kinetics HER, HOR, OER, ORR in acidic basic solutions are provided, examples state-of-the-art specific mass date given. First, experimental setup discussed provide common guidelines including design, reference electrode selection, counter concerns, working preparation. Second, protocols, collection processing such as ohmic- background-correction catalyst surface area estimation, practice testing comparing different classes recommended. Lastly, some benchmarked comparison across laboratories.
Language: Английский
Citations
1104