Abstract
In
just
over
a
decade,
certified
single-junction
perovskite
solar
cells
(PSCs)
boast
an
impressive
power
conversion
efficiency
(PCE)
of
26.1%.
Such
outstanding
performance
makes
it
highly
viable
for
further
development.
Here,
we
have
meticulously
outlined
challenges
that
arose
during
the
industrialization
PSCs
and
proposed
their
corresponding
solutions
based
on
extensive
research.
We
discussed
main
in
this
field
including
technological
limitations,
multi-scenario
applications,
sustainable
development,
etc.
Mature
photovoltaic
provide
community
with
invaluable
insights
overcoming
industrialization.
upcoming
stages
advancement,
has
become
evident
addressing
concerning
long-term
stability
sustainability
is
paramount.
manner,
can
facilitate
more
effective
integration
into
our
daily
lives.
For
more
than
a
decade,
the
U.S.
Department
of
Energy
(DOE)
has
funded
basic
and
applied
research
development
(R&D)
related
to
critical
materials
address
scientific
technological
(S&T)
challenges
that
underpin
Science,
Journal Year:
2023,
Volume and Issue:
382(6668), P. 284 - 289
Published: Oct. 19, 2023
P-i-n
geometry
perovskite
solar
cells
(PSCs)
offer
simplified
fabrication,
greater
amenability
to
charge
extraction
layers,
and
low-temperature
processing
over
n-i-p
counterparts.
Self-assembled
monolayers
(SAMs)
can
enhance
the
performance
of
p-i-n
PSCs
but
ultrathin
SAMs
be
thermally
unstable.
We
report
a
robust
hole-selective
layer
comprised
nickel
oxide
(NiOx)
nanoparticle
film
with
surface-anchored
(4-(3,11-dimethoxy-7H-dibenzo[c,g]carbazol-7-yl)butyl)phosphonic
acid
(MeO-4PADBC)
SAM
that
improve
stabilize
NiOx/perovskite
interface.
The
energetic
alignment
favorable
contact
binding
between
NiOx/MeO-4PADBC
reduced
voltage
deficit
various
compositions
led
strong
interface
toughening
effects
under
thermal
stress.
resulting
1.53-electron-volt
devices
achieved
25.6%
certified
power
conversion
efficiency
maintained
>90%
their
initial
after
continuously
operating
at
65
degrees
Celsius
for
1200
hours
1-sun
illumination.
Science,
Journal Year:
2023,
Volume and Issue:
381(6654), P. 209 - 215
Published: July 13, 2023
Perovskite
solar
cells
(PSCs)
consisting
of
interfacial
two-
and
three-dimensional
heterostructures
that
incorporate
ammonium
ligand
intercalation
have
enabled
rapid
progress
toward
the
goal
uniting
performance
with
stability.
However,
as
field
continues
to
seek
ever-higher
durability,
additional
tools
avoid
progressive
are
needed
minimize
degradation
at
high
temperatures.
We
used
ligands
nonreactive
bulk
perovskites
investigated
a
library
varies
molecular
structure
systematically.
found
fluorinated
aniliniums
offer
passivation
simultaneously
reactivity
perovskites.
Using
this
approach,
we
report
certified
quasi-steady-state
power-conversion
efficiency
24.09%
for
inverted-structure
PSCs.
In
an
encapsulated
device
operating
85°C
50%
relative
humidity,
document
1560-hour
T85
maximum
power
point
under
1-sun
illumination.
Science,
Journal Year:
2024,
Volume and Issue:
383(6679)
Published: Jan. 11, 2024
Perovskite/silicon
tandem
solar
cells
offer
a
promising
route
to
increase
the
power
conversion
efficiency
of
crystalline
silicon
(c-Si)
beyond
theoretical
single-junction
limitations
at
an
affordable
cost.
In
past
decade,
progress
has
been
made
toward
fabrication
highly
efficient
laboratory-scale
tandems
through
range
vacuum-
and
solution-based
perovskite
processing
technologies
onto
various
types
c-Si
bottom
cells.
However,
become
commercial
reality,
transition
from
laboratory
industrial
will
require
appropriate,
scalable
input
materials
manufacturing
processes.
addition,
perovskite/silicon
research
needs
increasingly
focus
on
stability,
reliability,
throughput
cell
production
characterization,
cell-to-module
integration,
accurate
field-performance
prediction
evaluation.
This
Review
discusses
these
aspects
in
view
contemporary
manufacturing,
offers
insights
into
possible
pathways
photovoltaics,
highlights
opportunities
realize
this
goal.
