Constructing robust heterointerfaces for carrier viaduct via interfacial molecular bridges enables efficient and stable inverted perovskite solar cells DOI
Huifen Xu, Zheng Liang, Jiajiu Ye

et al.

Energy & Environmental Science, Journal Year: 2023, Volume and Issue: 16(12), P. 5792 - 5804

Published: Jan. 1, 2023

To ensure carrier selectivity, we propose an interfacial molecular bridge comprised of Ph-CH 2 N + H 3− n (CH 3 ) ammonium cation at the perovskite–substrate interface and reveal its underlying impact on PSCs performance.

Language: Английский

Improved charge extraction in inverted perovskite solar cells with dual-site-binding ligands DOI
Hao Chen, Cheng Liu, Jian Xu

et al.

Science, Journal Year: 2024, Volume and Issue: 384(6692), P. 189 - 193

Published: April 11, 2024

Inverted (pin) perovskite solar cells (PSCs) afford improved operating stability in comparison to their nip counterparts but have lagged power conversion efficiency (PCE). The energetic losses responsible for this PCE deficit pin PSCs occur primarily at the interfaces between and charge-transport layers. Additive surface treatments that use passivating ligands usually bind a single active binding site: This dense packing of electrically resistive passivants perpendicular may limit fill factor PSCs. We identified two neighboring lead(II) ion (Pb

Language: Английский

Citations

496
Solar cell efficiency tables (Version 63) DOI Creative Commons
Martin A. Green, Ewan D. Dunlop, Masahiro Yoshita

et al.

Progress in Photovoltaics Research and Applications, Journal Year: 2023, Volume and Issue: 32(1), P. 3 - 13

Published: Nov. 29, 2023

Abstract Consolidated tables showing an extensive listing of the highest independently confirmed efficiencies for solar cells and modules are presented. Guidelines inclusion results into these outlined new entries since July 2023 reviewed.

Language: Английский

Citations

430
Stabilized hole-selective layer for high-performance inverted p-i-n perovskite solar cells DOI
Zhen Li, Xianglang Sun, Xiaopeng Zheng

et al.

Science, Journal Year: 2023, Volume and Issue: 382(6668), P. 284 - 289

Published: Oct. 19, 2023

P-i-n geometry perovskite solar cells (PSCs) offer simplified fabrication, greater amenability to charge extraction layers, and low-temperature processing over n-i-p counterparts. Self-assembled monolayers (SAMs) can enhance the performance of p-i-n PSCs but ultrathin SAMs be thermally unstable. We report a robust hole-selective layer comprised nickel oxide (NiOx) nanoparticle film with surface-anchored (4-(3,11-dimethoxy-7H-dibenzo[c,g]carbazol-7-yl)butyl)phosphonic acid (MeO-4PADBC) SAM that improve stabilize NiOx/perovskite interface. The energetic alignment favorable contact binding between NiOx/MeO-4PADBC reduced voltage deficit various compositions led strong interface toughening effects under thermal stress. resulting 1.53-electron-volt devices achieved 25.6% certified power conversion efficiency maintained >90% their initial after continuously operating at 65 degrees Celsius for 1200 hours 1-sun illumination.

Language: Английский

Citations

324
Bimolecularly passivated interface enables efficient and stable inverted perovskite solar cells DOI
Cheng Liu, Yi Yang, Hao Chen

et al.

Science, Journal Year: 2023, Volume and Issue: 382(6672), P. 810 - 815

Published: Nov. 16, 2023

Compared with the n-i-p structure, inverted (p-i-n) perovskite solar cells (PSCs) promise increased operating stability, but these photovoltaic often exhibit lower power conversion efficiencies (PCEs) because of nonradiative recombination losses, particularly at perovskite/C60 interface. We passivated surface defects and enabled reflection minority carriers from interface into bulk using two types functional molecules. used sulfur-modified methylthio molecules to passivate suppress through strong coordination hydrogen bonding, along diammonium repel reduce contact-induced achieved field-effect passivation. This approach led a fivefold longer carrier lifetime one-third photoluminescence quantum yield loss certified quasi-steady-state PCE 25.1% for PSCs stable operation 65°C >2000 hours in ambient air. also fabricated monolithic all-perovskite tandem 28.1% PCE.

Language: Английский

Citations

320
Non-fullerene acceptor with asymmetric structure and phenyl-substituted alkyl side chain for 20.2% efficiency organic solar cells DOI
Yuanyuan Jiang,

Shaoming Sun,

Renjie Xu

et al.

Nature Energy, Journal Year: 2024, Volume and Issue: 9(8), P. 975 - 986

Published: June 12, 2024

Language: Английский

Citations

256
Low-loss contacts on textured substrates for inverted perovskite solar cells DOI

So Min Park,

Mingyang Wei, Nikolaos Lempesis

et al.

Nature, Journal Year: 2023, Volume and Issue: 624(7991), P. 289 - 294

Published: Oct. 23, 2023

Language: Английский

Citations

224
Lead-chelating hole-transport layers for efficient and stable perovskite minimodules DOI
Chengbin Fei, Nengxu Li, Mengru Wang

et al.

Science, Journal Year: 2023, Volume and Issue: 380(6647), P. 823 - 829

Published: May 25, 2023

The defective bottom interfaces of perovskites and hole-transport layers (HTLs) limit the performance p-i-n structure perovskite solar cells. We report that addition lead chelation molecules into HTLs can strongly interact with lead(II) ion (Pb 2+ ), resulting in a reduced amorphous region near passivated surface. minimodule an aperture area 26.9 square centimeters has power conversion efficiency (PCE) 21.8% (stabilized at 21.1%) is certified by National Renewable Energy Laboratory (NREL), which corresponds to minimal small-cell 24.6% 24.1%) throughout module area. Small-area cells large-area minimodules had light soaking stability 3010 2130 hours, respectively, loss 10% from initial value under 1-sun illumination open-circuit voltage conditions.

Language: Английский

Citations

193
Reinforcing self-assembly of hole transport molecules for stable inverted perovskite solar cells DOI
Hongcai Tang, Zhichao Shen, Yangzi Shen

et al.

Science, Journal Year: 2024, Volume and Issue: 383(6688), P. 1236 - 1240

Published: March 14, 2024

Power conversion efficiencies (PCEs) of inverted perovskite solar cells (PSCs) have been improved by the use a self-assembled monolayer (SAM) hole transport layer. Long-term stability PSCs requires keeping SAM compact under layer during operation. We found that strong polar solvents in precursor desorb if it is anchored on substrates hydrogen-bonded, rather than covalently bonded, hydroxyl groups. used atomic-layer deposition to create an indium tin oxide substrate with fully covalent hydroxyl-covered surface for anchoring, as well trimethoxysilane group exhibited tridentate anchoring substrate. The resulting achieved PCEs 24.8 (certified 24.6) and 23.2% aperture areas 0.08 1.01 square centimeters, respectively. devices retained 98.9 98.2% initial PCE after 1000 hours damp-heat test operation maximum power point tracking at 85°C 1200 standard illumination,

Language: Английский

Citations

151
Aqueous synthesis of perovskite precursors for highly efficient perovskite solar cells DOI
Peide Zhu, Deng Wang, Yong Zhang

et al.

Science, Journal Year: 2024, Volume and Issue: 383(6682), P. 524 - 531

Published: Feb. 1, 2024

High-purity precursor materials are vital for high-efficiency perovskite solar cells (PSCs) to reduce defect density caused by impurities in perovskite. In this study, we present aqueous synthesized microcrystals as PSCs. Our approach enables kilogram-scale mass production and synthesizes formamidinium lead iodide (FAPbI

Language: Английский

Citations

108
Multifunctional ytterbium oxide buffer for perovskite solar cells DOI
Peng Chen,

Yun Xiao,

Juntao Hu

et al.

Nature, Journal Year: 2024, Volume and Issue: 625(7995), P. 516 - 522

Published: Jan. 17, 2024

Language: Английский

Citations

96