Green Solvent-Processable Trifluoromethylated π-Extended Non-Fullerene Acceptors for High-Efficiency Organic Solar Cells
Liang−Wen Feng,
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Guoping Li,
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S. Mukherjee
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et al.
Energy & Fuels,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 26, 2025
Language: Английский
Advancing Intrinsically Stretchable Organic Photovoltaics with a Nearly Amorphous Polymer Semiconductor
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 7, 2025
Abstract
Current
state‐of‐the‐art
organic
photovoltaic
(OPV)
films,
composed
of
conjugated
polymer
donors
and
small
molecule
acceptors,
are
often
limited
by
the
high
brittleness
their
rigid
backbones,
which
restricts
application
in
wearable
devices.
In
contrast,
all‐polymer
OPVs
have
demonstrated
enhanced
intrinsic
stretchability,
but
further
advancements
necessary
to
meet
demands.
Here,
an
uncharted
strategy
is
reported
enhance
mechanical
stretchability
performance
incorporating
a
nearly‐amorphous
polymer,
poly(indacenodithiophene‐co‐benzothiadiazole)
(IDTBT)
into
layer‐by‐layer
structured
active
layer.
IDTBT
possesses
fracture
strain
≈80%,
significantly
outperforming
well‐known
donor
polymers
like
PM6.
The
incorporation
enhances
properties,
with
both
optimized
at
low
contents.
More
importantly,
intrinsically
stretchable
demonstrate
superior
stability
impressive
power
conversion
efficiency
14.2%,
highest
date
this
category.
Particularly,
IDTBT‐strengthened
retain
72%
initial
under
tensile
50%,
68%
even
after
being
stretched
hundreds
times
30%
strain,
demonstrating
exceptional
stability.
This
approach
underscores
potential
semiconductors
designing
highly
OPVs,
paving
way
for
seamless
integration
electronics.
Language: Английский
O, S, and N Bridged Atoms Screening on 2D Conjugated Central Units of High‐Performance Acceptors
Xiangjian Cao,
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Zheng Xu,
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Ruohan Wang
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et al.
Advanced Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 6, 2025
Abstract
Almost
all
of
central
cores
in
high‐performance
acceptors
are
limited
to
the
electron‐withdrawing
diimide
structure
currently,
which
constrains
further
acceptor
structural
innovation
greatly.
Herein,
oxygen
(O),
sulfur
(S),
and
nitrogen
(N)
atoms
adopted
bridge
2D
conjugated
cores,
yielding
three
platforms
CH─O,
CH─S,
CH─N
that
differ
by
only
two
atoms.
Because
characteristic
atomic
outer
electron
configuration
hybrid
orbital
orientation,
O‐,
S‐,
N‐bridged
display
quite
different
conformations
electronic
properties,
namely,
dibenzodioxin
(planar,
non‐aromatic),
thianthrene
(puckered,
non‐aromatic)
phenazine
aromatic),
respectively.
A
systematic
investigation
discloses
how
core,
especially
its
p‐π
overlap
between
lone
pair
on
O/S/N
coterminous
benzene
planes,
affect
intrinsic
photoelectronic
properties
for
first
time.
Finally,
CH─N‐based
binary
device
affords
highest
fill
factor
83.13%
organic
photovoltaics
along
with
a
first‐class
efficiency
20.23%.
By
evaluating
strictly
controlled
molecular
comprehensively,
work
reveals
potential
uniqueness
determining
excellent
photovoltaic
outcomes
acceptors.
Language: Английский
Organic solar cells: beyond 20%
Ruijie Ma,
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Zhenghui Luo,
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Youdi Zhang
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et al.
Science China Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 30, 2025
Language: Английский
Emerging flexible photovoltaic technology: From materials to devices
Zhiyang Xu,
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Tangyue Xue,
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Qiang Guo
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et al.
Deleted Journal,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 9, 2025
Abstract
The
third‐generation
photovoltaic
technologies
such
as
perovskite
solar
cells
and
organic
cells,
have
low‐temperature
solution‐processing
ability,
flexibility
lightweight,
which
is
expected
to
be
developed
into
a
wearable
device
that
fits
the
human
body.
Here,
flexible
substrates,
transparent
electrode
materials,
materials
devices
for
are
systematically
introduced.
First,
substrates
regarding
their
suitability
provided.
Then,
research
progress
of
commonly
used
electrodes
reviewed,
including
poly(3,4‐ethylenedioxythiophene):poly(styrene
sulfonate)
(PEDOT:PSS),
metal
nanowires,
carbon‐based
composite
materials.
Next,
we
summarize
how
realize
optimize
devices,
balance
power
conversion
efficiency
mechanical
stability
device.
Finally,
propose
several
promising
directions
intrinsically
cells.
Language: Английский