Polymeric anionic silver(I) complexes {Cat[Ag[B10H10]]} (Cat = Pr4N+, Ph4P+, Ph4As+) with facial and edge-facial coordination of the boron cluster

Polyhedron, Journal Year: 2022, Volume and Issue: 223, P. 115932 - 115932

Published: May 25, 2022

Language: Английский

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Boron cluster anions [B H ]2– (n = 10, 12) in design of polynuclear silver(I) and copper(II) complexes

Polyhedron, Journal Year: 2023, Volume and Issue: 247, P. 116710 - 116710

Published: Nov. 6, 2023

Language: Английский

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16-Vertex oblato–hypho-titanaborane [(Cp*Ti)₂B₁₄H₁₈]

Chemical Communications, Journal Year: 2023, Volume and Issue: 59(78), P. 11676 - 11679

Published: Jan. 1, 2023

Although Lipscomb predicted in 1977 that supra-icosahedral boron clusters would be viable, their synthesis has been impeded by the unavailability of appropriate synthetic methodologies. Herein, we report first examples open 16-vertex oblato-hypho-titanaborane [(Cp*Ti)2B14H17R] (1: R = H; 2: Me) having a non-Wadean 19-skeletal-electron-pair count. Interestingly, these show six-membered [Ti2B4] face, which could lead to closo-19-vertex clusters.

Language: Английский

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Features of the formation of d10 metal complexes with benzimidazoles derivatives in the presence of the closo-decaborate anion

Polyhedron, Journal Year: 2022, Volume and Issue: 226, P. 116108 - 116108

Published: Aug. 26, 2022

Language: Английский

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Nature of the Interactions between B12N12 and Inorganic Aromatic Molecules (B3N3H6, B3P3H6, B3O3H3, B3S3H3)

Russian Journal of Inorganic Chemistry, Journal Year: 2023, Volume and Issue: 68(6), P. 753 - 760

Published: June 1, 2023

Language: Английский

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