International Journal of Molecular Sciences,
Journal Year:
2022,
Volume and Issue:
23(7), P. 3577 - 3577
Published: March 25, 2022
A
post-nanotechnology
concept
has
been
assigned
to
an
emerging
concept,
nanoarchitectonics.
Nanoarchitectonics
aims
establish
a
discipline
in
which
functional
materials
are
fabricated
from
nano-scale
components
such
as
atoms,
molecules,
and
nanomaterials
using
various
techniques.
opens
ways
form
more
unified
paradigm
by
integrating
nanotechnology
with
organic
chemistry,
supramolecular
material
microfabrication
technology,
biotechnology.
On
the
other
hand,
biological
systems
consist
of
rational
organization
constituent
molecules.
Their
structures
have
highly
asymmetric
hierarchical
features
that
allow
for
chained
coordination,
signal
amplification,
vector-like
energy
flow.
The
process
nanoarchitectonics
is
based
on
premise
combining
several
different
processes,
makes
it
easier
obtain
structure.
Therefore,
suitable
methodology
creating
structural
asymmetry
hierarchy
like
biosystems.
creation
somewhat
similar
systems.
It
can
be
said
goal
create
those
found
This
review
article
summarizes
synthesis
biomimetic
molecules
their
structure
formation
viewpoints,
molecular
level
cellular
level.
Several
recent
examples
arranged
categorized
illustrate
trend
sections
(i)
synthetic
bio-related
units,
(ii)
self-assembly
(iii)
nucleic
acids,
(iv)
peptides,
(v)
proteins,
(vi)
conjugation
materials.
Small Methods,
Journal Year:
2022,
Volume and Issue:
6(5)
Published: March 29, 2022
Abstract
Mechanical
stimuli
have
rather
ambiguous
and
less‐specific
features
among
various
physical
stimuli,
but
most
materials
exhibit
a
certain
level
of
responses
upon
mechanical
inputs.
Unexplored
sciences
remain
in
responding
systems
as
one
the
frontiers
science.
Nanoarchitectonics
approaches
for
mechanically
are
discussed
mechano‐nanoarchitectonics
this
review
article.
Recent
on
molecular
with
response
capabilities
first
exemplified
two
viewpoints:
i)
control
supramolecular
assemblies
ii)
evaluation
atom/molecular
structures.
In
following
sections,
special
attentions
interfacial
environments
emphasized.
The
section
entitled
iii)
Control
Molecular
System
at
Dynamic
Interface
describes
coupling
macroscopic
forces
molecular‐level
phenomena.
Delicate
can
be
applied
to
functional
molecules
embedded
air–water
interface
where
operation
machines
tuning
receptors
actions
discussed.
Finally,
important
role
media
further
extended
living
cells
described
iv)
Biosystems.
Pioneering
cell
fate
regulations
liquid–liquid
interfaces
addition
well‐known
mechanobiology.
Organic Letters,
Journal Year:
2020,
Volume and Issue:
22(21), P. 8658 - 8664
Published: Oct. 12, 2020
We
report
the
catalytic
direct
peptide
bond
formations
via
dehydrative
condensation
of
β-hydroxy-α-amino
acids,
affording
serine,
threonine,
or
β-hydroxyvaline-derived
peptides
in
high
to
excellent
yields
with
functional
group
tolerance,
minimum
epimerization,
and
chemoselectivity.
The
key
success
these
atom-economical
transformations
is
use
diboronic
acid
anhydride
catalyst
for
hydroxy-directed
reactions.
Chemical Communications,
Journal Year:
2021,
Volume and Issue:
57(52), P. 6346 - 6359
Published: Jan. 1, 2021
The
development
of
methods
for
amide
bond
formation
without
recourse
to
typical
condensation
reagents
has
become
an
emerging
research
area
and
been
actively
explored
in
the
past
quarter
century.
Journal of the American Chemical Society,
Journal Year:
2022,
Volume and Issue:
144(4), P. 1758 - 1765
Published: Jan. 21, 2022
A
new
type
of
peptide
bond
formation
utilizing
silacyclic
amino
acids
or
peptides
is
described.
This
work
has
the
following
advantages:
(1)
imidazolylsilane
a
highly
fascinating
coupling
reagent
for
dipeptide
synthesis
from
N-,C-terminal
unprotected
with
acid
tert-butyl
esters;
(2)
deprotection
ester
at
C-terminus
and
cyclization
sequentially
proceed
depending
on
reaction
conditions
to
afford
novel
dipeptides;
(3)
cyclized
products
show
remarkable
capacity
as
substrates
elongation
because
compounds
can
act
both
nucleophiles
electrophiles,
this
lead
one-pot
site-selective
tetra-
oligopeptide
syntheses.
These
innovative
advantages
will
help
simplify
classical
significantly.
Molecules,
Journal Year:
2021,
Volume and Issue:
26(15), P. 4636 - 4636
Published: July 30, 2021
Nanoarchitectonics
of
two-dimensional
materials
from
zero-dimensional
fullerenes
is
mainly
introduced
in
this
short
review.
Fullerenes
are
simple
objects
with
mono-elemental
(carbon)
composition
and
structure.
However,
their
derivatives
can
create
various
types
materials.
The
exemplified
approaches
demonstrated
fabrications
including
size-tunable
hexagonal
fullerene
nanosheet,
nano-mesh,
van
der
Waals
solid,
fullerene/ferrocene
hybrid
fullerene/cobalt
porphyrin
array
the
supramolecular
template,
framework,
liquid
crystal,
frustrated
layered
self-assembly
hierarchical
zero-to-one-to-two
dimensional
assembly
for
cell
culture.
The Journal of Organic Chemistry,
Journal Year:
2023,
Volume and Issue:
88(14), P. 9853 - 9869
Published: July 11, 2023
Triarylsilanols
have
been
reported
as
the
first
silicon-centered
molecular
catalysts
for
direct
amidation
of
carboxylic
acids
with
amines
identified
after
a
screen
silanols,
silanediols,
disiloxanediols,
and
incompletely
condensed
silsesquioxanes
potential
homogeneous
catalysts.
Subsequent
synthesis
testing
various
electronically
differentiated
triarylsilanols
tris(p-haloaryl)silanols
more
active
than
parent
triarylsilanol,
where
bromide
congener
is
found
to
be
most
active.
Catalyst
decomposition
can
observed
by
NMR
methods,
but
RPKA
methods
reveal
that
product
inhibition
operative,
tertiary
amides
are
inhibitory
secondary
amides.
Studies
using
an
authentically
synthesized
triaryl
silylester
putative
intermediate
in
catalytic
system
enable
plausible
mechanism
proposed
supported
computationals.
